The Law of Absorption of Carbon Dioxide by Rubber as a Function of the Time
Abstract 1. As the form of the curves shows, factice does not appear to obey the law for rubber. Calculations give values which, in relation to the observed values, show deviations of 8.5 per cent for brown factice and 13.7 per cent for white factice, whereas Table I gives smaller deviations for the different rubbers. 2. Crude rubber absorbs more than the same rubber cut into pieces, which indicates that the latter has become less porous. The absorption measurements can therefore give an idea of the porosity. It is a curious fact that if crude or cut-up rubber is boiled with alcohol the same value for the coefficient of absorption is obtained. 3. Vulcanized rubber or rubber mixed with mineral or organic fillers absorbs carbon dioxide in the same way. 4. Although Reychler has assumed that carbon dioxide dissolves in rubber, it should be noted that the law of the phenomenon of absorption is identical to that of monomolecular chemical combination. Might there not be formed therefore a compound with one of the components of the rubber? In any case, it is extremely difficult to remove the carbon dioxide from rubber, even after subjecting it to a vacuum for a long time. Moreover, if successive experiments are repeated on a single sample, it is found that the coefficients of absorption become smaller and smaller. This indicates that more and more carbon dioxide remains in the rubber. The coefficient of absorption for plantation rubber at the end of four tests changed from 0.165 to 0.141 and did not regain its value at the end of 50 days' standing. Upon washing the rubber at this stage, traces of carbon dioxide were detected in the wash water by means of lime water. 5. The study of the k coefficients, which may be called diffusion coefficients, likewise gives information about a rubber. 6. A sample left for one whole day in carbon dioxide did not appear to have altered, as judged by its elongation and tensile strength. 7. Without desiring to draw any definite conclusions from this work, it is believed that more complete tests such as those described would doubtless be of value in obtaining information about the constitution or the quality of different rubbers.