An Attempt at a Rational Classification of the Principal Accelerators of Vulcanization. II. A Study of the Time Required for Vulcanization Giving the Maxima Physical Properties at Different Temperatures
Abstract We have attempted to classify the principal accelerators of vulcanization according to their chief characteristics which are the following: (1) Time necessary for the fixation of mixtures at different temperatures. (2) Times required at different temperatures to obtain vulcanization giving the maxima physical properties. (3) Aging. The first of these 3 items has been treated in Caoutchouc et Gutta-Percha (April, 1929) and we have shown how accelerators can be classified by their “precocity” of action; that is to say, by the rapidity with which they “fix” mixtures at different temperatures. The mixture being fixed, vulcanization continues and the physical quality of the rubber improves. It thus reaches a maximum, then diminishes upon too prolonged heating. In this second study we have attempted to determine the following points: (1) At a given temperature, how long a period of vulcanization is required to impart to the mixtures their maxima physical properties? (2) Within the range of temperatures, which temperature gives the optima physical properties?