scholarly journals Three-year monitoring of stable isotopes of precipitation at Concordia Station, East Antarctica

Author(s):  
Barbara Stenni ◽  
Claudio Scarchilli ◽  
Valerie Masson-Delmotte ◽  
Elisabeth Schlosser ◽  
Virginia Ciardini ◽  
...  

Abstract. Past temperature reconstructions from Antarctic ice cores require a good quantification and understanding of the relationship between snow isotopic composition and 2&thninsp;m air or inversion (condensation) temperature. Here, we focus on the French-Italian Concordia Station, central East Antarctic plateau, where the European Project for Ice Coring in Antarctica (EPICA) Dome C ice cores were drilled. We provide a multi-year record of daily precipitation types identified from crystal morphologies, daily precipitation amounts, and isotopic composition. Our sampling period (2008–2010) encompasses a warmer year (2009, +1.6 °C with respect to 2&thninsp;m air temperature period average), with larger total precipitation and snowfall amounts (14 %, 76 % above average, respectively), and a colder and drier year (2010, −1.4 °C, 4 % below average, respectively) with larger diamond dust amounts (49 % above average). Relationships between local meteorological data and precipitation isotopic composition are investigated at daily, monthly and inter-annual scale, and for the different types of precipitation. Water stable isotopes are more closely related to 2 m air temperature than to inversion temperature at all time scales (e.g. R2 = 0.63 and 0.44, respectively for daily values). The slope of the temporal relationship between daily d18O and 2 m air temperature is approximately two times smaller (0.49 ‰/°C) than the average Antarctic spatial (0.8 ‰/°C) relationship initially used for the interpretation of EPICA Dome C records. In accordance to results from precipitation monitoring at Vostok and Dome F, deuterium excess is anti-correlated with δ18O at daily and monthly scales, reaching maximum values in winter. Hoar frost precipitation samples have a specific fingerprint with more depleted d18O (about 5 ‰ below average) and higher deuterium excess (about 8 ‰ above average) values than other precipitation types. These datasets provide a basis for comparison with shallow ice core records, to investigate post-deposition effects. A preliminary comparison between observations and precipitation from the European Centre for Medium-Range Weather Forecast (ECMWF) re-analysis and the simulated water stable isotopes from the Laboratoire de Météorologie Dynamique Zoom atmospheric general circulation model (LMDZiso), shows that models do correctly capture the amount of precipitation as well as more than 50 % of the variance of the observed δ18O, driven by large scale weather patterns. Despite a warm bias and an underestimation of the variance in water stable isotopes, LMDZiso correctly captures these relationships between δ18O, 2 m air temperature and deuterium excess. Our dataset is therefore available for further in depth model evaluation at the synoptic scale.

2016 ◽  
Vol 10 (5) ◽  
pp. 2415-2428 ◽  
Author(s):  
Barbara Stenni ◽  
Claudio Scarchilli ◽  
Valerie Masson-Delmotte ◽  
Elisabeth Schlosser ◽  
Virginia Ciardini ◽  
...  

Abstract. Past temperature reconstructions from Antarctic ice cores require a good quantification and understanding of the relationship between snow isotopic composition and 2 m air or inversion (condensation) temperature. Here, we focus on the French–Italian Concordia Station, central East Antarctic plateau, where the European Project for Ice Coring in Antarctica (EPICA) Dome C ice cores were drilled. We provide a multi-year record of daily precipitation types identified from crystal morphologies, daily precipitation amounts and isotopic composition. Our sampling period (2008–2010) encompasses a warmer year (2009, +1.2 °C with respect to 2 m air temperature long-term average 1996–2010), with larger total precipitation and snowfall amounts (14 and 76 % above sampling period average, respectively), and a colder and drier year (2010, −1.8 °C, 4 % below long-term and sampling period averages, respectively) with larger diamond dust amounts (49 % above sampling period average). Relationships between local meteorological data and precipitation isotopic composition are investigated at daily, monthly and inter-annual scale, and for the different types of precipitation. Water stable isotopes are more closely related to 2 m air temperature than to inversion temperature at all timescales (e.g. R2 = 0.63 and 0.44, respectively for daily values). The slope of the temporal relationship between daily δ18O and 2 m air temperature is approximately 2 times smaller (0.49 ‰ °C−1) than the average Antarctic spatial (0.8 ‰ °C−1) relationship initially used for the interpretation of EPICA Dome C records. In accordance with results from precipitation monitoring at Vostok and Dome F, deuterium excess is anti-correlated with δ18O at daily and monthly scales, reaching maximum values in winter. Hoar frost precipitation samples have a specific fingerprint with more depleted δ18O (about 5 ‰ below average) and higher deuterium excess (about 8 ‰ above average) values than other precipitation types. These datasets provide a basis for comparison with shallow ice core records, to investigate post-deposition effects. A preliminary comparison between observations and precipitation from the European Centre for Medium-Range Weather Forecasts (ECMWF) reanalysis and the simulated water stable isotopes from the Laboratoire de Météorologie Dynamique Zoom atmospheric general circulation model (LMDZiso) shows that models do correctly capture the amount of precipitation as well as more than 50 % of the variance of the observed δ18O, driven by large-scale weather patterns. Despite a warm bias and an underestimation of the variance in water stable isotopes, LMDZiso correctly captures these relationships between δ18O, 2 m air temperature and deuterium excess. Our dataset is therefore available for further in-depth model evaluation at the synoptic scale.


2014 ◽  
Vol 14 (20) ◽  
pp. 27619-27661 ◽  
Author(s):  
A. Ghosh ◽  
P. K. Patra ◽  
K. Ishijima ◽  
T. Umezawa ◽  
A. Ito ◽  
...  

Abstract. Atmospheric methane (CH4) increased from ~900 ppb (parts per billion, or nanomoles per mole of dry air) in 1900 to ~1800 ppb during the 2000s at a rate unprecedented in any observational records. However, the causes of the CH4 increase are poorly understood. Here we use initial emissions from bottom-up inventories for anthropogenic sources, emissions from wetlands and rice paddies simulated by a terrestrial biogeochemical model, and an atmospheric general circulation model (AGCM)-based chemistry-transport model (i.e. ACTM) to simulate atmospheric CH4 concentrations for 1910 to 2010. The ACTM simulations are compared with the CH4 concentration records reconstructed from Antarctic and Arctic ice cores and firn air samples, and from direct measurements since the 1980s at multiple sites around the globe. The differences between ACTM simulations and observed CH4 concentrations are minimized to optimize the global total emissions using a mass balance calculation. During 1910–2010, the global total CH4 emission increased from ~290 Tg yr−1 to ~580 Tg yr−1. Compared to optimized emission the bottom-up emission dataset underestimates the rate of change of global total CH4 emissions by ~30% during the high growth period of 1940–1990, while it overestimates by ~380% during a~low growth period of 1990–2010. Further, using the CH4 stable carbon isotopic data (δ13C), we attribute the emission increase during 1940–1990 primarily to enhancement of biomass burning. The total lifetime of CH4 shortened from 9.4 yr during 1910–1919 to 9 yr during 2000–2009 by the combined effect of increasing abundance of atomic chlorine radicals (Cl) and increases in average air temperature. We show that changes of CH4 loss rate due to increased tropospheric air temperature and CH4 loss due to Cl in the stratosphere are important sources of uncertainty to more accurately estimate global CH4 budget from δ13C observations.


2018 ◽  
Vol 14 (6) ◽  
pp. 923-946 ◽  
Author(s):  
Sentia Goursaud ◽  
Valérie Masson-Delmotte ◽  
Vincent Favier ◽  
Anaïs Orsi ◽  
Martin Werner

Abstract. Polar ice core water isotope records are commonly used to infer past changes in Antarctic temperature, motivating an improved understanding and quantification of the temporal relationship between δ18O and temperature. This can be achieved using simulations performed by atmospheric general circulation models equipped with water stable isotopes. Here, we evaluate the skills of the high-resolution water-isotope-enabled atmospheric general circulation model ECHAM5-wiso (the European Centre Hamburg Model) nudged to European Centre for Medium-Range Weather Forecasts (ECMWF) reanalysis using simulations covering the period 1960–2013 over the Antarctic continent. We compare model outputs with field data, first with a focus on regional climate variables and second on water stable isotopes, using our updated dataset of water stable isotope measurements from precipitation, snow, and firn–ice core samples. ECHAM5-wiso simulates a large increase in temperature from 1978 to 1979, possibly caused by a discontinuity in the European Reanalyses (ERA) linked to the assimilation of remote sensing data starting in 1979. Although some model–data mismatches are observed, the (precipitation minus evaporation) outputs are found to be realistic products for surface mass balance. A warm model bias over central East Antarctica and a cold model bias over coastal regions explain first-order δ18O model biases by too-strong isotopic depletion on coastal areas and underestimated depletion inland. At the second order, despite these biases, ECHAM5-wiso correctly captures the observed spatial patterns of deuterium excess. The results of model–data comparisons for the inter-annual δ18O standard deviation differ when using precipitation or ice core data. Further studies should explore the importance of deposition and post-deposition processes affecting ice core signals and not resolved in the model. These results build trust in the use of ECHAM5-wiso outputs to investigate the spatial, seasonal, and inter-annual δ18O–temperature relationships. We thus make the first Antarctica-wide synthesis of prior results. First, we show that local spatial or seasonal slopes are not a correct surrogate for inter-annual temporal slopes, leading to the conclusion that the same isotope–temperature slope cannot be applied for the climatic interpretation of Antarctic ice core for all timescales. Finally, we explore the phasing between the seasonal cycles of deuterium excess and δ18O as a source of information on changes in moisture sources affecting the δ18O–temperature relationship. The few available records and ECHAM5-wiso show different phase relationships in coastal, intermediate, and central regions. This work evaluates the use of the ECHAM5-wiso model as a tool for the investigation of water stable isotopes in Antarctic precipitation and calls for extended studies to improve our understanding of such proxies.


2019 ◽  
Vol 116 (10) ◽  
pp. 4099-4104 ◽  
Author(s):  
Louise C. Sime ◽  
Peter O. Hopcroft ◽  
Rachael H. Rhodes

Greenland ice cores provide excellent evidence of past abrupt climate changes. However, there is no universally accepted theory of how and why these Dansgaard–Oeschger (DO) events occur. Several mechanisms have been proposed to explain DO events, including sea ice, ice shelf buildup, ice sheets, atmospheric circulation, and meltwater changes. DO event temperature reconstructions depend on the stable water isotope (δ18O) and nitrogen isotope measurements from Greenland ice cores: interpretation of these measurements holds the key to understanding the nature of DO events. Here, we demonstrate the primary importance of sea ice as a control on Greenland ice coreδ18O: 95% of the variability inδ18O in southern Greenland is explained by DO event sea ice changes. Our suite of DO events, simulated using a general circulation model, accurately captures the amplitude ofδ18O enrichment during the abrupt DO event onsets. Simulated geographical variability is broadly consistent with available ice core evidence. We find an hitherto unknown sensitivity of theδ18O paleothermometer to the magnitude of DO event temperature increase: the change inδ18O per Kelvin temperature increase reduces with DO event amplitude. We show that this effect is controlled by precipitation seasonality.


2015 ◽  
Vol 15 (10) ◽  
pp. 5537-5555 ◽  
Author(s):  
R. Eichinger ◽  
P. Jöckel ◽  
S. Brinkop ◽  
M. Werner ◽  
S. Lossow

Abstract. This modelling study aims at an improved understanding of the processes that determine the water vapour budget in the stratosphere by means of the investigation of water isotope ratios. An additional (and separate from the actual) hydrological cycle has been introduced into the chemistry–climate model EMAC, including the water isotopologues HDO and H218O and their physical fractionation processes. Additionally an explicit computation of the contribution of methane oxidation to H2O and HDO has been incorporated. The model expansions allow detailed analyses of water vapour and its isotope ratio with respect to deuterium throughout the stratosphere and in the transition region to the troposphere. In order to assure the correct representation of the water isotopologues in the model's hydrological cycle, the expanded system has been evaluated in several steps. The physical fractionation effects have been evaluated by comparison of the simulated isotopic composition of precipitation with measurements from a ground-based network (GNIP) and with the results from the isotopologue-enabled general circulation model ECHAM5-wiso. The model's representation of the chemical HDO precursor CH3D in the stratosphere has been confirmed by a comparison with chemical transport models (1-D, CHEM2D) and measurements from radiosonde flights. Finally, the simulated stratospheric HDO and the isotopic composition of water vapour have been evaluated, with respect to retrievals from three different satellite instruments (MIPAS, ACE-FTS, SMR). Discrepancies in stratospheric water vapour isotope ratios between two of the three satellite retrievals can now partly be explained.


2013 ◽  
Vol 17 (6) ◽  
pp. 2147-2159 ◽  
Author(s):  
E. P. Maurer ◽  
T. Das ◽  
D. R. Cayan

Abstract. When correcting for biases in general circulation model (GCM) output, for example when statistically downscaling for regional and local impacts studies, a common assumption is that the GCM biases can be characterized by comparing model simulations and observations for a historical period. We demonstrate some complications in this assumption, with GCM biases varying between mean and extreme values and for different sets of historical years. Daily precipitation and maximum and minimum temperature from late 20th century simulations by four GCMs over the United States were compared to gridded observations. Using random years from the historical record we select a "base" set and a 10 yr independent "projected" set. We compare differences in biases between these sets at median and extreme percentiles. On average a base set with as few as 4 randomly-selected years is often adequate to characterize the biases in daily GCM precipitation and temperature, at both median and extreme values; 12 yr provided higher confidence that bias correction would be successful. This suggests that some of the GCM bias is time invariant. When characterizing bias with a set of consecutive years, the set must be long enough to accommodate regional low frequency variability, since the bias also exhibits this variability. Newer climate models included in the Intergovernmental Panel on Climate Change fifth assessment will allow extending this study for a longer observational period and to finer scales.


2013 ◽  
Vol 9 (2) ◽  
pp. 871-886 ◽  
Author(s):  
M. Casado ◽  
P. Ortega ◽  
V. Masson-Delmotte ◽  
C. Risi ◽  
D. Swingedouw ◽  
...  

Abstract. In mid and high latitudes, the stable isotope ratio in precipitation is driven by changes in temperature, which control atmospheric distillation. This relationship forms the basis for many continental paleoclimatic reconstructions using direct (e.g. ice cores) or indirect (e.g. tree ring cellulose, speleothem calcite) archives of past precipitation. However, the archiving process is inherently biased by intermittency of precipitation. Here, we use two sets of atmospheric reanalyses (NCEP (National Centers for Environmental Prediction) and ERA-interim) to quantify this precipitation intermittency bias, by comparing seasonal (winter and summer) temperatures estimated with and without precipitation weighting. We show that this bias reaches up to 10 °C and has large interannual variability. We then assess the impact of precipitation intermittency on the strength and stability of temporal correlations between seasonal temperatures and the North Atlantic Oscillation (NAO). Precipitation weighting reduces the correlation between winter NAO and temperature in some areas (e.g. Québec, South-East USA, East Greenland, East Siberia, Mediterranean sector) but does not alter the main patterns of correlation. The correlations between NAO, δ18O in precipitation, temperature and precipitation weighted temperature are investigated using outputs of an atmospheric general circulation model enabled with stable isotopes and nudged using reanalyses (LMDZiso (Laboratoire de Météorologie Dynamique Zoom)). In winter, LMDZiso shows similar correlation values between the NAO and both the precipitation weighted temperature and δ18O in precipitation, thus suggesting limited impacts of moisture origin. Correlations of comparable magnitude are obtained for the available observational evidence (GNIP (Global Network of Isotopes in Precipitation) and Greenland ice core data). Our findings support the use of archives of past δ18O for NAO reconstructions.


2007 ◽  
Vol 4 (5) ◽  
pp. 3413-3440 ◽  
Author(s):  
E. P. Maurer ◽  
H. G. Hidalgo

Abstract. Downscaling of climate model data is essential to most impact analysis. We compare two methods of statistical downscaling to produce continuous, gridded time series of precipitation and surface air temperature at a 1/8-degree (approximately 140 km² per grid cell) resolution over the western U.S. We use NCEP/NCAR Reanalysis data from 1950–1999 as a surrogate General Circulation Model (GCM). The two methods included are constructed analogues (CA) and a bias correction and spatial downscaling (BCSD), both of which have been shown to be skillful in different settings, and BCSD has been used extensively in hydrologic impact analysis. Both methods use the coarse scale Reanalysis fields of precipitation and temperature as predictors of the corresponding fine scale fields. CA downscales daily large-scale data directly and BCSD downscales monthly data, with a random resampling technique to generate daily values. The methods produce comparable skill in producing downscaled, gridded fields of precipitation and temperatures at a monthly and seasonal level. For daily precipitation, both methods exhibit some skill in reproducing both observed wet and dry extremes and the difference between the methods is not significant, reflecting the general low skill in daily precipitation variability in the reanalysis data. For low temperature extremes, the CA method produces greater downscaling skill than BCSD for fall and winter seasons. For high temperature extremes, CA demonstrates higher skill than BCSD in summer. We find that the choice of most appropriate downscaling technique depends on the variables, seasons, and regions of interest, on the availability of daily data, and whether the day to day correspondence of weather from the GCM needs to be reproduced for some applications. The ability to produce skillful downscaled daily data depends primarily on the ability of the climate model to show daily skill.


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