Consequences and Development of an Invention

1965 ◽  
Vol 38 (1) ◽  
pp. 23-36 ◽  
Author(s):  
Karl Ziegler

Abstract The awarding of the Nobel Prize for Chemistry, for the year 1963, is related to the precipitous expansion of macromolecular chemistry and its industrial applications, which began precisely ten years ago at my Max-Planck-Institute for Coal Research, in Mülheim/Ruhr. The suddenness with which this began, and the rapidity with which it was propagated are comparable to an explosion. The energy sources in this case were the ingenuity, activity, creative imagination and bold concepts of the many unnamed chemists, designers and entrepreneurs in the world who have fashioned great industries from our humble beginnings. If today I stand with my colleague Natta, who has been particularly effective in promoting this explosive wave, in the limelight of distinction, and do wish to manifest, with this address, my appreciation for the honor bestowed upon me, I must begin by thanking these many anonymous persons. They, too, deserve this distinction. The extent of this “explosion” may be illustrated by two charts, in which the location of newly-established plants is indicated. The places marked by black circles refer to new production facilities which, though concerned with low molecular weight materials, nevertheless also have some connection with the address I am delivering today (Figures 1 and 2). The new development had its inception near the end of 1953, when I, together with Holzkamp, Breil and Martin observed, for several days, an almost dramatic occurrence: that ethylene gas will polymerize very rapidly with certain catalysts that are extremely easy to prepare, at 100, 20 and 5 atmospheres and, finally, even at normal pressure, to a high molecular weight plastic.

2013 ◽  
Vol 2013 ◽  
pp. 1-15 ◽  
Author(s):  
Meenu Kapoor ◽  
Dhriti Khandal ◽  
Ruchi Gupta ◽  
Pinklesh Arora ◽  
Geetha Seshadri ◽  
...  

Guar gum and its derivatives are highly important industrial hydrocolloids as they find applications in various industrial sectors. Guar is a polymer of high molecular weight and its aqueous solutions exhibit unique rheological properties, which has led to its wide acceptance by the industry. In certain industrial applications low molecular weight guar and its derivatives are needed, and conventionally chemical depolymerisation of guar is carried out for this purpose. Radiation processing is a novel and green technology for carrying out depolymerization and can be an ideal substitute for chemical depolymerisation technique. In order to study the effect of radiation on guar derivatives, three types of derivatives have been taken in the present study: carboxymethyl, hydroxyethyl, and methyl guar. The effect of 1–50 KGy radiation dose on the rheological behavior of these derivatives has been studied, and the results have been described in the present paper. The effect on storage and loss modulus with respect to frequency and effect on viscosity with respect to shear rate have been discussed in detail.


RSC Advances ◽  
2016 ◽  
Vol 6 (107) ◽  
pp. 105476-105486 ◽  
Author(s):  
Mansoore Hosseini-Koupaei ◽  
Behzad Shareghi ◽  
Ali Akbar Saboury ◽  
Fatemeh Davar ◽  
Fatame Raisi

Polyamines (such as spermidine) are low molecular weight compounds which can be used as cosolvents in biological and industrial applications.


Soft Matter ◽  
2015 ◽  
Vol 11 (24) ◽  
pp. 4768-4787 ◽  
Author(s):  
Babatunde O. Okesola ◽  
Vânia M. P. Vieira ◽  
Daniel J. Cornwell ◽  
Nicole K. Whitelaw ◽  
David K. Smith

DBS is an efficient, versatile, low-molecular-weight gelator with a wide-range of industrial applications – greater understanding of its self-assembly and the creation of new derivatives are expanding the scope of this fascinating family of gels.


Author(s):  
G.K.W. Balkau ◽  
E. Bez ◽  
J.L. Farrant

The earliest account of the contamination of electron microscope specimens by the deposition of carbonaceous material during electron irradiation was published in 1947 by Watson who was then working in Canada. It was soon established that this carbonaceous material is formed from organic vapours, and it is now recognized that the principal source is the oil-sealed rotary pumps which provide the backing vacuum. It has been shown that the organic vapours consist of low molecular weight fragments of oil molecules which have been degraded at hot spots produced by friction between the vanes and the surfaces on which they slide. As satisfactory oil-free pumps are unavailable, it is standard electron microscope practice to reduce the partial pressure of organic vapours in the microscope in the vicinity of the specimen by using liquid-nitrogen cooled anti-contamination devices. Traps of this type are sufficient to reduce the contamination rate to about 0.1 Å per min, which is tolerable for many investigations.


1998 ◽  
Vol 1 (5) ◽  
pp. 166-174 ◽  
Author(s):  
Evelyn R Hermes De Santis ◽  
Betsy S Laumeister ◽  
Vidhu Bansal ◽  
Vandana Kataria ◽  
Preeti Loomba ◽  
...  

VASA ◽  
2007 ◽  
Vol 36 (1) ◽  
pp. 17-22
Author(s):  
Schulz ◽  
Kesselring ◽  
Seeberger ◽  
Andresen

Background: Patients admitted to hospital for surgery or acute medical illnesses have a high risk for venous thromboembolism (VTE). Today’s widespread use of low molecular weight heparins (LMWH) for VTE prophylaxis is supposed to have reduced VTE rates substantially. However, data concerning the overall effectiveness of LMWH prophylaxis is sparse. Patients and methods: We prospectively studied all patients with symptomatic and objectively confirmed VTE seen in our hospital over a three year period. Event rates in different wards were analysed and compared. VTE prophylaxis with Enoxaparin was given to all patients at risk during their hospital stay. Results: A total of 50 464 inpatients were treated during the study period. 461 examinations were carried out for symptoms suggestive of VTE and yielded 89 positive results in 85 patients. Seventy eight patients were found to have deep vein thrombosis, 7 had pulmonary embolism, and 4 had both deep venous thrombosis and pulmonary embolism. The overall in hospital VTE event rate was 0.17%. The rate decreased during the study period from 0.22 in year one to 0,16 in year two and 0.13 % in year three. It ranged highest in neurologic and trauma patients (0.32%) and lowest (0.08%) in gynecology-obstetrics. Conclusions: With a simple and strictly applied regimen of prophylaxis with LMWH the overall rate of symptomatic VTE was very low in our hospitalized patients. Beside LMWH prophylaxis, shortening hospital stays and substantial improvements in surgical and anasthesia techniques achieved during the last decades probably play an essential role in decreasing VTE rates.


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