scholarly journals Structural Disorder of Graphite and Implications for Graphite Thermometry

2017 ◽  
Author(s):  
Martina Kirilova ◽  
Virginia Toy ◽  
Jeremy S. Rooney ◽  
Carolina Giorgetti ◽  
Keith C. Gordon ◽  
...  

Abstract. Graphitization, or the progressive maturation of carbonaceous material, is considered an irreversible process. Thus, the degree of graphite crystallinity has been calibrated as an indicator of the peak metamorphic temperatures experienced by the host rocks. However, discrepancies between temperatures indicated by graphite crystallinity versus other thermometers have been documented in deformed rocks. To examine the possibility of mechanical modifications of graphite structure and the potential impacts on graphite thermometry we performed laboratory deformation experiments. We sheared highly crystalline graphite powder at normal stresses of 5 and 25 MPa and aseismic slow sliding velocities of 1 µm/s, 10 µm/s and 100 µm/s. The degree of graphite crystallinity both in the starting and resulting materials was analyzed by Raman microspectroscopy. Our results demonstrate consistent decrease of graphite crystallinity with increasing shear strain. We conclude that the calibrated graphite thermometer is ambiguous in active tectonic settings and we suggest that a calibration that accounts for shear strain is needed.

Solid Earth ◽  
2018 ◽  
Vol 9 (1) ◽  
pp. 223-231 ◽  
Author(s):  
Martina Kirilova ◽  
Virginia Toy ◽  
Jeremy S. Rooney ◽  
Carolina Giorgetti ◽  
Keith C. Gordon ◽  
...  

Abstract. Graphitization, or the progressive maturation of carbonaceous material, is considered an irreversible process. Thus, the degree of graphite crystallinity, or its structural order, has been calibrated as an indicator of the peak metamorphic temperatures experienced by the host rocks. However, discrepancies between temperatures indicated by graphite crystallinity versus other thermometers have been documented in deformed rocks. To examine the possibility of mechanical modifications of graphite structure and the potential impacts on graphite thermometry, we performed laboratory deformation experiments. We sheared highly crystalline graphite powder at normal stresses of 5 and 25  megapascal (MPa) and aseismic velocities of 1, 10 and 100 µm s−1. The degree of structural order both in the starting and resulting materials was analyzed by Raman microspectroscopy. Our results demonstrate structural disorder of graphite, manifested as changes in the Raman spectra. Microstructural observations show that brittle processes caused the documented mechanical modifications of the aggregate graphite crystallinity. We conclude that the calibrated graphite thermometer is ambiguous in active tectonic settings.


2020 ◽  
Vol 90 (11) ◽  
pp. 1581-1600
Author(s):  
Luke A. Pettinga ◽  
Zane R. Jobe

ABSTRACT Submarine landscapes, like their terrestrial counterparts, are sculpted by autogenic sedimentary processes toward morphologies at equilibrium with their allogenic controls. While submarine channels and nearby, inter-channel continental-margin areas share boundary conditions (e.g., terrestrial sediment supply, tectonic deformation), there are significant differences between the style, recurrence, and magnitude of their respective autogenic sedimentary processes. We predict that these process-based differences affect the rates of geomorphic change and equilibrium (i.e., graded) morphologies of submarine-channel and continental-margin longitudinal profiles. To gain insight into this proposed relationship, we document, classify (using machine learning), and analyze longitudinal profiles from 50 siliciclastic continental margins and associated submarine channels which represent a range of sediment-supply regimes and tectonic settings. These profiles tend to evolve toward smooth, lower-gradient longitudinal profiles, and we created a “smoothness” metric as a proxy for the relative maturity of these profiles toward the idealized equilibrium profile. Generally, higher smoothness values occur in systems with larger sediment supply, and the smoothness of channels typically exceeds that of the associated continental margin. We propose that the high rates of erosion, bypass, and deposition via sediment gravity flows act to smooth and mature channel profiles more rapidly than the surrounding continental margin, which is dominated by less-energetic diffusive sedimentary processes. Additionally, tectonic deformation will act to reduce the smoothness of these longitudinal profiles. Importantly, the relationship between total sediment supply and the difference between smoothness values of associated continental margins and submarine channels (the “smoothness Δ”) follows separate trends in passive and active tectonic settings, which we attribute to the variability in relative rates of smoothness development between channelized and inter-channel environments in the presence or absence of tectonic deformation. We propose two endmember pathways by which continental margins and submarine channels coevolve towards their respective equilibrium profiles with increased sediment supply: 1) Coupled Evolution Model (common in passive tectonic settings), in which the smoothness Δ increases only slightly before remaining static, and 2) Decoupled Evolution Model (common in active tectonic settings), in which the smoothness Δ increases more rapidly and to a greater final value. Our analysis indicates that the interaction of the allogenic factors of sediment supply and tectonic deformation with the autogenic sedimentary processes characteristic of channelized and inter-channel areas of the continental margin may account for much of the variability between coevolution pathways and depositional architectures.


2021 ◽  
Author(s):  
David Muirhead

<p>Amorphous carbonaceous materials are typically those that would be considered immature, at temperatures below 300°C, in a typical sedimentary basin burial setting. Only recently has there been much discussion on the efficacy of Raman spectroscopy on amorphous carbon at temperatures below 300°C. Here we present data from a variety of published sources alongside our own data reviewing the apparent trends in amorphous carbon with some discussion related to thermal regime (intensity, duration), with case studies including intruded host rocks, fold and thrust belts and wildfires. We conclude that Raman spectroscopy can be applied successfully to ‘low-temperature’ carbonaceous material whilst noting the challenges faced to fully understand the physio-chemical mechanisms at these temperature ranges.</p>


2015 ◽  
Vol 5 (1) ◽  
Author(s):  
Win Khant ◽  
I Wayan Warmada ◽  
Arifudin Idrus ◽  
Lucas Donny Setijadji ◽  
Koichiro Watanabe

The Soripesa prospect area is located at Maria village, Wawo district, Bima region in the eastern part of Sumbawa Island, Indonesia. This area is a part of Cenozoic Calc-alkaline volcanic inner Banda- Sunda Arc. There are five main polymetallic epithermal quartz veins in the Soripesa prospect area, namely, Rini vein, Jambu air vein, Dollah vein,Merpati vein, and Arif vein. The dominant lithology is a lithic-crystal tuff of andesitic and dacitic composition and bedded limestone. Major oxides and trace elements were analyzed by using X-Ray Fluorescence (XRF) to identify the host rock geochemistry. The main veins are hosted by andesitic and andesitic/ basaltic volcanic host rocks. Major elements compositions are affected by alteration. Based on the trace element data, host rocks of all veins were formed in the volcanic arc basalt (VAB) and island arc basalt (IAB) tectonic settings. Host rocks of Rini vein contain higher amount of precious and base metal elements (Zn, Cu, Pb, and Ag.etc.) than those of other host rocks. Keywords: Soripesa prospect area, lithology, tectonic setting, mineralization.


2009 ◽  
pp. 192-206
Author(s):  
Jean Braun ◽  
Peter van der Beek ◽  
Geoffrey Batt

2017 ◽  
Vol 88 (3) ◽  
pp. 831-839 ◽  
Author(s):  
Magali Riesner ◽  
Pauline Durand‐Riard ◽  
Judith Hubbard ◽  
Andreas Plesch ◽  
John H. Shaw

Minerals ◽  
2020 ◽  
Vol 10 (12) ◽  
pp. 1068
Author(s):  
Alessandro Croce ◽  
Enrico Pigazzi ◽  
Patrizia Fumagalli ◽  
Caterina Rinaudo ◽  
Michele Zucali

Carbonaceous materials (CMs) have been widely used to assess temperatures in sedimentary and metamorphic carbonate rocks. The use of Raman spectroscopy of carbonaceous material (RSCM) is largely devoted to the study of deformed rocks hosted in thrust-tectonic settings. Raman spectroscopy of carbonaceous material successfully allows the study of carbonate rocks at a temperature as high as 650 °C. In this study, a set of carbonate-mylonite rocks (Italian Alps) were investigated using micro-Raman spectroscopy, in order to infer the deformation conditions associated with the Alpine thrusts, expected to occur at T < 350 °C. Micro-Raman spectra were collected using two sources: green (532 nm) and red (632.8 nm) lasers. Several deconvolution procedures and parameters were tested to optimize the collected spectrum morphologies for the laser sources, also in accordance with the low temperature expected. The obtained temperatures highlight two clusters: one at 340–350 °C for the samples collected in the axial part of the Alpine chain, and the other at 200–240 °C for those collected in the external thrust-and-fold belt. These results agree with the independent geological and petrological constraints. Consistent results were obtained using 532 and 632.8 nm laser sources when the appropriate deconvolution approach was used.


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