scholarly journals An assessment of Ozone Mini-holes Representation in Reanalyses Over the Northern Hemisphere

Author(s):  
Luis Millan ◽  
Gloria Manney

Abstract. An ozone mini-hole is a synoptic-scale region with strongly decreased total column ozone resulting from dynamical processes. Using total column measurements from the Ozone Monitoring Instrument and ozone profile measurements from the Microwave Limb Sounder, we evaluate the accuracy of mini-hole representation in five reanalyses. This study provides a metric of the reanalyses’ ability to capture dynamically-driven ozone variability. The reanalyses and the measurements show similar seasonal variability and geographical distributions of mini-holes; however, all of the reanalyses underestimate the number of mini-holes, their area, and in many reanalyses their location displays an eastward bias. The reanalyses’ underestimation of mini-hole number ranges from about 34 % to about 83 %. The mini-hole vertical representation in the reanalyses agrees well with that in the MLS measurements and, furthermore, is consistent with previously reported mechanisms for mini-hole formation. The skill of the reanalyses is not closely tied to the ozone fields assimilated, suggesting that the dynamics of the reanalysis models are more important than the assimilated ozone fields to reproducing ozone mini-holes.

2017 ◽  
Vol 17 (15) ◽  
pp. 9277-9289 ◽  
Author(s):  
Luis F. Millán ◽  
Gloria L. Manney

Abstract. An ozone mini-hole is a synoptic-scale region with strongly decreased total column ozone resulting from dynamical processes. Using total column measurements from the Ozone Monitoring Instrument and ozone profile measurements from the Microwave Limb Sounder, we evaluate the accuracy of mini-hole representation in five reanalyses. This study provides a metric of the reanalyses' ability to capture dynamically driven ozone variability. The reanalyses and the measurements show similar seasonal variability and geographical distributions of mini-holes; however, all of the reanalyses underestimate the number of mini-holes and their area, and in many reanalyses their location displays an eastward bias. The reanalyses' underestimation of mini-hole number ranges from about 34 to about 83 %. The mini-hole vertical representation in the reanalyses agrees well with that in the MLS measurements and, furthermore, is consistent with previously reported mechanisms for mini-hole formation. The skill of the reanalyses is not closely tied to the ozone fields assimilated, suggesting that the dynamics of the reanalysis models are more important than the assimilated ozone fields to reproducing ozone mini-holes.


Author(s):  
R. McPeters ◽  
M. Kroon ◽  
G. Labow ◽  
E. Brinksma ◽  
D. Balis ◽  
...  

2007 ◽  
Vol 7 (13) ◽  
pp. 3571-3578 ◽  
Author(s):  
X. Liu ◽  
K. Chance ◽  
C. E. Sioris ◽  
T. P. Kurosu

Abstract. We investigate the effect of using three different cross section data sets on ozone profile retrievals from Global Ozone Monitoring Experiment (GOME) ultraviolet measurements (289–307 nm, 326–337 nm). These include Bass-Paur, Brion, and GOME flight model cross sections (references below). Using different cross sections can significantly affect the retrievals, by up to 12 Dobson Units (DU, 1 DU=2.69×1016 molecules cm−2) in total column ozone, up to 10 DU in tropospheric column ozone, and up to 100% in retrieved ozone values for individual atmospheric layers. Compared to using the Bass-Paur and GOME flight model cross sections, using the Brion cross sections not only reduces fitting residuals by 15–60% in the Huggins bands, but also improves retrievals, especially in the troposphere, as seen from validation against ozonesonde measurements. Therefore, we recommend using the Brion cross section for ozone profile retrievals from ultraviolet measurements. The total column ozone retrieved using the GOME flight model cross sections is systematically lower, by 7–10 DU, than that retrieved using the Brion and Bass-Paur cross sections and is also systematically lower than Total Ozone Mapping Spectrometer (TOMS) observations. This study demonstrates the need for improved ozone cross section measurements in the ultraviolet to improve profile retrievals of this key atmospheric constituent.


2007 ◽  
Vol 7 (1) ◽  
pp. 971-993
Author(s):  
X. Liu ◽  
K. Chance ◽  
C. E. Sioris ◽  
T. P. Kurosu

Abstract. We investigate the effect of using three different cross section data sets on ozone profile retrievals from Global Ozone Monitoring Experiment (GOME) ultraviolet measurements (289–307 nm, 326–337 nm). These include Bass-Paur, Brion, and GOME flight model cross sections (references below). Using different cross sections can significantly affect the retrievals, by up to 12 Dobson Units (DU, 1 DU=2.69×1016 molecules cm−2) in total column ozone, up to 10 DU in tropospheric column ozone, and up to 100% in retrieved ozone values for individual atmospheric layers. Compared to using the Bass-Paur and GOME flight model cross sections, using the Brion cross sections not only reduces fitting residuals by 15–60% in the Huggins bands, but also improves retrievals, especially in the troposphere, as seen from validation against ozonesonde measurements. Therefore, we recommend using the Brion cross section for ozone profile retrievals from ultraviolet measurements. The total column ozone retrieved using the GOME flight model cross sections is systematically lower, by 7–10 DU, than that retrieved using the Brion and Bass-Paur cross sections and is also systematically lower than Total Ozone Mapping Spectrometer (TOMS) observations. This study demonstrates the need for improved ozone cross section measurements in the ultraviolet to improve profile retrievals of this key atmospheric constituent.


2019 ◽  
Vol 19 (6) ◽  
pp. 3939-3962 ◽  
Author(s):  
Antje Inness ◽  
Johannes Flemming ◽  
Klaus-Peter Heue ◽  
Christophe Lerot ◽  
Diego Loyola ◽  
...  

Abstract. The TROPOspheric Monitoring Instrument (TROPOMI) on board the Sentinel-5 Precursor (S5P) satellite launched in October 2017 yields a wealth of atmospheric composition data, including retrievals of total column ozone (TCO3) that are provided in near-real-time (NRT) and off-line. The NRT TCO3 retrievals (v1.0.0–v1.1.2) have been included in the data assimilation system of the Copernicus Atmosphere Monitoring Service (CAMS), and tests to monitor the data and to carry out first assimilation experiments with them have been performed for the period 26 November 2017 to 30 November 2018. The TROPOMI TCO3 data agree to within 2 % with the CAMS analysis over large parts of the globe between 60∘ N and 60∘ S and also with TCO3 retrievals from the Ozone Monitoring Instrument (OMI) and the Global Ozone Monitoring Experiment-2 (GOME-2) that are routinely assimilated by CAMS. However, the TCO3 NRT data from TROPOMI show some retrieval anomalies at high latitudes, at low solar elevations and over snow/ice (e.g. Antarctica and snow-covered land areas in the Northern Hemisphere), where the differences with the CAMS analysis and the other data sets are larger. These differences are particularly pronounced over land in the NH during winter and spring (when they can reach up to 40 DU) and come mainly from the surface albedo climatology that is used in the NRT TROPOMI TCO3 retrieval. This climatology has a coarser horizontal resolution than the TROPOMI TCO3 data, which leads to problems in areas where there are large changes in reflectivity from pixel to pixel, e.g. pixels covered by snow/ice or not. The differences between TROPOMI and the CAMS analysis also show some dependency on scan position. The assimilation of TROPOMI TCO3 has been tested in the CAMS system for data between 60∘ N and 60∘ S and for solar elevations greater than 10∘ and is found to have a small positive impact on the ozone analysis compared to Brewer TCO3 data and an improved fit to ozone sondes in the tropical troposphere and to IAGOS aircraft profiles at West African airports. The impact of the TROPOMI data is relatively small because the CAMS analysis is already well constrained by several other ozone retrievals that are routinely assimilated. When averaged over the periods February–April and September–October 2018, differences between experiments with and without assimilation of TROPOMI data are less than 2 % for TCO3 and less than 3 % in the vertical for seasonal mean zonal mean O3 mixing ratios, with the largest relative differences found in the troposphere.


2007 ◽  
Vol 7 (6) ◽  
pp. 1575-1583 ◽  
Author(s):  
X. Liu ◽  
K. Chance ◽  
T. P. Kurosu

Abstract. We present a simple method to perform degradation correction to Global Ozone Monitoring Experiment (GOME) reflectance spectra by comparing the average reflectance for 60° N–60° S with that at the beginning of GOME observations (July–December 1995) after removing the dependences on solar zenith angle and seasonal variation. The results indicate positive biases of up to ~15–25% in the wavelength range 289–370 nm during 2000–2002; the degradation also exhibits significant dependence on wavelength and viewing zenith angle. These results are consistent with previous studies using radiative transfer models and ozone observations. The degradation causes retrieval biases of up to ~3% (10 DU, 1 DU=2.69×1016 molecules cm−2), 30% (10 DU), 10%, and 40% in total column ozone, tropospheric column ozone, stratospheric ozone and tropospheric ozone, respectively, from our GOME ozone profile retrieval algorithm. In addition, retrieval biases due to degradation vary significantly with latitude. The application of this degradation correction improves the retrievals relative to Dobson and ozonesonde measurements at Hohenpeißenberg station during 2000–2003 and improves the spatiotemporal consistency of retrieval quality during 1996–2003. However, because this method assumes that the deseasonalized globally-averaged reflectance does not change much with time, retrievals with this correction may be inadequate for trend analysis. In addition, it does not correct for instrument biases that have occurred since launch.


2015 ◽  
Vol 8 (8) ◽  
pp. 3407-3418 ◽  
Author(s):  
J. Herman ◽  
R. Evans ◽  
A. Cede ◽  
N. Abuhassan ◽  
I. Petropavlovskikh ◽  
...  

Abstract. A comparison of retrieved total column ozone (TCO) amounts between the Pandora #34 spectrometer system and the Dobson #061 spectrophotometer from direct-sun observations was performed on the roof of the Boulder, Colorado, NOAA building. This paper, part of an ongoing study, covers a 1-year period starting on 17 December 2013. Both the standard Dobson and Pandora TCO retrievals required a correction, TCOcorr = TCO (1 + C(T)), using a monthly varying effective ozone temperature, TE, derived from a temperature and ozone profile climatology. The correction is used to remove a seasonal difference caused by using a fixed temperature in each retrieval algorithm. The respective corrections C(TE) are CPandora = 0.00333(TE-225) and CDobson = -0.0013(TE-226.7) per degree K. After the applied corrections removed most of the seasonal retrieval dependence on ozone temperature, TCO agreement between the instruments was within 1 % for clear-sky conditions. For clear-sky observations, both co-located instruments tracked the day-to-day variation in total column ozone amounts with a correlation of r2 = 0.97 and an average offset of 1.1 ± 5.8 DU. In addition, the Pandora TCO data showed 0.3 % annual average agreement with satellite overpass data from AURA/OMI (Ozone Monitoring Instrument) and 1 % annual average offset with Suomi-NPP/OMPS (Suomi National Polar-orbiting Partnership, the nadir viewing portion of the Ozone Mapper Profiler Suite).


2016 ◽  
Author(s):  
Jiyoung Kim ◽  
Jhoon Kim ◽  
Hi-Ku Cho ◽  
Jay Herman ◽  
Sang Seo Park ◽  
...  

Abstract. Daily total column ozone (TCO) measured using the Pandora spectrophotometer (#19) was intercompared with data from the Dobson (#124) and Brewer (#148) spectrophotometers, as well as from the Ozone Monitoring Instrument (OMI), over the 2-year period between March 2012 and March 2014 at Yonsei University, Seoul, Korea. The Pandora TCO measurements are closely correlated with those from the Dobson, Brewer, and OMI instruments with regression coefficients (slopes) of 0.95, 1.00, 0.98 (OMI-TOMS), and 0.97 (OMI-DOAS), respectively, and determination coefficients (R2) of 0.95, 0.97, 0.96 (OMI-TOMS), and 0.95 (OMI-DOAS), respectively. In particular, they show a close agreement with the Brewer TCO measurements, with slope and R2 values of 1.00 and 0.97, respectively. The difference between the Pandora and Dobson data can be explained by smaller amount of Dobson data available to calculate the daily averages, observation times, solar zenith angles, SO2 effect, temperature, and humidity between the two datasets. The difference in the results obtained from the Pandora instrument and Ozone Monitoring Instrument-Differential Optical Absorption Spectroscopy (OMI-DOAS algorithm) can be explained by the dependence on seasonal variations of about ± 2 % and solar zenith angle leading to overestimation by 5 % of OMI-DOAS measurements. For the Dobson measurements in particular, the difference caused by the inconsistency in observation times when compared with the Pandora measurements was up to 12.5 % on 22 June 2013 because of diurnal variations in the TCO values. However, despite these various differences and discrepancies, the daily TCO values measured by the four instruments during the 2-year study period are accurate and closely correlated.


2010 ◽  
Vol 10 (3) ◽  
pp. 6797-6827 ◽  
Author(s):  
M. Antón ◽  
V. E. Cachorro ◽  
J. M. Vilaplana ◽  
C. Toledano ◽  
N. A. Krotkov ◽  
...  

Abstract. The main objective of this study is to compare the erythemal UV irradiance (UVER) and spectral UV irradiances (at 305, 310 and 324 nm) from Ozone Monitoring Instrument (OMI) onboard NASA EOS/Aura polar sun-synchronous satellite (launched in July 2004, local equator crossing time 01:45 p.m.) with ground-based measurements from the Brewer spectroradiometer #150 located at El Arenosillo (South of Spain). The analyzed period comprises more than four years, from October 2004 to December 2008. The effects of several factors (clouds, aerosols, ozone and the solar elevation) on OMI-Brewer comparisons were analyzed. The proxies used for each factor were: OMI Lambertian Equivalent Reflectivity (LER) at 360 nm (clouds), the Aerosol Optical Depth (AOD) at 440 nm measured from the ground-based Cimel sun-photometer (http://aeronet.gsfc.nasa.gov), OMI total column ozone, and solar elevation at OMI overpass time. The comparison for all sky conditions reveals positive biases (OMI higher than Brewer) 12.3% for UVER, 14.2% for UV irradiance at 305 nm, 10.6% for 310 nm and 8.7% for 324 nm. The OMI-Brewer Root Mean Square Error (RMSE) is reduced when cloudy cases are removed from the analysis, (e.g., RMSE ~20% for all sky conditions and RMSE smaller than 10% for cloud-free conditions). However, the biases remain and even become more significant for the cloud-free cases with respect to all sky conditions. The mentioned overestimation is clearly documented as due to aerosol extinction influence. The differences OMI-Brewer typically decrease with increasing the Solar Zenith Angle (SZA). The seasonal dependence of the OMI-Brewer difference for cloud-free conditions is driven by aerosol climatology. To account for the aerosol effect, a first evaluation in order to compare with previous TOMS results (Anton et al., 2007) was performed. This comparison shows that the OMI bias is between +14% and +19% for UVER and spectral UV irradiances for moderately-high aerosol load (AOD>0.25). The OMI bias is decreased by a factor of 2 (the typical bias varies from +8% to +12%) under cloud-free and low aerosol load conditions (AOD<0.1). More detailed analysis of absorbing aerosols influence on OMI bias at our station is presented in a companion paper (Cachorro et al., 2010).


2015 ◽  
Vol 33 (9) ◽  
pp. 1135-1146 ◽  
Author(s):  
A. M. Toihir ◽  
H. Bencherif ◽  
V. Sivakumar ◽  
L. El Amraoui ◽  
T. Portafaix ◽  
...  

Abstract. This paper presents comparison results of the total column ozone (TCO) data product over 13 southern tropical and subtropical sites recorded from the Infrared Atmospheric Sounder Interferometer (IASI) onboard the EUMETSAT (European organization for the exploitation of METeorological SATellite) MetOp (Meteorological Operational satellite program) satellite. TCO monthly averages obtained from IASI between June 2008 and December 2012 are compared with collocated TCO measurements from the Ozone Monitoring Instrument (OMI) on the OMI/Aura satellite and the Dobson and SAOZ (Système d'Analyse par Observation Zénithale) ground-based instruments. The results show that IASI displays a positive bias with an average less than 2 % with respect to OMI and Dobson observations, but exhibits a negative bias compared to SAOZ over Bauru with a bias around 2.63 %. There is a good agreement between IASI and the other instruments, especially from 15° S southward where a correlation coefficient higher than 0.87 is found. IASI exhibits a seasonal dependence, with an upward trend in autumn and a downward trend during spring, especially before September 2010. After September 2010, the autumn seasonal bias is considerably reduced due to changes made to the retrieval algorithm of the IASI level 2 (L2) product. The L2 product released after August (L2 O3 version 5 (v5)) matches TCO from the other instruments better compared to version 4 (v4), which was released between June 2008 and August 2010. IASI bias error recorded from September 2010 is estimated to be at 1.5 % with respect to OMI and less than ±1 % with respect to the other ground-based instruments. Thus, the improvement made by O3 L2 version 5 (v5) product compared with version 4 (v4), allows IASI TCO products to be used with confidence to study the distribution and interannual variability of total ozone in the southern tropics and subtropics.


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