Air-sea gas exchange at hurricane wind speeds
Abstract. Gas transfer velocities were measured in two high-speed wind-wave tanks (Kyoto University and the SUSTAIN facility, RSMAS, University of Miami) using fresh water, simulated seawater and seawater for wind speeds between 7 and 80 m s−1. Using a mass balance technique, transfer velocities of a total of 12 trace gases were measured, with dimensionless solubilities ranging from 0.005 to 150 and Schmidt numbers between 149 and 1360. This choice of tracers allowed to separate gas transfer across the free interface from gas transfer at closed bubble surfaces. The major effect found was a very steep increase of the gas transfer across the free water surface at wind speeds beyond 33 m s−1, which is the same for fresh water, simulated seawater and seawater. This steep increase might start at a lower wind speed in the open ocean as compared to the short-fetch wind-wave tanks. Bubble-induced gas transfer plays no significant role for all tracers in fresh water and for tracers with moderate solubility such as carbon dioxide and DMS in seawater, while for low solubility tracers bubble-induced gas transfer in seawater was found to be about 1.7 times larger than the transfer at the free water surface at the highest wind speed of 80 m s−1.