Metathesis Polycondensation Chemistry as a Route to Unsaturated Elastomers

K. B. Wagener; J. G. Nel; R. P. Duttweiler; M. A. Hillmyer; J. M. Boncella; J. Konzelman; D. W. Smith; R. Puts; L. Willoughby

doi:10.5254/1.3538543

Metathesis Polycondensation Chemistry as a Route to Unsaturated Elastomers

Rubber Chemistry and Technology ◽

10.5254/1.3538543 ◽

1991 ◽

Vol 64 (1) ◽

pp. 83-95 ◽

Cited By ~ 12

Author(s):

K. B. Wagener ◽

J. G. Nel ◽

R. P. Duttweiler ◽

M. A. Hillmyer ◽

J. M. Boncella ◽

...

Keyword(s):

Room Temperature ◽

Temperature Reaction ◽

Acyclic Diene Metathesis ◽

Elastic Structures ◽

Reaction Conditions ◽

Admet Polymerization ◽

Diene Metathesis

Abstract Acyclic diene metathesis (ADMET) polymerization offers a new opportunity to generate a wide variety of elastic structures using room temperature reaction conditions. It also offers the opportunity to modify existing elastomer structures through trans-metathesis copolymerization reactions. ADMET depolymerization could have tremendous significance if, in fact, the reaction can be applied to the recovery of commercial vulcanized elastomers. All of these opportunities are presently being investigated in our laboratory.

Download Full-text

Acyclic Diene Metathesis (ADMET) Polymerization by Electrochemically Generated Tungsten-Based Active Catalyst System: Optimization of Reaction Conditions

Novel Metathesis Chemistry: Well-Defined Initiator Systems for Specialty Chemical Synthesis, Tailored Polymers and Advanced Material Applications ◽

10.1007/978-94-010-0066-6_20 ◽

2003 ◽

pp. 243-247

Author(s):

O. Derelİ ◽

B. Düz ◽

Y. İmamoğlu

Keyword(s):

Active Catalyst ◽

System Optimization ◽

Catalyst System ◽

Acyclic Diene Metathesis ◽

Reaction Conditions ◽

Admet Polymerization ◽

Diene Metathesis

Download Full-text

Regio-regular poly(thienylene vinylene)s (rr-PTVs) through acyclic diene metathesis (ADMET) polymerization and the impact of alkyl side-chains on polymer molecular weight and solubility

Polymer ◽

10.1016/j.polymer.2021.124150 ◽

2021 ◽

Vol 231 ◽

pp. 124150

Author(s):

Yousef M. Katba-Bader ◽

Lingyao Meng ◽

Chao Guan ◽

Yang Qin

Keyword(s):

Molecular Weight ◽

Side Chains ◽

Acyclic Diene Metathesis ◽

Polymer Molecular Weight ◽

Admet Polymerization ◽

Alkyl Side Chains ◽

Diene Metathesis ◽

The Impact

Download Full-text

Synthesis of All-Trans High Molecular Weight Poly(N-alkylcarbazole-2,7-vinylene)s and Poly(9,9-dialkylfluorene-2,7-vinylene)s by Acyclic Diene Metathesis (ADMET) Polymerization Using Ruthenium−Carbene Complex Catalysts

Macromolecules ◽

10.1021/ma900775x ◽

2009 ◽

Vol 42 (14) ◽

pp. 5104-5111 ◽

Cited By ~ 48

Author(s):

Nobuhiro Yamamoto ◽

Ryusuke Ito ◽

Yves Geerts ◽

Kotohiro Nomura

Keyword(s):

Molecular Weight ◽

High Molecular Weight ◽

Acyclic Diene Metathesis ◽

Carbene Complex ◽

Admet Polymerization ◽

Diene Metathesis ◽

High Molecular Weight Poly

Download Full-text

Functional α,ω-dienes via thiol-Michael chemistry: synthesis, oxidative protection, acyclic diene metathesis (ADMET) polymerization and radical thiol–ene modification

Polymer Chemistry ◽

10.1039/c4py00783b ◽

2014 ◽

Vol 5 (21) ◽

pp. 6225-6235 ◽

Cited By ~ 18

Author(s):

Johannes A. van Hensbergen ◽

Taylor W. Gaines ◽

Kenneth B. Wagener ◽

Robert P. Burford ◽

Andrew B. Lowe

Keyword(s):

The Novel ◽

Acyclic Diene Metathesis ◽

Admet Polymerization ◽

Oxidative Protection ◽

Diene Metathesis

The synthesis of the novel α,ω-diene 2-(undec-10-en-1-yl)tridec-12-en-1-yl acrylate is described.

Download Full-text

Acyclic diene metathesis (ADMET) polymerization

Macromolecules ◽

10.1021/ma00010a001 ◽

1991 ◽

Vol 24 (10) ◽

pp. 2649-2657 ◽

Cited By ~ 129

Author(s):

K. B. Wagener ◽

J. M. Boncella ◽

J. G. Nel

Keyword(s):

Acyclic Diene Metathesis ◽

Admet Polymerization ◽

Diene Metathesis

Download Full-text

Structure-Reactivity Relationships in Acyclic Diene Metathesis (ADMET) Polymerization

Progress in Pacific Polymer Science 3 ◽

10.1007/978-3-642-78759-1_18 ◽

1994 ◽

pp. 217-224

Author(s):

K. B. Wagener

Keyword(s):

Acyclic Diene Metathesis ◽

Admet Polymerization ◽

Diene Metathesis

Download Full-text

Acyclic diene metathesis (ADMET) polymerization of allyl undec-10-enoate and some related esters

Journal of Organometallic Chemistry ◽

10.1016/j.jorganchem.2006.09.020 ◽

2006 ◽

Vol 691 (24-25) ◽

pp. 5431-5437 ◽

Cited By ~ 11

Author(s):

Andrew J. Hall ◽

Philip Hodge ◽

Stephen D. Kamau ◽

Abderrakak Ben-Haida

Keyword(s):

Acyclic Diene Metathesis ◽

Admet Polymerization ◽

Diene Metathesis

Download Full-text

Acyclic Diene Metathesis (ADMET) Polymerization

Synthesis of Polymers ◽

10.1002/9783527619313.ch4 ◽

2008 ◽

pp. 105-122

Author(s):

Tammy A. Davidson ◽

Kenneth B. Wagener

Keyword(s):

Acyclic Diene Metathesis ◽

Admet Polymerization ◽

Diene Metathesis

Download Full-text

Catalytic One-Pot Synthesis of End-Functionalized Poly(9,9′-di-n-octylfluorenevinylene)s by Acyclic Diene Metathesis (ADMET) Polymerization Using Ruthenium–Carbene Catalysts

Macromolecules ◽

10.1021/acs.macromol.5b02287 ◽

2016 ◽

Vol 49 (2) ◽

pp. 518-526 ◽

Cited By ~ 18

Author(s):

Tomonari Miyashita ◽

Kotohiro Nomura

Keyword(s):

Acyclic Diene Metathesis ◽

One Pot ◽

Admet Polymerization ◽

One Pot Synthesis ◽

Diene Metathesis

Download Full-text

Acyclic diene metathesis (ADMET) polymerization. Design and synthesis of unsaturated poly(carbosiloxanes)

Macromolecules ◽

10.1021/ma00059a022 ◽

1993 ◽

Vol 26 (7) ◽

pp. 1633-1642 ◽

Cited By ~ 45

Author(s):

D. W. Smith ◽

K. B. Wagener

Keyword(s):

Acyclic Diene Metathesis ◽

Admet Polymerization ◽

Design And Synthesis ◽

Diene Metathesis

Download Full-text