Liquid-Metal-Bath Stress-Strain Apparatus
Abstract A simple, reliable apparatus for measuring stress-strain properties of vulcanizates at temperatures up to at least 800° F has been developed. The heating medium is a molten metal bath which provides uniform temperature distribution and rapid heat transfer while excluding atmospheric oxygen. Ultimate tensile strengths are in excellent agreement with those obtained in conventional air-oven tests. Stress relaxation tests show the effects of excluding atmospheric oxygen from the specimens. Somewhat higher ultimate elongations are obtained in the liquid-bath than in air-oven apparatus, for which possible reasons are suggested. Results on vulcanizates of heat-resistant polymers demonstrate that retention of physical properties at 500° F or 600° F cannot be safely predicted from data obtained at 400° F. The curing system, as well as the base polymer, is very important to high temperature resistance. In both Diene and butyl rubber compounds, for example, resin cures were superior in this respect to more conventional curing systems.