Some Observations on the Flex-Cracking Characteristics of GR-S (BUNA-S) Compounds
Abstract Probably the most serious defect of GR-S rubber is its poor resistance to flex-cracking, and much research has been conducted in an effort to improve this characteristic. Among the many tests employed in the study of rubber is the bend-flexing method, using the De Mattia apparatus, as described in A.S.T.M. Method D430-35T. However, when GR-S vulcanizates were flexed according to the standard procedure, erratic results were obtained. In an effort to secure more reproducible test data, a study was made of the crack growth that proceeded from small nicks made initially in the surface of the sample. Some difficulty was encountered in making a nick of uniform dimensions until a procedure was developed whereby a pinhole about 0.025 inch in diameter and approximately 0.05 inch deep was made in the center of the grooved surface of the test-piece. The hole was made by a pointed piece of steel, shielded so that it could penetrate the sample only to a constant depth. When the samples were prepared in this manner, the crack growth which extended from the hole during flexing was fairly uniform, and the results were reproducible within rather close limits.