The Permeability of Organic Substances to Water

1939 ◽  
Vol 12 (1) ◽  
pp. 74-77
Author(s):  
E. Badum

Abstract Although organic substances are in the ordinary sense regarded as waterproof, actually they are somewhat permeable to water vapor, and this permeability is sufficient to render them inapplicable as covering or sheathing for cables. In view of this, it was decided to study in a quantitative way the phenomenon of permeability to water of organic substances. The method chosen for making these measurements and the results obtained are described in a brief way in the following paragraphs. The first measurements were made with an apparatus which consisted of a hemispherical bell jar, the open part of which was carefully sealed by a sheet of the substance to be tested. To this bell jar was attached, by a ground-glass connection, a tube which could be closed by a stopcock, and which contained phosphorous pentoxide. In this way the vapor pressure of water within the bell jar was maintained at zero. The small apparatus was suspended in a constant-temperature chamber saturated with water vapor. The increase in weight of the weighing tube containing the phosphorous pentoxide was a measure of the amount of water which diffused through the sheet being tested.

Author(s):  
V. R. Matricardi ◽  
G. G. Hausner ◽  
D. F. Parsons

In order to observe room temperature hydrated specimens in an electron microscope, the following conditions should be satisfied: The specimen should be surrounded by water vapor as close as possible to the equilibrium vapor pressure corresponding to the temperature of the specimen.The specimen grid should be inserted, focused and photo graphed in the shortest possible time in order to minimize dehydration.The full area of the specimen grid should be visible in order to minimize the number of changes of specimen required.There should be no pressure gradient across the grid so that specimens can be straddled across holes.Leakage of water vapor to the column should be minimized.


Membranes ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 593
Author(s):  
Nasim Alikhani ◽  
Douglas W. Bousfield ◽  
Jinwu Wang ◽  
Ling Li ◽  
Mehdi Tajvidi

In this study, a simplified two-dimensional axisymmetric finite element analysis (FEA) model was developed, using COMSOL Multiphysics® software, to simulate the water vapor separation in a moisture-selective hollow-fiber membrane for the application of air dehumidification in wood drying processes. The membrane material was dense polydimethylsiloxane (PDMS). A single hollow fiber membrane was modelled. The mass and momentum transfer equations were simultaneously solved to compute the water vapor concentration profile in the single hollow fiber membrane. A water vapor removal experiment was conducted by using a lab-scale PDMS hollow fiber membrane module operated at constant temperature of 35 °C. Three operation parameters of air flow rate, vacuum pressure, and initial relative humidity (RH) were set at different levels. The final RH of dehydrated air was collected and converted to water vapor concentration to validate simulated results. The simulated results were fairly consistent with the experimental data. Both experimental and simulated results revealed that the water vapor removal efficiency of the membrane system was affected by air velocity and vacuum pressure. A high water vapor removal performance was achieved at a slow air velocity and high vacuum pressure. Subsequently, the correlation of Sherwood (Sh)–Reynolds (Re)–Schmidt (Sc) numbers of the PDMS membrane was established using the validated model, which is applicable at a constant temperature of 35 °C and vacuum pressure of 77.9 kPa. This study delivers an insight into the mass transport in the moisture-selective dense PDMS hollow fiber membrane-based air dehumidification process, with the aims of providing a useful reference to the scale-up design, process optimization and module development using hollow fiber membrane materials.


MAUSAM ◽  
2021 ◽  
Vol 68 (2) ◽  
pp. 335-348
Author(s):  
YOUNES KHOSRAVI ◽  
HASAN LASHKARI ◽  
HOSEIN ASAKEREH

Recognitionanddetectionofclimaticparameters inhave animportant role inclimate change monitoring. In this study, the analysis of oneofthe most importantparameters, water vapor pressure (WVP), was investigated. For this purpose, two non-parametric techniques, Mann-Kendall and Sen's Slope Estimator, were used to analyze the WVP trend and to determine the magnitude of the trends, respectively. To analyze these tests, ground station observations [10 stations for period of 44 years (1967-2010)] and gridded data [pixels with the dimension of 9 × 9 km over a 30-year period (1981-2010)] in South and SouthwestofIran were used. By programming in MATLAB software, the monthly, seasonal and annual WVP time series were extracted and MK and Sen's slope estimator tests were done. The results of monthly MK test on ground station observations showed that the significant downward trends are more considerable than significant upward trends. It also showed that the WVP highest frequency was more in warm months, April to September and the highest frequency of significant trends slope was in February and May. The spatial distribution of MK test of monthly gridded WVP time series showed that the upward trends were detected mostly in western zone and near the Persian Gulf in August. On the other hand, the downward trends through months. The maximum and minimum values of positive trends slope occurred in warm months and cold months, respectively. The analysis of the MK test of the annual WVP time series indicated the upward significant trends in the southeast and southwest zones of study area.  


2009 ◽  
Vol 131 (3) ◽  
Author(s):  
Pamela L. Dickrell ◽  
N. Argibay ◽  
Osman L. Eryilmaz ◽  
Ali Erdemir ◽  
W. Gregory Sawyer

Microtribological measurements of a hydrogenated diamondlike carbon film in controlled gaseous environments show that water vapor plays a significant role in the friction coefficient. These experiments reveal an initial high friction transient behavior that does not reoccur even after extended periods of exposure to low partial pressures of H2O and O2. Experiments varying both water vapor pressure and sample temperature show trends of a decreasing friction coefficient as a function of both the decreasing water vapor pressure and the increasing substrate temperature. Theses trends are examined with regard to first order gas-surface interactions. Model fits give activation energies on the order of 40 kJ/mol, which is consistent with water vapor desorption.


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