Pulsed NMR for Molecular Structure Analysis of EPDM

1989 ◽  
Vol 62 (4) ◽  
pp. 643-655
Author(s):  
Richard W. Tomlinson ◽  
Daniel F. Sheridan
Keyword(s):  
Tensile Strength ◽  
Relaxation Times ◽  
Operating Conditions ◽  
Test Method ◽  
Major Contributor ◽  
Nmr Analysis ◽  
Pulsed Nmr ◽  
Molecular Structure Analysis ◽  
Separate Calibration ◽  
Comparison Data

Abstract The use of pulsed NMR analysis under proper operating conditions has proven to be useful for controlling various polymer compositions in the manufacture of EPDM. It can be used in determining the amount of oil incorporated into oil-extended EPDMs. At higher oil contents, the differences in EPDM properties will affect this test method, which will require a separate calibration curve for each type of polymer. It can be used to measure the propylene content of EPDM. Comparison data have shown that this technique is more accurate in predicting crystallinity or propylene content than the standard IR method within the propylene range of 22 to 41%. Pulsed NMR can also be used to predict uncured EPDM compound tensile strength and EPDM/PP compression-molded tensile strength. Since these properties are affected by the crystallinity of EPDM, of which percent ethylene is the major contributor, then tensile strength can be determined indirectly. Based on the tensile and SER correlation, it seems obvious that this technique is measuring the spin-spin relaxation times of the crystalline phase, whereas the ir method is only measuring propylene content.

Investigations of Road Wear Caused by Studded Tires

2014 ◽  
Vol 42 (1) ◽  
pp. 2-15
Author(s):  
Johannes Gültlinger ◽  
Frank Gauterin ◽  
Christian Brandau ◽  
Jan Schlittenhard ◽  
Burkhard Wies
Keyword(s):  
Traffic Safety ◽  
Test Bench ◽  
Operating Conditions ◽  
Test Method ◽  
Analytical Models ◽  
The Road ◽  
Driving Speed ◽  
Major Factors ◽  
Tire Friction ◽  
Variable Operating Conditions

ABSTRACT The use of studded tires has been a subject of controversy from the time they came into market. While studded tires contribute to traffic safety under severe winter conditions by increasing tire friction on icy roads, they also cause damage to the road surface when running on bare roads. Consequently, one of the main challenges in studded tire development is to reduce road wear while still ensuring a good grip on ice. Therefore, a research project was initiated to gain understanding about the mechanisms and influencing parameters involved in road wear by studded tires. A test method using the institute's internal drum test bench was developed. Furthermore, mechanisms causing road wear by studded tires were derived from basic analytical models. These mechanisms were used to identify the main parameters influencing road wear by studded tires. Using experimental results obtained with the test method developed, the expected influences were verified. Vehicle driving speed and stud mass were found to be major factors influencing road wear. This can be explained by the stud impact as a dominant mechanism. By means of the test method presented, quantified and comparable data for road wear caused by studded tires under controllable conditions can be obtained. The mechanisms allow predicting the influence of tire construction and variable operating conditions on road wear.

scholarly journals Comprehensive Parameters Identification and Dynamic Model Validation of Interior-Mount Line-Start Permanent Magnet Synchronous Motors

Machines ◽  
2019 ◽  
Vol 7 (1) ◽  
pp. 4 ◽  
Author(s):  
Luqman S. Maraaba ◽  
Zakariya M. Al-Hamouz ◽  
Abdulaziz S. Milhem ◽  
Ssennoga Twaha
Keyword(s):  
Mathematical Model ◽  
Permanent Magnet ◽  
High Efficiency ◽  
Experimental Tests ◽  
Induction Machines ◽  
Test Methods ◽  
Operating Conditions ◽  
Test Method ◽  
Permanent Magnet Synchronous Motors ◽  
Synchronous Motors

The application of line-start permanent magnet synchronous motors (LSPMSMs) is rapidly spreading due to their advantages of high efficiency, high operational power factor, being self-starting, rendering them as highly needed in many applications in recent years. Although there have been standard methods for the identification of parameters of synchronous and induction machines, most of them do not apply to LSPMSMs. This paper presents a study and analysis of different parameter identification methods for interior mount LSPMSM. Experimental tests have been performed in the laboratory on a 1-hp interior mount LSPMSM. The measurements have been validated by investigating the performance of the machine under different operating conditions using a developed qd0 mathematical model and an experimental setup. The dynamic and steady-state performance analyses have been performed using the determined parameters. It is found that the experimental results are close to the mathematical model results, confirming the accuracy of the studied test methods. Therefore, the output of this study will help in selecting the proper test method for LSPMSM.

scholarly journals Dynamic Fracture Toughness and Dynamic Tensile Strength of the Rock from Different Depths of Beijing Datai Well

2018 ◽  
Vol 2018 ◽  
pp. 1-8 ◽  
Author(s):  
Ke Man ◽  
Xiaoli Liu
Keyword(s):  
Fracture Toughness ◽  
Tensile Strength ◽  
Dynamic Fracture ◽  
Empirical Relation ◽  
Dynamic Fracture Toughness ◽  
Rock Failure ◽  
Test Method ◽  
Strength Increase ◽  
Dynamic Tensile Strength ◽  
Different Depths

From the standard test method suggested by ISRM and GB/T50266-2013, the uniaxial static tensile strength, dynamic tensile strength, and dynamic fracture toughness of the same basalt at different depths have been measured, respectively. It is observed that there may be an empirical relation between dynamic fracture toughness and dynamic tensile strength. The testing data show that both the dynamic fracture toughness and dynamic tensile strength increase with the loading rate and the dynamic tensile strength increases a little bit more quickly than the dynamic fracture toughness. With an increasing depth, the dynamic tensile strength has much more influence on the dynamic fracture toughness, as which it is much liable to bring out the unexpected catastrophes in the engineering projects, especially during the excavation at deep mining. From the rock failure mechanisms, it is pointed out that the essential reason of the rock failure is the microcrack unstable propagation. The crack processes growth, propagation, and coalescence are induced by tensile stress, not shear stress or compressive stress. The paper provides estimation of the dynamic fracture toughness from the dynamic tensile strength value, which can be measured more easily.

scholarly journals Characterization of 3-Dimensional Printing and Casting Materials for use in Magnetic Resonance Imaging Phantoms at 3 T

2020 ◽  
Vol 125 ◽  
Author(s):  
B. E. Yunker ◽  
K. F. Stupic ◽  
J. L. Wagner ◽  
S. Huddle ◽  
R. Shandas ◽  
...  
Keyword(s):  
Magnetic Resonance Imaging ◽  
Tensile Strength ◽  
Magnetic Resonance ◽  
3D Printing ◽  
Spin Echo ◽  
Relaxation Times ◽  
Patient Specific ◽  
Resonance Imaging ◽  
Fused Deposition ◽  
Imaging Phantoms

Imaging phantoms are used to calibrate and validate the performance of magnetic resonance imaging (MRI) systems. Many new materials have been developed for additive manufacturing (three-dimensional [3D] printing) processes that may be useful in the direct printing or casting of dimensionally accurate, anatomically accurate, patient-specific, and/or biomimetic MRI phantoms. The T1, T2, and T2* spin relaxation times of polymer samples were tested to discover materials for use as tissue mimics and structures in MRI phantoms. This study included a cohort of polymer compounds that was tested in cured form. The cohort consisted of 101 standardized polymer samples fabricated from: two-part silicones and polyurethanes used in commercial casting processes; one-part optically cured polyurethanes used in 3D printing; and fused deposition thermoplastics used in 3D printing. The testing was performed at 3 T using inversion recovery, spin echo, and gradient echo sequences for T1, T2, and T2*, respectively. T1, T2, and T2* values were plotted with error bars to allow the reader to assess how well a polymer matches a tissue for a specific application. A correlation was performed between T1, T2 , T2* values and material density, elongation, tensile strength, and hardness. Two silicones, SI_XP-643 and SI_P-45, may be usable mimics for reported liver values; one silicone, SI_XP-643, may be a useful mimic for muscle; one silicone, SI_XP-738, may be a useful mimic for white matter; and four silicones, SI_P-15, SI_GI-1000, SI_GI-1040, and SI_GI-1110, may be usable mimics for spinal cord. Elongation correlated to T2 (p = 0.0007), tensile strength correlated to T1 (p = 0.002), T2 (p = 0.0003), and T2* (p = 0.003). The 80 samples not providing measurable signal with T1, T2, T2* relaxation values too short to measure with the standard sequences, may be useful for MRI-invisible fixturing and medical devices at 3 T.

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