Studies of Heat Generation in Polyester Cord Tires

1976 ◽  
Vol 49 (5) ◽  
pp. 1145-1159 ◽  
Author(s):  
G. E. R. Lamb ◽  
H-D. Weigmann ◽  
B. C. Goswami

Abstract Measurements of loss factor in polyester cord and cured rubber stock were made. From the results, the equilibrium cord temperatures in a rotating tire were estimated. These calculated values agree with measured values reported in the literature. It is shown that, for truck tires, cord temperatures can easily rise to levels where cord degradation in the presence of sulfenamide accelerators is known to occur. Measurements on cords which had been degraded by aminolysis indicate that loss factors increase as a result of the degradation and cause significant increases in local steady-state temperatures. This effect will tend to accelerate the rate of degradation at those locations. The increases in loss factor agree with observations on loss factors at increasing levels of crystallinity in polyester fibers in the literature.

1976 ◽  
Vol 49 (4) ◽  
pp. 1040-1059 ◽  
Author(s):  
H-D. Weigmann ◽  
G. E. R. Lamb

Abstract The degradative effects of accelerators of the sulfenamide and thiuram types on polyester tire yarns depends on the stability of the accelerator and the reactivity of the amines generated. Thermal decomposition of the accelerator alone is not sufficient to explain the degradative effects reported by other workers. The complexes formed by the accelerators in the presence of activators, such as zinc oxide and stearic acid, have lower thermal stability than the accelerators alone and release amines at lower temperatures. The formation of the complexes can be shown by differential scanning calorimetry. The findings of this investigation may have important implications with regard to the release of amines during the life of a tire and to the efficient compounding of rubber stock. If, as it appears, the decomposition of TMTM and TBBS occurs more efficiently if they are previously allowed to form a complex, there may be advantages in forming such complexes before addition of the ingredients to the rubber stock. If the ingredients are added separately, the formation of the complex would be controlled by diffusion of the ingredients in the rubber, and incomplete complex formation may result, leaving residues of unreacted components. These would, over a period of time, release more amine, causing degradation of the polyester cord. Advantages of prior complex formation, beside reduction of the above effect, might be lower concentration requirements for the accelerator and possibly better long-term physical properties of the elastomer. As pointed out in the introduction, effects of moisture, which were discussed by Iyengar, were not taken into consideration in this investigation. The conclusions drawn here are therefore strictly applicable only to the thermal decomposition of the accelerators and accelerator-activator complexes. This mode of decomposition is, however, felt to be of major significance for the degradation of polyester tire cords in truck tires during actual use.


Author(s):  
Oscar O. Rodriguez ◽  
Arturo A. Fuentes ◽  
Constantine Tarawneh ◽  
Robert E. Jones

Thermoplastic elastomers (TPE’s) are increasingly being used in rail service in load damping applications. They are superior to traditional elastomers primarily in their ease of fabrication. Like traditional elastomers they offer benefits including reduction in noise emissions and improved wear resistance in metal components that are in contact with such parts in the railcar suspension system. However, viscoelastic materials, such as the railroad bearing thermoplastic elastomer suspension element (or elastomeric pad), are known to develop self-heating (hysteresis) under cyclic loading, which can lead to undesirable consequences. Quantifying the hysteresis heating of the pad during operation is therefore essential to predict its dynamic response and structural integrity, as well as, to predict and understand the heat transfer paths from bearings into the truck assembly and other contacting components. This study investigates the internal heat generation in the suspension pad and its impact on the complete bearing assembly dynamics and thermal profile. Specifically, this paper presents an experimentally validated finite element thermal model of the elastomeric pad and its internal heat generation. The steady-state and transient-state temperature profiles produced by hysteresis heating of the elastomer pad are developed through a series of experiments and finite element analysis. The hysteresis heating is induced by the internal heat generation, which is a function of the loss modulus, strain, and frequency. Based on previous experimental studies, estimations of internally generated heat were obtained. The calculations show that the internal heat generation is impacted by temperature and frequency. At higher frequencies, the internally generated heat is significantly greater compared to lower frequencies, and at higher temperatures, the internally generated heat is significantly less compared to lower temperatures. However, during service operation, exposure of the suspension pad to higher loading frequencies above 10 Hz is less likely to occur. Therefore, internal heat generation values that have a significant impact on the suspension pad steady-state temperature are less likely to be reached. The commercial software package ALGOR 20.3TM is used to conduct the thermal finite element analysis. Different internal heating scenarios are simulated with the purpose of obtaining the bearing suspension element temperature distribution during normal and abnormal conditions. The results presented in this paper can be used in the future to acquire temperature distribution maps of complete bearing assemblies in service conditions and enable a refined model for the evolution of bearing temperature during operation.


2019 ◽  
Vol 50 (9-11) ◽  
pp. 306-312
Author(s):  
Mandale Maruti Bhagwan ◽  
Bangarubabu Popuri

In statistical energy analysis, coupling loss factor is the essential parameter for vibro-acoustic analysis of complicated structures. The coupling loss factors have been estimated using energy-level difference method. The tightening torque applied at structural junction has been varied. Higher values of coupling loss factor have been observed for higher tightening torque on bolted junction. The coupling loss factors have been determined for various structural junctions of rectangular composite plates. The riveted and bolted junctions have been examined for composite plates in same plane and size. The coupling loss factors for bolted junction are relatively higher than that for riveted junction of composite plates. The values of coupling loss factors are found to increase with increasing tightening torque applied at structural junctions of composite plates. It is also noted that the experimental results of coupling loss factors for point junctions vary with changes in fiber orientations of composite plates. It is firmly believed that the various findings of the coupling loss factors in this article help for vibro-acoustic analysis of complicated structures.


Author(s):  
Lyudmyla Barannyk ◽  
John Crepeau ◽  
Patrick Paulus ◽  
Ali Siahpush

A nonlinear, first-order ordinary differential equation that involves Fourier-Bessel series terms has been derived to model the time-dependent motion of the solid-liquid interface during melting and solidification of a material with constant internal heat generation in cylindrical coordinates. The model is valid for all Stefan numbers. One of the primary applications of this problem is for a nuclear fuel rod during meltdown. The numerical solutions to this differential equation are compared to the solutions of a previously derived model that was based on the quasi-steady approximation, which is valid only for Stefan numbers less than one. The model presented in this paper contains exponentially decaying terms in the form of Fourier-Bessel series for the temperature gradients in both the solid and liquid phases. The agreement between the two models is excellent in the low Stefan number regime. For higher Stefan numbers, where the quasi-steady model is not accurate, the new model differs from the approximate model since it incorporates the time-dependent terms for small times, and as the system approaches steady-state, the curves converge. At higher Stefan numbers, the system approaches steady-state faster than for lower Stefan numbers. During the transient process for both melting and solidification, the temperature profiles become parabolic.


Energies ◽  
2019 ◽  
Vol 12 (21) ◽  
pp. 4037 ◽  
Author(s):  
Mikhail Tokarev

A full scale lab prototype of an adsorptive heat transformer (AHT), consisting of two adsorbers, an evaporator, and a condenser, was designed and tested in subsequent cycles of heat upgrading. The composite LiCl/SiO2 was used as an adsorbent with methanol as an adsorbtive substance under boundary temperatures of TL/TM/TH = −30/20/30 °C. Preliminary experiments demonstrated the feasibility of the tested AHT in continuous heat generation, with specific power output of 520 W/kg over 1–1.5 h steady-state cycling. The formal and experimental thermal efficiency of the tested rig were found to be 0.5 and 0.44, respectively. Although the low potential heat to be upgraded was available for free from a natural source, the electric efficiency of the prototype was found to be as high as 4.4, which demonstrates the promising potential of the “heat from cold” concept. Recommendations for further improvements are also outlined and discussed in this paper.


1985 ◽  
Vol 58 (4) ◽  
pp. 740-750 ◽  
Author(s):  
D. Barnard ◽  
C. S. L. Baker ◽  
I. R. Wallace

Abstract An 80 NR/20 BR truck tread compound containing a semi-EV cure system and modified with a 6.0 phr level of stearic acid has been shown to exhibit excellent resistance to reversion when compared to a similar compound containing a normal 2.0 phr level of stearic acid. Improvements in the retention of laboratory abrasion resistance, heat generation, and most physical properties have been identified on test pieces subjected to typical truck retread overcure conditions. In highway fleet testing trials of 1100 × 22.5 truck retreads fitted to both third and fourth drive axles of tipper trucks, the modified compound displayed a 42% improvement in treadwear performance over the normal compound in the lower severity third axle positions while performance in the higher severity fourth axle positions was inferior by 20%. In comparison to a 55 SBR/45 BR truck tread, both NR compounds displayed superior wear performance on the fourth axles while some further adjustments of the modified compound are required to match the synthetic compound on the third axles. The reversal of wear performances for all compounds between third and fourth axles is due to the different abrasion mechanisms encountered. Laboratory abrasion rankings do not correlate with wear performances of compounds on the fourth drive axle of trucks, but they do correlate with wear performances on third drive axles. Despite the reversion characteristics of the normal semi-EV compound, no significant adverse effect on treadwear performance was evident at the start of tire life. The low heat generation of the modified compound in laboratory tests is confirmed in actual tire testing. Advantages in rolling resistance characteristics are also evident for the modified compound. Current studies at MRPRA suggest that further modifications of cure system design, in combination with the optimization of NR/BR ratios and mixing methods, will potentially provide NR dominant truck tread compounds which will exhibit superior wear performance in both the higher and lower abrasion severities encountered in heavy-duty truck tire service conditions.


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