The Interaction between Carbon Black and Sulfur during Vulcanization

1959 ◽  
Vol 32 (1) ◽  
pp. 118-122
Author(s):  
G. A. Blokh ◽  
A. G. Yaroshevich
Keyword(s):  
Free Energy ◽  
Carbon Black ◽  
High Strength ◽  
Point Of View ◽  
Physical Point ◽  
Space Lattice ◽  
Carbon Particles ◽  
Continuous Mass ◽  
Filler Particles ◽  
Increased Strength

Abstract The mechanism of the reinforcement of rubber by carbon black has until recently been interpreted from the physical point of view. According to the researches of P. A. Rebinder and coworkers the extent of the interaction between the filler and the rubber is given by the decrease in the free energy of the system resulting from the wetting of 1 cm2 of the surface of the filler particles by rubber. The rubber is bound to the surface of the carbon black particles through adsorption and forms around these particles an extended film which is characterized by high strength; in this state the rubber is referred to as “bound” or film-like rubber. In systems in which such adsorbed rubber is present there appears on the surface of the filler particles an effect which resembles a kind of “crystallization” of rubber which results in a strengthening of the interaction between individual chains and hence in increased strength of the rubber. According to Kusov, at optimum filling of the rubber with carbon black the mixture constitutes a continuous mass—a molecular space lattice with carbon particles situated in its nodes.

scholarly journals Information processing in biological molecular machines

2020 ◽  
Author(s):  
M. Kurzynski ◽  
P. Chelminiak
Keyword(s):  
Free Energy ◽  
Time Course ◽  
Stochastic Dynamics ◽  
Short Term Memory ◽  
Molecular Machines ◽  
Complex Model ◽  
Point Of View ◽  
Physical Point ◽  
Protein Motors ◽  
Organized Assemblies

ABSTRACTBiological molecular machines are enzymes that simultaneously catalyze two processes, one donating free energy and second accepting it. Recent studies show that most native protein enzymes have a rich stochastic dynamics of conformational transitions which often manifests in fluctuating rates of the catalyzed processes and the presence of short-term memory resulting from the preference of certain conformations. For arbitrarily complex stochastic dynamics of protein machines, we proved the generalized fluctuation theorem predicting the possibility of reducing free energy dissipation at the expense of creating some information stored in memory. That this may be the case has been shown by interpreting results of computer simulations for a complex model network of stochastic transitions. The subject of the analysis was the time course of the catalyzed processes expressed by sequences of jumps at random moments of time. Since similar signals can be registered in the observation of real systems, all theses of the paper are open to experimental verification.STATEMENT OF SIGNIFICANCEThe transient utilization of memory for storing information turns out to be crucial for the movement of protein motors and the reason for most protein machines to operate as dimers or higher organized assemblies. From a broader physical point of view, the division of free energy into the operation and organization energies is worth emphasizing. Information can be assigned a physical meaning of a change in the value of both these functions of state.

GROUNDWATER TIME SERIES

1970 ◽  
Vol 1 (3) ◽  
pp. 181-205 ◽  
Author(s):  
ERIK ERIKSSON
Keyword(s):  
Time Series ◽  
Point Of View ◽  
Hydrologic Models ◽  
Physical Point ◽  
Run Off ◽  
Fort Collins ◽  
Statistical Sense ◽  
Full Benefit ◽  
Future Work ◽  
Prediction Problems

The term “stochastic hydrology” implies a statistical approach to hydrologic problems as opposed to classic hydrology which can be considered deterministic in its approach. During the International Hydrology Symposium, held 6-8 September 1967 at Fort Collins, a number of hydrology papers were presented consisting to a large extent of studies on long records of hydrological elements such as river run-off, these being treated as time series in the statistical sense. This approach is, no doubt, of importance for future work especially in relation to prediction problems, and there seems to be no fundamental difficulty for introducing the stochastic concepts into various hydrologic models. There is, however, some developmental work required – not to speak of educational in respect to hydrologists – before the full benefit of the technique is obtained. The present paper is to some extent an exercise in the statistical study of hydrological time series – far from complete – and to some extent an effort to interpret certain features of such time series from a physical point of view. The material used is 30 years of groundwater level observations in an esker south of Uppsala, the observations being discussed recently by Hallgren & Sands-borg (1968).

scholarly journals On factors affecting surface free energy of carbon black for reinforcing rubber

2020 ◽  
Vol 9 (1) ◽  
pp. 170-181 ◽  
Author(s):  
Shangyong Zhang ◽  
Ruipeng Zhong ◽  
Ruoyu Hong ◽  
David Hui
Keyword(s):  
Free Energy ◽  
Carbon Black ◽  
Surface Free Energy ◽  
Surface Activity ◽  
Gas Flow ◽  
Influential Factors ◽  
Chromatographic Column ◽  
Factors Affecting ◽  
Carrier Gas Flow

AbstractThe surface activity of carbon black (CB) is an important factor affecting the reinforcement of rubber. The quantitative determination of the surface activity (surface free energy) of CB is of great significance. A simplified formula is obtained to determine the free energy of CB surface through theoretical analysis and mathematical derivation. The surface free energy for four kinds of industrial CBs were measured by inverse gas chromatography, and the influential factors were studied. The results showed that the aging time of the chromatographic column plays an important role in accurate measurement of the surface free energy of CB, in comparison with the influences from the inlet pressure and carrier gas flow rate of the chromatographic column filled with CB. Several kinds of industrial CB were treated at high temperature, and the surface free energy of CB had a significant increase. With the increase of surface free energy, the maximum torque was decreased significantly, the elongation at break tended to increase, the heat generation of vulcanizates was increased, and the wear resistance was decreased.

scholarly journals Boron Concentration Induced Co-Ta-B Composite Formation Observed in the Transition from Metallic to Covalent Glasses

2020 ◽  
Vol 5 (1) ◽  
pp. 18
Author(s):  
Simon Evertz ◽  
Stephan Prünte ◽  
Lena Patterer ◽  
Amalraj Marshal ◽  
Damian M. Holzapfel ◽  
...  
Keyword(s):  
Electronic Structure ◽  
Metallic Glasses ◽  
Boron Concentration ◽  
High Strength ◽  
Point Of View ◽  
Composite Formation ◽  
Structural Applications ◽  
Glassy Materials ◽  
Metallic Bonding ◽  
Composite Region

Due to their unique property combination of high strength and toughness, metallic glasses are promising materials for structural applications. As the behaviour of metallic glasses depends on the electronic structure which in turn is defined by chemical composition, we systematically investigate the influence of B concentration on glass transition, topology, magnetism, and bonding for B concentrations x = 2 to 92 at.% in the (Co6.8±3.9Ta)100−xBx system. From an electronic structure and coordination point of view, the B concentration range is divided into three regions: Below 39 ± 5 at.% B, the material is a metallic glass due to the dominance of metallic bonds. Above 69 ± 6 at.%, the presence of an icosahedra-like B network is observed. As the B concentration is increased above 39 ± 5 at.%, the B network evolves while the metallic coordination of the material decreases until the B concentration of 67 ± 5 at.% is reached. Hence, a composite is formed. It is evident that, based on the B concentration, the ratio of metallic bonding to icosahedral bonding in the composite can be controlled. It is proposed that, by tuning the coordination in the composite region, glassy materials with defined plasticity and processability can be designed.

scholarly journals Percolation and tortuosity in heart-like cells

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
R. Rabinovitch ◽  
Y. Biton ◽  
D. Braunstein ◽  
I. Aviram ◽  
R. Thieberger ◽  
...  
Keyword(s):  
Action Potential ◽  
Forest Fire ◽  
Sinus Node ◽  
Heart Tissue ◽  
Point Of View ◽  
Physical Point ◽  
Electrical Currents ◽  
Single Wave ◽  
Heart Arrhythmia ◽  
The One

AbstractIn the last several years, quite a few papers on the joint question of transport, tortuosity and percolation have appeared in the literature, dealing with passage of miscellaneous liquids or electrical currents in different media. However, these methods have not been applied to the passage of action potential in heart fibrosis (HF), which is crucial for problems of heart arrhythmia, especially of atrial tachycardia and fibrillation. In this work we address the HF problem from these aspects. A cellular automaton model is used to analyze percolation and transport of a distributed-fibrosis inflicted heart-like tissue. Although based on a rather simple mathematical model, it leads to several important outcomes: (1) It is shown that, for a single wave front (as the one emanated by the heart's sinus node), the percolation of heart-like matrices is exactly similar to the forest fire case. (2) It is shown that, on the average, the shape of the transport (a question not dealt with in relation to forest fire, and deals with the delay of action potential when passing a fibrotic tissue) behaves like a Gaussian. (3) Moreover, it is shown that close to the percolation threshold the parameters of this Gaussian behave in a critical way. From the physical point of view, these three results are an important contribution to the general percolation investigation. The relevance of our results to cardiological issues, specifically to the question of reentry initiation, are discussed and it is shown that: (A) Without an ectopic source and under a mere sinus node operation, no arrhythmia is generated, and (B) A sufficiently high refractory period could prevent some reentry mechanisms, even in partially fibrotic heart tissue.

scholarly journals Focal transformation, an imaging concept for signal restoration and noise removal

Geophysics ◽  
2006 ◽  
Vol 71 (6) ◽  
pp. A55-A59 ◽  
Author(s):  
A. J. Berkhout ◽  
D. J. Verschuur
Keyword(s):  
Input Data ◽  
Noise Removal ◽  
Point Of View ◽  
Data Interpolation ◽  
Signal Restoration ◽  
Physical Point ◽  
Seismic Processing ◽  
Promising Tool ◽  
Focal Area ◽  
Forward Operator

Interpolation of data beyond aliasing limits and removal of noise that occurs within the seismic bandwidth are still important problems in seismic processing. The focal transform is introduced as a promising tool in data interpolation and noise removal, allowing the incorporation of macroinformation about the involved wavefields. From a physical point of view, the principal action of the forward focal operator is removing the spatial phase of the signal content from the input data, and the inverse focal operator restores what the forward operator has removed. The strength of the method is that in the transformed domain, the focused signals at the focal area can be separated from the dispersed noise away from the focal area. Applications of particular interest in preprocessing are interpolation of missing offsets and reconstruction of signal beyond aliasing. The latter can be seen as the removal of aliasing noise.

Constitutive modeling for the mechanical behavior of rubber with filler particles

2021 ◽  
Author(s):  
Sankalp Gour ◽  
Deepu Kumar Singh ◽  
Deepak Kumar ◽  
Vinod Yadav
Keyword(s):  
Mechanical Properties ◽  
Carbon Black ◽  
Mechanical Behavior ◽  
Experimental Observation ◽  
Continuum Mechanics ◽  
Constitutive Modeling ◽  
Carbon Nanoparticles ◽  
Material Behavior ◽  
Experimental Results ◽  
Filler Particles

Abstract The present study deals with the constitutive modeling for the mechanical behavior of rubber with filler particles. An analytical model is developed to predict the mechanical properties of rubber with added filler particles based on experimental observation. To develop the same, a continuum mechanics-based hyperelasticity theory is utilized. The model is validated with the experimental results of the chloroprene and nitrile butadiene rubbers filled with different volume fractions of carbon black and carbon nanoparticles, respectively. The findings of the model agree well with the experimental results. In general, the developed model will be helpful to the materialist community working in characterizing the material behavior of tires and other rubber-like materials.

scholarly journals Comparison of Different Approaches to Predict the Performance of Pumps As Turbines (PATs)

Energies ◽  
2018 ◽  
Vol 11 (4) ◽  
pp. 1016 ◽  
Author(s):  
Mauro Venturini ◽  
Stefano Alvisi ◽  
Silvio Simani ◽  
Lucrezia Manservigi
Keyword(s):  
Simulation Model ◽  
Ad Hoc ◽  
Polynomial Regression ◽  
Point Of View ◽  
Box Model ◽  
Physical Point ◽  
Evolutionary Polynomial Regression ◽  
Box Models ◽  
Performance Curves ◽  
Physics Based Simulation

This paper deals with the comparison of different methods which can be used for the prediction of the performance curves of pumps as turbines (PATs). The considered approaches are four, i.e., one physics-based simulation model (“white box” model), two “gray box” models, which integrate theory on turbomachines with specific data correlations, and one “black box” model. More in detail, the modeling approaches are: (1) a physics-based simulation model developed by the same authors, which includes the equations for estimating head, power, and efficiency and uses loss coefficients and specific parameters; (2) a model developed by Derakhshan and Nourbakhsh, which first predicts the best efficiency point of a PAT and then reconstructs their complete characteristic curves by means of two ad hoc equations; (3) the prediction model developed by Singh and Nestmann, which predicts the complete turbine characteristics based on pump shape and size; (4) an Evolutionary Polynomial Regression model, which represents a data-driven hybrid scheme which can be used for identifying the explicit mathematical relationship between PAT and pump curves. All approaches are applied to literature data, relying on both pump and PAT performance curves of head, power, and efficiency over the entire range of operation. The experimental data were provided by Derakhshan and Nourbakhsh for four different turbomachines, working in both pump and PAT mode with specific speed values in the range 1.53–5.82. This paper provides a quantitative assessment of the predictions made by means of the considered approaches and also analyzes consistency from a physical point of view. Advantages and drawbacks of each method are also analyzed and discussed.

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