Preparation and Use of Cyclized Rubber as a Stiffening Resin in Rubber
Abstract The condition for miscibility of low-molecular liquids is that the cohesion-energy densities should be of the same order of magnitude. The permissible difference decreases sharply as the molecular weight is increased, and a solution of equal amounts of rubber and polystyrene separates into two layers at room temperature when the concentration rises above 2 per cent, whereas low-molecular aliphatic and aromatic hydrocarbons are completely miscible. The undiluted polymers can, however, be mixed to an apparently homogeneous state on the mill if the correct mixing temperature is chosen. Presumably the extreme length of the polymer molecules allows them to be caught and dispersed separately in the stress gradient between the rolls. That the mixture is not stable and tends to separate into the components on extension, even after vulcanization of the rubber, can be deduced from the bending of the stress-strain curve towards the strain axis—generally an indication of irreversible changes in structure for many materials. This tendency to irreversible separation, which is a disadvantage for any application, can be suppressed by the formation of primary bonds between the two polymers. There are at present three methods to produce such bonds : (1) covulcanization (if the added polymer is unsaturated); (2) mastication in an inert atmosphere; (3) graft polymerization. If a sufficient number of such bonds has been formed, the added polymer can no longer be extracted from the vulcanized compound by solvents, and the bend in the stress-strain curve has disappeared.