A New Hydrocarbon Elastomer. II. Properties of an Ethylene-Propylene-Nonconjugated Diene Terpolymer
Abstract A new hydrocarbon elastomer has been synthesized from petrochemical intermediates using coordination catalysis. This amorphous polymer resembles commercial diene elastomers in general appearance, is completely soluble in hydrocarbon and chlorinated hydrocarbon solvents, and is stable to prolonged storage. It can be vulcanized effectively by the use of accelerated sulfur systems and reinforced by numerous fillers such as carbon blacks, clays, and certain silicas. Reinforced vulcanizates are strong, resilient, and extremely resistant to oxygen, ozone, heat, light, and many chemical agents. Properly compounded vulcanizates exhibit excellent electrical and low temperature properties. Permeability to gases, specifically nitrogen, oxygen, and carbon dioxide, parallels natural rubber. Thermal diffusivity and thermal conductivity are ∼15% greater than polyisoprene. The practical significance of the thermal data remains to be determined.