The Application of Small Angle Neutron Scattering to Elastomers

1994 ◽  
Vol 67 (3) ◽  
pp. 367-383 ◽  
Author(s):  
David J. Lohse

Abstract The last twenty years have seen a dramatic increase in the application of small angle neutron scattering to polymer science. In this review the use of SANS to study elastomers and elastomeric systems has been summarized. This has focused on those applications most significant to the understanding of rubber. These have included the dimensions of polymer chains in the bulk melt state, the miscibility of polymer blends, the structure of block copolymers, and the nature of crosslinked networks. The information that has been obtained so far has cleared up many of the outstanding questions about elastomers, and one can only expect that this use will increase in the future and will yield a wealth of useful information.

1981 ◽  
Vol 19 (7) ◽  
pp. 1019-1031 ◽  
Author(s):  
L. Ionescu ◽  
C. Picot ◽  
M. Duval ◽  
R. Duplessix ◽  
H. Benoit ◽  
...  

1997 ◽  
Vol 234-236 ◽  
pp. 240-241 ◽  
Author(s):  
J. Caspar ◽  
B. Dünges ◽  
R.G. Kirste ◽  
T. Heitz ◽  
A. Wiedenmann

1989 ◽  
Vol 166 ◽  
Author(s):  
Alan I. Nakatani ◽  
Hongdoo Kim ◽  
Charles C. Han

ABSTRACTThe phase behavior of polymer blends and solutions can be changed dramatically by a flow field using a variety of flow geometries. Unlike simple binary fluids which require extremely high shear rates to produce only small shifts in the phase boundary, polymer phase behavior may be influenced by as much as 10 degrees with the application of much lower shear rates. However, there is a large body of conflicting data concerning the nature of these shear effects in polymers.Here we report on the effects of shear on the phase behavior of polymer blends by small angle neutron scattering (SANS). Experiments were conducted using a specially constructed, concentric cylinder apparatus for in situ studies of concentrated polymer solutions and melts. Two separate systems will be discussed: 1) a blend of polystyrene and polybutadiene. 2) a blend of polystyrene and poly(vinylmethylether). Both systems exhibit shifts in the phase behavior which indicate shear induced mixing in agreement with previous results obtained by other techniques. These results will be interpreted within the context of existing theories of shear induced phase behavior.


2008 ◽  
Vol 41 (2) ◽  
pp. 471-477 ◽  
Author(s):  
Nisita S. Wanakule ◽  
Alisyn J. Nedoma ◽  
Megan L. Robertson ◽  
Zhuangxi Fang ◽  
Andrew Jackson ◽  
...  

1999 ◽  
Vol 60 (8-9) ◽  
pp. 1307-1312 ◽  
Author(s):  
H Hasegawa ◽  
N Sakamoto ◽  
H Takeno ◽  
H Jinnai ◽  
T Hashimoto ◽  
...  

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