scholarly journals Rheological and functional properties of Roselle (Hibiscus sabdariffa) leaves puree

10.5219/929 ◽  
2019 ◽  
Vol 13 (1) ◽  
pp. 46-57
Author(s):  
Jaga Mohan Meher ◽  
Bidyut Mazumdar ◽  
Amit Keshav

Pureed form of leaves (Hibiscus sabdariffa L. (Roselle)) was taken for physicochemical and rheological analysis at temperatures and TSS range of 278 K - 318 K and 3 - 5 °Brix respectively. The steady-state rheological analysis was performed with a shear rate of 1 - 100 s-1. Different rheological models are tried; Power-law was best fitted with the experimental data (R2 ≥0.98). Temperature dependence of viscosity was found out using an Arrhenius-type relationship at a shear rate of 10, 50, 100 s-1 IR analysis was done to know the influence of functional groups on rheological properties of purees. Consistency index (K) of puree increases with increase in TSS content but at a fixed TSS, there is a decrease in K with an increase in temperatures but the opposite was observed for flow behavior index (n). Puree showed a shear thinning behavior with an increment in temperature level and puree having 5 °Brix (8.37) has higher activation energy (kJ.mol-1) than 3 °Brix (6.32).  

2018 ◽  
Vol 7 (2) ◽  
pp. 694 ◽  
Author(s):  
Anawe P. A. L ◽  
Folayan J. Adewale

The determination of pressure losses in the drill pipe and annulus with a very high degree of precision and accuracy is sacrosanct for proper pump operating conditions and correct bit nozzle sizes for maximum jet impact and forestalling of possible kicks and eventual blow outs during drilling operation. The two major uncertainties in pump pressure estimation that are being addressed in this research work are the flow behavior index (n) and the consistency index factor (k). It is in this light that the accuracy of various rheological models in predicting pump pressure losses as well as the uncertainties associated with each model was investigated. In order to come by with a decisive conclusion, two synthetic based drilling fluids were used to form synthetic muds known as sample A and B respectively. Inference from results shows that the Newtonian model underestimated the pump pressure by 78.27% for sample A and 82.961% by for sample B. While the Bingham plastic model overestimated the total pump pressure by 100.70% for sample A and 48.17% for sample B. Three different power law rheological model approaches were used to obtain the flow behavior index and consistency factor of the drilling fluids. For the power law rheological model approaches, an underestimation error of 23.5743% was encountered for the Formular method for sample A while the proposed consistency index averaging method reduces the error to 14.9306%. The Graphical method showed a reasonable degree of accuracy with underestimation error of 5.6435%. Sample B showed an underestimation error of 47.8234% by using the power law formula method while the Consistency averaging method reduced the error to 20.7508. The graphical method showed an underestimation error of 0.4318%.


2019 ◽  
Vol 70 (2) ◽  
pp. 382-386
Author(s):  
Andra Tamas ◽  
Sabina Nitu

The paper presents the study of the rheological and superficial behavior (foaming power and wetting capacity) of some aqueous solutions with polyethoxylated fatty alcohols content. The influence of fatty alcohols concentration and their degree of ethoxylation as well as that of temperature on the rheological behavior was determined from the dependences between the shear stress t and the shear rate. The results demonstrate that all the studied solutions have non-Newtonian behavior, with flow behavior index smaller than 1.


2006 ◽  
Vol 517 ◽  
pp. 147-152 ◽  
Author(s):  
W.S. Wan Nik ◽  
S.G. Eng Giap ◽  
H.H. Masjuki ◽  
H.B. Senin

Tribological aspects of bio-oils have to be investigated before they are used as industrial fluids. In this paper rheological (fluid deformation under shear) properties of four bio-oils are presented. A Couette type viscometer was used to evaluate flow behavior of the oils at seven discrete temperatures. Commercial coconut, canola, sunflower and corn oil were used in this study. For all the oil samples, viscosities were affected by the change of shear rate and temperature. Two rheological models, temperature dependence and shear rate dependence, were used in the study. The original power law gives contradict picture of flow curves and flow parameters. Thus, modified power law model was proposed. The modified model was fitted to experimental data to obtain the flow behavior index. Arrhenius type equation was fitted to experimental data to obtain the activation energy due to different temperatures and shear rates. Evaluation of rheological properties by modified power law model indicates that these bio-oils belong to the pseudo-plastic group.


2019 ◽  
Vol 15 (4) ◽  
pp. 437-441 ◽  
Author(s):  
Vasiliki Lagouri ◽  
Georgia Dimitreli ◽  
Aikatarini Kouvatsi

Background: Oxidation reactions are known to shorten the shelf life and cause damage to foods rich in fat, such as dairy products. One way to limit oxidation and increase the shelf life of fermented dairy products is to use natural antioxidants. The aim of this study was to examine the effect of adding pomegranate extracts in the antioxidant properties, rheological characteristics and the storage stability of the fermented product of kefir. Methods: The Pomegranate Juice (PGJ) and Peel Extracts (PGPE) (5%, 10% w/v) were added to kefir and the antioxidant properties were evaluated by using the methods of radical scavenging activity (DPPH) and Ferric Reducing Antioxidant Power Activity (FRAP). Spectrophotometric and instrumental methods were used to determine the Total Phenols (TPs), pH values, viscosity and flow behavioral index values of enriched with pomegranate kefir samples. The same properties were tested when kefir samples stored at 4°C for 7, 14, 21 and 28 days. Results: The addition of PGJ and PGPE results in an increase in the antioxidant activity (DPPH, FRAP) and total phenol content (TPs) of kefir samples. Increasing the concentration of the added PGJ and PGPE, results in an increase in the TP content and the DPPH activity of kefir. As far as the storage time is concerned, the results showed an increase in the amount of TP at 7th day and a reduction in the DPPH activity in the 14th day of storage. In contrary to the DPPH method, the increase in storage time has resulted in a reduction in antioxidant activity by the FRAP method. The addition of PGJ and PGPE in kefir results in a decrease in pH values while the pH of kefir samples increased during storage at 4°C for 28 days. The addition of PGJ and PGPE to kefir samples results to a decrease in viscosity and an increase in the flow behavior index. Increasing storage time results in increased flow behavior index of kefir samples. Conclusion: The addition of PGJ and PGPE increased the antioxidant activity and total phenols of the kefir product and preserved its properties during the total storage time of 28 days at 4°C.


Author(s):  
Cunlu Zhao ◽  
Chun Yang

Electroosmotic flow of power-law fluids in a slit channel is analyzed. The governing equations including the linearized Poisson–Boltzmann equation, the Cauchy momentum equation and the continuity equation are solved to seek analytical expressions for the shear stress, dynamic viscosity and velocity distributions. Specifically, exact solutions of the velocity distributions are explicitly found for several special values of the flow behavior index. Furthermore, with the implementation of an approximate scheme for the hyperbolic cosine function, approximate solutions of the velocity distributions are obtained. In addition, a mathematical expression for the average electroosmotic velocity is derived for large values of the dimensionless electrokinetic parameter, κH, in a fashion similar to the Smoluchowski equation. Hence, a generalized Smoluchowski velocity is introduced by taking into account contributions due to the finite thickness of the electric double layer and the flow behavior index of power-law fluids. Finally, calculations are performed to examine the effects of κH, flow behavior index, double layer thickness, and applied electric field on the shear stress, dynamic viscosity, velocity distribution, and average velocity/flow rate of the electroosmotic flow of power-law fluids.


2008 ◽  
Vol 18 (3) ◽  
pp. 34482-1-34482-11 ◽  
Author(s):  
Vassilios C. Kelessidis ◽  
Roberto Maglione

AbstractA methodology is presented to invert the flow equation of a Herschel-Bulkley fluid in Couette concentric cylinder geometry, thus enabling simultaneous computation of the true shear rates, γ̇HB, and of the three Herschel-Bulkley rheological parameters. The errors made when these rheological parameters are computed using Newtonian shear rates, γ̇N, as it is normal practice by research and industry personnel, can then be estimated. Quantification of these errors has been performed using narrow gap viscometer data from literature, with most of them taken with oil-field rheometers. The results indicate that significant differences exist between the yield stress and the flow behavior index computed using γ̇HB versus the parameters obtained using γ̇N and this is an outcome of the higher γ̇HB values. Predicted true shear rates and rheological parameters are in very good agreement with results reported by other investigators, who have followed different approaches to invert the flow equation, both for yield-pseudoplastic and power-law fluids.


Materials ◽  
2018 ◽  
Vol 11 (6) ◽  
pp. 917 ◽  
Author(s):  
Chao Li ◽  
Shaopeng Wu ◽  
Guanyu Tao ◽  
Yue Xiao

Author(s):  
Suresh Kumar Patel ◽  
Subrata Kumar Majumder

The packed bed columns with non-Newtonian liquid are increasing importance as a simple and inexpensive means of achieving yield of different chemical and biochemical processes though their hydrodynamic behavior is complex and not yet fully understood. In this article non-Newtonian flow behavior on frictional pressure was investigated in packed bed within a range of liquid velocity 0.004-0.04 m/s. The frictional pressure loss in non-Newtonian liquid system has been analyzed by modified Ergun equation. The modification of the Ergun equation is incorporated with the flow behavior index of non-Newtonian liquid. The degree of frictional pressure loss decreases with increase in flow behavior index. A correlation has been developed to interpret the degree of effect on the frictional pressure loss. The correlation may be useful for further understanding and scale-up of the packed bed column for its industrial application.


Sign in / Sign up

Export Citation Format

Share Document