The Effect of Bis(3-Triethoxysilylpropyl) Tetrasulfide on Silica Reinforcement of Styrene-Butadiene Rubber

1998 ◽  
Vol 71 (2) ◽  
pp. 289-299 ◽  
Author(s):  
A. S. Hashim ◽  
B. Azahari ◽  
Y. Ikeda ◽  
S. Kohjiya
Keyword(s):  
Fine Particles ◽  
Sol Gel ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Mechanical Mixing ◽  
Transmission Electron ◽  
Curing Characteristics ◽  
Sol Gel Process ◽  
Styrene Butadiene

Abstract Bis(3-triethoxysilylpropyl)tetrasulfide (TESPT) was found to affect the curing characteristics and the physical properties of styrene-butadiene (SBR) gum rubber and xin situ silica-filled SBR vulcanizates. Silica incorporated by the in situ sol-gel reaction of tetraethoxysilane with TESPT showed a much higher reinforcing efficiency than did conventional mechanical mixing and the in situ method without TESPT. The higher reinforcing efficiency is attributed to the formation of a silica-rubber network, which also changed the dynamic mechanical behavior of the SBR vulcanizates. Transmission electron microscopy observations showed in situ silica incorporation of very fine particles in comparison to the sol-gel process without TESPT.

In situsilica reinforcement of vinyltriethoxysilane-grafted styrene-butadiene rubber by sol-gel process

2012 ◽  
Vol 128 (4) ◽  
pp. 2262-2268 ◽  
Author(s):  
Changjie Yin ◽  
Qiuyu Zhang ◽  
Junwei Gu ◽  
Jucheng Zheng ◽  
Guangbi Gong ◽  
...  
Keyword(s):  
Sol Gel ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Sol Gel Process ◽  
Styrene Butadiene

scholarly journals Effects of octamethylcyclotetrasiloxane grafting and in situ silica particle generation on the curing and mechanical properties of a styrene butadiene rubber composite

RSC Advances ◽  
2019 ◽  
Vol 9 (59) ◽  
pp. 34330-34341 ◽  
Author(s):  
Changjie Yin ◽  
Qiuyu Zhang
Keyword(s):  
Mechanical Properties ◽  
Silica Particle ◽  
Sol Gel ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Particle Generation ◽  
In Situ Silica ◽  
Rubber Composite ◽  
Styrene Butadiene

The reinforcement of octamethylcyclotetrasiloxane (D4) grafted styrene butadiene rubber (SBR-g-D4) with in situ generated silica was performed using the sol–gel reaction of tetraethoxysilane (TEOS) in latex.

Improvement of mechanical performance of solution styrene butadiene rubber by controlling the concentration and the size of in situ derived sol–gel silica particles

RSC Advances ◽  
2016 ◽  
Vol 6 (40) ◽  
pp. 33643-33655 ◽  
Author(s):  
V. Sankar Raman ◽  
A. Das ◽  
K. W. Stöckelhuber ◽  
S. B. Eshwaran ◽  
J. Chanda ◽  
...  
Keyword(s):  
Mechanical Performance ◽  
Sol Gel ◽  
Silica Particles ◽  
Polymer Chains ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Styrene Butadiene ◽  
Elastomeric Composites ◽  
Alkoxide Route

The silica particles generated from alkoxide route are grown onto the styrene butadiene polymer chains and offer a direct rubber to filler interaction. As a result, superior mechanical performance of the elastomeric composites can be realised.

In Situ Silica Reinforcement of Styrene-Butadiene Rubber by Sol-Gel Method, 1.

1994 ◽  
Vol 67 (12) ◽  
pp. 859-861 ◽  
Author(s):  
Shinzo KOHJIYA ◽  
Aiko YAJIMA ◽  
Jae Ryong YOON ◽  
Yuko IKEDA
Keyword(s):  
Sol Gel ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Gel Method ◽  
Sol Gel Method ◽  
In Situ Silica ◽  
Styrene Butadiene

scholarly journals Reinforcement of styrene-butadiene rubber by sol-gel process in the latex.

1996 ◽  
Vol 69 (7) ◽  
pp. 485-490 ◽  
Author(s):  
Kazumasa YOSHIKAI ◽  
Masahiro YAMAGUCHI ◽  
Katsumi NISHIMURA
Keyword(s):  
Sol Gel ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Sol Gel Process ◽  
Styrene Butadiene

scholarly journals Synthesis of Modified Styrene-Butadiene Rubber Latex Containing Triethoxysilyl Group and Its in situ Silica Filling

2003 ◽  
Vol 76 (7) ◽  
pp. 234-239 ◽  
Author(s):  
Kiyoshi SUNADA ◽  
Hiroki TAKESHITA ◽  
Masamitsu MIYA ◽  
Tsukasa NAKAMURA ◽  
Katsuhiko TAKENAKA ◽  
...  
Keyword(s):  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Rubber Latex ◽  
In Situ Silica ◽  
Styrene Butadiene
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