scholarly journals In situ measurement of low-frequency sea-ice dielectric properties and implications for tracking seasonal evolution of microstructure

2016 ◽  
Author(s):  
Megan O'Sadnick ◽  
Malcolm Ingham ◽  
Hajo Eicken ◽  
Erin Pettit

Abstract. The seasonal evolution of sea-ice microstructure controls key ice properties, including those governing ocean-atmosphere heat and gas exchange, remote-sensing signatures and the role of the ice cover as a habitat. Non-destructive in situ monitoring of sea-ice microstructure is of value for sea-ice research and operations, but remains elusive to date. We examine the potential for the electric properties of sea ice, which is highly sensitive to the brine distribution within the ice, to serve as a proxy for microstructure and, hence, other ice transport properties. Throughout spring of 2013 and 2014, we measured complex dielectric permittivity in the range of 10 Hz to 95 kHz in landfast ice off the coast of Barrow, Alaska. Temperature and salinity measurements and ice samples provide data to characterize ice microstructure in relation to these permittivity measurements. The results reveal a significant correlation between complex dielectric permittivity, brine volume fraction, and microstructural characteristics including pore volume and connectivity, derived from x-ray microtomography of core samples. The influence of temperature and salinity variations, as well as the relationships between ice properties, microstructural characteristics, and dielectric behavior emerge from multivariate analysis of the combined data set. Our findings suggest some promise for low-frequency permittivity measurements to track seasonal evolution of a combination of mean pore volume, fractional connectivity, and pore surface area-to-volume ratio, which in turn may serve as proxies for key sea-ice transport properties.

2016 ◽  
Vol 10 (6) ◽  
pp. 2923-2940 ◽  
Author(s):  
Megan O'Sadnick ◽  
Malcolm Ingham ◽  
Hajo Eicken ◽  
Erin Pettit

Abstract. The seasonal evolution of sea-ice microstructure controls key ice properties, including those governing ocean–atmosphere heat and gas exchange, remote-sensing signatures, and the role of the ice cover as a habitat. Non-destructive in situ monitoring of sea-ice microstructure is of value for sea-ice research and operations but remains elusive to date. We examine the potential for the electric properties of sea ice, which is highly sensitive to the brine distribution within the ice, to serve as a proxy for microstructure and, hence, other ice transport properties. Throughout spring of 2013 and 2014, we measured complex dielectric permittivity in the range of 10 to 95 kHz in landfast ice off the coast of Barrow (Utqiaġvik), Alaska. Temperature and salinity measurements and ice samples provide data to characterize ice microstructure in relation to these permittivity measurements. The results reveal a significant correlation between complex dielectric permittivity, brine volume fraction, and microstructural characteristics including pore volume and connectivity, derived from X-ray microtomography of core samples. The influence of temperature and salinity variations as well as the relationships between ice properties, microstructural characteristics, and dielectric behavior emerge from multivariate analysis of the combined data set. Our findings suggest some promise for low-frequency permittivity measurements to track seasonal evolution of a combination of mean pore volume, fractional connectivity, and pore surface area-to-volume ratio, which in turn may serve as proxies for key sea-ice transport properties.


Polymers ◽  
2021 ◽  
Vol 13 (7) ◽  
pp. 1173
Author(s):  
Ilze Beverte ◽  
Ugis Cabulis ◽  
Sergejs Gaidukovs

As a non-metallic composite material, widely applied in industry, rigid polyurethane (PUR) foams require knowledge of their dielectric properties. In experimental determination of PUR foams’ dielectric properties protection of one-side capacitive sensor’s active area from adverse effects caused by the PUR foams’ test objects has to be ensured. In the given study, the impact of polytetrafluoroethylene (PTFE) films, thickness 0.20 mm and 0.04 mm, in covering or simulated coating the active area of one-side access capacitive sensor’ electrodes on the experimentally determined true dielectric permittivity spectra of rigid PUR foams is estimated. Penetration depth of the low frequency excitation field into PTFE and PUR foams is determined experimentally. Experiments are made in order to evaluate the difference between measurements on single PUR foams’ samples and on complex samples “PUR foams + PTFE film” with two calibration modes. A modification factor and a small modification criterion are defined and values of modifications are estimated in numerical calculations. Conclusions about possible practical applications of PTFE films in dielectric permittivity measurements of rigid PUR foams with one-side access capacitive sensor are made.


2009 ◽  
Vol 55 (189) ◽  
pp. 81-94 ◽  
Author(s):  
Daniel Pringle ◽  
Guy Dubuis ◽  
Hajo Eicken

AbstractWe report impedance measurements of the complex dielectric permittivity ε = ε′ − jε″ of sea ice and laboratory-grown NaCl single crystals using 50 MHz Stevens Water Monitoring Systems Hydra Probes. Temperature cycling of the single-crystal samples shows hydrohalite precipitation, and hysteresis in ε′ and ε″ qualitatively consistent with the expected evolution of brine-inclusion microstructure. Measurements parallel and perpendicular to intra-crystalline brine layers show weak (<10%) anisotropy in ε′ and a 20–40% difference in ε″ due to enhanced d.c. conductivity along the layers. Measurements in landfast, first-year ice near Barrow, Alaska, USA, indicate brine motion in warming ice as the brine volume fraction vb increases above 5%. Plots of vb derived from salinity profiles against ε′ and ε″ for these and previous measurements display too much variability between datasets for unguided inversion of vb. Contributing to this variability are intrinsic microstructural dependence, uncertainties in vb, and sub-representative sample volumes. A standard model of sea-ice permittivity is inverted to derive the apparent brine-inclusion aspect ratio and bulk d.c. conductivity at a spatial scale complementary to previous measurements. We assess Hydra Probe performance in high-salinity environments and conclude that they are not generally suited for autonomous sea-ice salinity measurements, partly due to the range of relevant brine pocket inclusion length scales.


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