The Ultimate Properties of Simple Elastomers

1958 ◽  
Vol 31 (1) ◽  
pp. 19-26 ◽  
Author(s):  
A. M. Bueche

Abstract The ultimate properties of polymers are very poorly understood. A large mass of practical data is available but at present there seem to be no molecular theories for its correlation or for use as a guide in obtaining new data. In the following pages a theoretical approach to the ultimate properties of simple crosslinked elastomers will be described. The treatment will be limited to the tensile strength and ultimate elongation at temperatures high enough so that crystallinity and the viscous work during extension are negligible. The theory can be extended to cover compressive or shear strength with relatively little effort. The incorporation of the effects of viscosity and crystallinity will require somewhat more work. (After the completion of the major part of this work I learned that Prof. F. Bueche, University of Wyoming, has developed a somewhat similar theory for the tensile strength of viscous elastomers.)

1961 ◽  
Vol 34 (3) ◽  
pp. 897-909
Author(s):  
Thor L. Smith ◽  
Paul J. Stedry

Abstract A study was made previously of the temperature and strain rate dependence of the stress at break (tensile strength) and the ultimate elongation of an unfilled SBR rubber. In that study, stress-strain curves to the point of rupture were measured with an Instron tensile tester on ring type specimens at 14 temperatures between −67.8° and 93.3° C, and at 11 strain rates between 0.158×10−3 and 0.158 sec−1 at most temperatures. The tensile strength was found to increase with both increasing strain rate and decreasing temperature. At all temperatures above −34.4° C, the ultimate elongation was likewise found to increase with increasing strain rate and decreasing temperature but at lower temperatures the opposite dependence on rate was observed; at −34.4° C, the ultimate elongation passed through a maximum with increasing rate.


1964 ◽  
Vol 37 (4) ◽  
pp. 808-817 ◽  
Author(s):  
F. Bueche ◽  
J. C. Halpin

Abstract The tensile strength and ultimate elongation properties of any given amorphous elastomer can be described by a characteristic failure curve. It is shown in this paper that the failure curve can be predicted from a knowledge of the creep curve of the elastomer together with the data from a Mooney-Rivlin plot. The theory relating the ultimate properties to the viscoelastic properties of the elastomer is based upon the idea of a propagating crack, the rate of propagation being limited by viscoelastic mechanisms. Data for the failure curves and creep response for EPR and SBR elastomers are presented and shown to support the theory. Literature data for butyl rubber are also shown to confirm the theory.


1962 ◽  
Vol 35 (3) ◽  
pp. 753-775 ◽  
Author(s):  
Thor L. Smith ◽  
Alan B. Magnusson

Abstract The tensile strength and elongation at rupture of elastomers vary markedly with the experimental conditions used in measurement. For example, when measured at a fixed rate of extension, the tensile strength may increase by a factor of 100 or more as the temperature is decreased, and the ultimate elongation may increase concomitantly by a factor of 10 or more and then decrease to a few per cent. The ultimate properties also depend on the chemical nature of the network chains, the degree of crosslinking, and on the regularity of spacing of the crosslinking sites. In addition, those elastomers which crystallize during extension (e.g., vulcanized natural rubber) normally exhibit higher tensile strengths and ultimate elongations than those which do not crystallize (e.g., SBR rubbers). In seeking relationships between the structure and the ultimate properties of elastomers, these various factors which affect ultimate properties must be carefully considered. Previously a study was made of the tensile strength and ultimate elongation of several series of polyether-polyurethan elastomers prepared from polyoxypropylene glycol 2025 (PPG), trimethylolpropane (TMP), and either toluene 2,4-diisocyanate (TDI) or hexamethylene 1,6-diisocyanate (HDI). The structure of these elastomers was characterized by (1) the number of network chains per unit volume ν and (2) the concentration of urethan groups [U]. These parameters could be varied independently over certain ranges by making appropriate changes in the average molecular weight of PPG 2025 through blending it with dipropylene glycol (DPG). The glass temperature Tg of the elastomers increased linearly with [U], the rate of increase being considerably greater for the TDI-linked than for the HDI-linked elastomers. These elastomers apparently did not crystallize upon extension, and their ultimate properties, measured at a fixed extension rate, were found to depend on both [U] and ν. However, when compared in corresponding temperature states, i.e., at equal values of T−Tg, the ultimate properties over a wide temperature range were found to be independent of [U], or approximately so, when [U] was less than about 1.85 moles/kg. Also, the ultimate elongation was observed to be inversely proportional to ν, although the proportionality constant was temperature-dependent. It thus appears that certain elastomers which do not crystallize have ultimate properties which depend not only on ν and Tg but also on the chemical nature of the network chains.


Alloy Digest ◽  
1981 ◽  
Vol 30 (8) ◽  

Abstract CENTRI-CAST GRAY IRON 50 is a centrifugally cast gray iron with a nominal tensile strength of 50,000 psi. It is cast in the form of tubing which has a wide range of uses in applications where size and shape are of paramount importance and freedom from pattern cost is an important consideration. Among its many applications are farm machinery, seals, bushings, machine tools and general machinery uses. This datasheet provides information on composition, physical properties, microstructure, hardness, elasticity, tensile properties, and compressive and shear strength as well as fatigue. It also includes information on casting, heat treating, machining, and surface treatment. Filing Code: CI-51. Producer or source: Federal Bronze Products Inc..


Alloy Digest ◽  
1979 ◽  
Vol 28 (9) ◽  

Abstract CENTRI-CAST GRAY IRON 55 is a centrifugally cast gray iron with a nominal tensile strength of 55,000 psi. It is produced in the form of tubing which has a wide range of uses in applications where size and shape are of paramount importance and freedom from pattern cost is an important consideration. Typical applications are seals, bushings, farm machinery, casings and general machinery uses. This datasheet provides information on composition, physical properties, microstructure, hardness, elasticity, tensile properties, and compressive and shear strength as well as fatigue. It also includes information on casting, heat treating, machining, and surface treatment. Filing Code: CI-48. Producer or source: Federal Bronze Products Inc..


Author(s):  
Vijay Kumar Vishvakarma ◽  
Ramesh Chandra ◽  
Prashant Singh

: Fever is a response of human body due to an increase the temperature against the certain stimuli. It may be associated with several reasons and one of the major causes of fever is mosquito bite. Fever due to dengue virus (DENV) infection is being paid most attention out of several other fevers because of a large number of deaths reported worldwide. Dengue virus is transmitted by biting of the mosquitoes, Aedes aegypti and Aedes albopictus. DENV1, DENV2, DENV3 and DENV4 are the four serotypes of dengue virus and these serotypes have 65% similarities in their genomic structure. Genome of DENV is composed of single stranded RNA and it encodes for the polyprotein. Structural and non-structural proteins (nsP) are the two major part of protese. Researchers have paid high attention on the non-structural protease (nsP) of DENV like nsP1, nsP2A, nsP2B, nsP3, nsP4A, nsP4B and nsP5. The NS2B-NS3 protease of DENV is the prime target of the researchers as it is responsible for the catalytic activity. In the present time, Dengvaxia (vaccine) is being recommended to the patients suffering severely due to DENV infection in few countries only. Till date, neither a vaccine nor an effective medicine is available to combat with all four serotypes. This review describes the fever, its causes and studies to cure the infection due to DENV using theoretical and experimental approaches.


2010 ◽  
Vol 97-101 ◽  
pp. 814-817 ◽  
Author(s):  
Jun Deng

One of the greatest drawbacks to predicting the behaviour of bonded joints has been the lack of reliable data on the mechanical properties of adhesives. In this study, methods for determining mechanical properties of structural adhesive were discussed. The Young’s modulus, Poisson’s ratio and tensile strength of the adhesive were tested by dogbone specimens (bulk form) and butt joint specimens (in situ form). The shear modulus and shear strength were test by V-notched specimens (bulk form) and thick adherend lap-shear (TALS) joint specimens (in situ form). The test results show that the elastic modulus provided by the manufacturer is too low, the dogbone specimen is better than the butt joint specimen to test the tensile strength and elastic modulus and the TALS joint specimen is better than the V-notched specimen to test the shear strength.


2021 ◽  
Vol 15 (1) ◽  
pp. 81-92
Author(s):  
Constantinos B. Demakos ◽  
Constantinos C. Repapis ◽  
Dimitros P. Drivas

Aims: The aim of this paper is to investigate the influence of the volume fraction of fibres, the depth of the beam and the shear span-to-depth ratio on the shear strength of steel fibre reinforced concrete beams. Background: Concrete is a material widely used in structures, as it has high compressive strength and stiffness with low cost manufacturing. However, it presents low tensile strength and ductility. Therefore, through years various materials have been embedded inside it to improve its properties, one of which is steel fibres. Steel fibre reinforced concrete presents improved flexural, tensile, shear and torsional strength and post-cracking ductility. Objective: A better understanding of the shear performance of SFRC could lead to improved behaviour and higher safety of structures subject to high shear forces. Therefore, the influence of steel fibres on shear strength of reinforced concrete beams without transverse reinforcement is experimentally investigated. Methods: Eighteen concrete beams were constructed for this purpose and tested under monotonic four-point bending, six of which were made of plain concrete and twelve of SFRC. Two different aspect ratios of beams, steel fibres volume fractions and shear span-to-depth ratios were selected. Results: During the experimental tests, the ultimate loading, deformation at the mid-span, propagation of cracks and failure mode were detected. From the tests, it was shown that SFRC beams with high volume fractions of fibres exhibited an increased shear capacity. Conclusion: The addition of steel fibres resulted in a slight increase of the compressive strength and a significant increase in the tensile strength of concrete and shear resistance capacity of the beam. Moreover, these beams exhibit a more ductile behaviour. Empirical relations predicting the shear strength capacity of fibre reinforced concrete beams were revised and applied successfully to verify the experimental results obtained in this study.


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