Rubber-Thermoplastic Compositions. Part VII. Chlorinated Polyethylene Rubber-Nylon Compositions

1983 ◽  
Vol 56 (1) ◽  
pp. 210-225 ◽  
Author(s):  
A. Y. Coran ◽  
R. Patel
Keyword(s):  
High Strength ◽  
Fiber Composites ◽  
Short Fiber ◽  
Thermoplastic Elastomers ◽  
Chemical Bonds ◽  
Dynamic Vulcanization ◽  
Chlorinated Polyethylene ◽  
Vulcanized Rubber ◽  
High Integrity

Abstract Nylon resins and CPE rubber can be melt-blended to give compositions which have useful properties. If the rubber is cured by dynamic vulcanization, high strength oil resistant thermoplastic elastomers result. Cold milling of melt-mixed compositions results in nylon-reinforced rubber which can be mixed with curatives and press cured or statically vulcanized to give reinforced rubber compositions which resemble vulcanized rubber-short fiber composites. The reason for the high integrity of either the statically or the dynamically vulcanized composition appears to be that chemical bonds form between the rubber and plastic.

High Strength - Low Hardness Thermoplastic Elastomers from Ethylene-Butene Copolymers and Low Density Polyethylene

2008 ◽  
Vol 81 (1) ◽  
pp. 60-76 ◽  
Author(s):  
Sandeep Tembhekar ◽  
Madhuchhanda Maiti ◽  
Jinu Jacob George ◽  
Anjan Biswas ◽  
Anil K. Bhowmick ◽  
...  
Keyword(s):  
Elevated Temperature ◽  
Functional Performance ◽  
High Strength ◽  
Thermoplastic Elastomer ◽  
Ethylene Vinyl Acetate ◽  
Thermoplastic Elastomers ◽  
Low Density Polyethylene ◽  
Low Density ◽  
Vulcanized Rubber ◽  
Rubbery Material

Abstract A thermoplastic elastomer (TPE) is a rubbery material with final properties and functional performance similar to those of a conventional vulcanized rubber at ambient temperature, yet it can be processed as a thermoplastic at elevated temperature. The main objective of the present investigation was to prepare novel olefinic thermoplastic elastomers based on blends of a thermoplastic i.e. low density polyethylene (PE) and new ethylene-butene copolymers (PEB), which would have higher strength and lower hardness compared to the existing TPEs. The 70:30 PEB: PE blend exhibited the best properties. Ethylene vinyl acetate was found to work as compatibilizer at lower loadings in these blends. The resultant blends were of low hardness (60–80 Shore A) and high strength (26–33 MPa). The interaction parameter and the morphology of the blends were the key parameters, which governed the final properties of blends.

Novel Styrenic Thermoplastic Elastomers from Blends with Special Reference to Compatibilization and Dynamic Vulcanization

2005 ◽  
Vol 78 (5) ◽  
pp. 893-909 ◽  
Author(s):  
J. D. Patel ◽  
M. Maiti ◽  
K. Naskar ◽  
Anil K. Bhowmick
Keyword(s):  
Special Reference ◽  
Interaction Parameter ◽  
Functional Performance ◽  
Thermoplastic Elastomer ◽  
Thermoplastic Elastomers ◽  
Dynamic Vulcanization ◽  
Vulcanized Rubber ◽  
Styrene Acrylonitrile ◽  
Modified Polystyrene ◽  
Styrene Butadiene

Abstract A thermoplastic elastomer (TPE) is a rubbery material with final properties and functional performance similar to those of a conventional vulcanized rubber at ambient temperature, yet it can be processed in a molten condition as a thermoplastic polymer at elevated temperature. The main objectives of the present investigation are: to prepare novel styrenic-based thermoplastic elastomers based on blends of a thermoplastic (polystyrene or styrene acrylonitrile) with a rubber (styrene butadiene or ethylene vinylacetate) and to investigate the interaction between various polymers with special reference to compatibilization via oxazoline-modified polystyrene or oxazoline-modified styrene acrylonitrile and dynamic vulcanization. Styrene acrylonitrile/ethylene vinylacetate blends are found to exhibit better overall properties, especially tensile strength, elongation at break and tension set. The solubility or interaction parameter and the morphology of the blends are the key parameters, which basically govern the final properties of blends. Physical properties of these blends have been correlated with the interaction parameter and final morphology.

Characterization of orientation clustering in short-fiber composites

1990 ◽  
Vol 28 (13) ◽  
pp. 2651-2672 ◽  
Author(s):  
Sridhar Ranganathan ◽  
Suresh G. Advani
Keyword(s):  
Fiber Composites ◽  
Short Fiber

EXPERIMENTAL STUDY ON THE CO2 LASER CUTTING OF NOVEL POLYAMIDE 6/FLUOROELASTOMER THERMOPLASTIC ELASTOMERIC BLENDS

2015 ◽  
Vol 88 (1) ◽  
pp. 125-137 ◽  
Author(s):  
Shib Shankar Banerjee ◽  
Anil K. Bhowmick
Keyword(s):  
Low Power ◽  
Co2 Laser ◽  
Process Parameters ◽  
Laser Power ◽  
Laser Cutting ◽  
Manufacturing Industry ◽  
Cutting Speed ◽  
Polyamide 6 ◽  
Thermoplastic Elastomers ◽  
Dynamic Vulcanization

ABSTRACT The application of the low-power CO2 laser-cutting process to fluoroelastomer (FKM), polyamide 6 (PA6), PA6/FKM thermoplastic elastomers (TPEs), and their thermoplastic vulcanizate (TPV) is reported. The main laser process parameters studied were laser power, cutting speed, and material thickness. The value of the top and bottom widths of the slit that were formed during laser cutting (kerf width), melted transverse area, and melted volume per unit time were measured and analyzed. Interestingly, TPE showed a smaller melted area and melted volume per unit time when compared with those values with PA6. Dynamic vulcanization further decreased these values. For example, the melted areas of PA6 and TPE were 510 × 10−3 mm2 and 305 × 10−3 mm2, respectively, which reduced to 238 × 10−3 mm2 for TPV at 40 W laser power. FKM showed the lowest value (melted area of 180 × 10−3 mm2). In addition, the output quality of the cut surface was examined by measuring the root mean square (RMS) roughness of the cut edges and heat-affected zone (HAZ). The obtained results indicated that the dimension of the HAZ and RMS roughness largely decreased in TPE when compared with PA6. For example, the HAZ of PA6 was 700 μm, which decreased to 230 μm for TPE at 40 W laser power. On the other hand, HAZ was nonexistent for FKM. Infrared spectroscopic analysis showed that there was no structural change of TPE or pristine polymers after applying the low-power CO2 laser on the surface of materials. CO2 laser cutting will be a new technique in this industry, and this analysis will assist the manufacturing industry to choose a suitable laser system with exhaustive information of process parameters for cutting or machining of rubber, TPEs, and TPVs.

Thermal Decomposition of Vulcanized Structures of Deformed Vulcanizates Containing Various Accelerators

1953 ◽  
Vol 26 (4) ◽  
pp. 759-763 ◽  
Author(s):  
B. Dogadkin ◽  
Z. Tarasova
Keyword(s):  
Stress Relaxation ◽  
Physical And Mechanical Properties ◽  
Heat Stability ◽  
Chemical Bonds ◽  
Structural Elements ◽  
Specific Chemical ◽  
Vulcanized Rubber ◽  
Different Temperatures ◽  
Chemical Groups ◽  
The Given

Abstract According to the hypotheses developed by the authors, vulcanized rubber is a system in which the molecular chains are united by local molecular and chemical bonds of varying intensity. The concentration, distribution, and strength of these bonds determine the principal physical and mechanical properties of the vulcanizates. Consequently the study of the structure of the vulcanizate is of primary practical value. The explanation of the nature of the bonds in a vulcanizate by chemical methods is very difficult, mainly because of the impossibility of distinguishing the specific chemical groups which enter into the composition of the different molecular chains from those bonds between the chains which are responsible for the development of spatial structures. From this view point, the thermo-mechanical method described below, which is based on the study of stress relaxation at different temperatures, is of great significance. As was shown by Dogadkin and Reznikovskii˘, the delayed stress relaxation in a vulcanizate at temperatures up to 70° C is caused by rupture of the local intermolecular bonds and the regrouping of the structural elements of the polymeric chains without destruction of the chemical bonds between them. Accordingly, after some time at these temperatures, a practically balanced stress is established, which depends on the number of the stronger bonds remaining. At temperatures above 70° C, rupture of the chemical bonds between the chains takes place; its speed increases with decrease of the energy activating the rupture of the given type of bond. Particularly in the case of sulfur vulcanizates, we can assume that the following types of bonds exist between the chains of the rubber: (1) —C—C—, which develop as a result of the polymerizationprocesses; (2) —C—S—C— monosulfide; (3) —C—S—S—C— disulfide, and (4) —C—Sn—C— polysulfide, formed as a result of the direct participation of the vulcanizing agent, sulfur, in the process of joining of the molecular chains. The energy of these chains can be estimated as 62.7 kcal, per mole for C—C, 54.5 kcal. per mole for C—S, and 27.5 kcal. per mole for the —S—S bond. Naturally, the heat stability of a vulcanizate will depend on which of the indicated types of bonds predominates.

The thermal conductivity of short-fiber composites

1990 ◽  
Vol 24 (4) ◽  
pp. 405-411
Author(s):  
L. Cao ◽  
B. Wang ◽  
D.F. Wang ◽  
C.K. Yao
Keyword(s):  
Thermal Conductivity ◽  
Fiber Composites ◽  
Short Fiber
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