Biaxial Extension Studies Using Inflation of Sheets of Unimodal Model Networks
1990 ◽
Vol 63
(2)
◽
pp. 276-284
◽
Keyword(s):
Abstract Measurements of uniaxial extension and compression were made on model poly(dimethylsiloxane) (PDMS) [−Si(CH3)2−O−]x networks to examine the molecular theories of rubber elasticity. The stress-strain isotherms showed that the Flory-Erman theory of rubber elasticity is in good agreement with experimental data from extension to compression (α−1: 0.3–13), while the Mooney-Rivlin relation is useful only in a specific region of extension ratio (α−1: 0.3–0.8). The experimental results strongly support the theory of Flory-Erman, rather than those of phantom and affine networks. It is thus evident that the Flory-Erman theory of rubber elasticity is the more nearly correct.
Keyword(s):
Keyword(s):
1972 ◽
Vol 328
(1575)
◽
pp. 529-539
◽
2011 ◽
Vol 110-116
◽
pp. 3453-3458
Keyword(s):
Keyword(s):