scholarly journals Growth of nucleation mode particles in the summertime Arctic: a case study

2016 ◽  
Author(s):  
Megan D. Willis ◽  
Julia Burkart ◽  
Jennie L. Thomas ◽  
Franziska Köllner ◽  
Johannes Schneider ◽  
...  
Keyword(s):  
Cloud Condensation Nuclei ◽  
Methanesulfonic Acid ◽  
Lower Troposphere ◽  
Atmospheric Conditions ◽  
Radiative Balance ◽  
Cloud Properties ◽  
Marine Influence ◽  
20 Nm ◽  
Growth Event

Abstract. The summertime Arctic lower troposphere is a relatively pristine, background aerosol environment dominated by nucleation and Aitken mode particles. Understanding the mechanisms that control the formation and growth of aerosol is crucial for our ability to predict cloud properties, and therefore radiative balance and climate. We present an analysis of an aerosol growth event observed in the Canadian Arctic Archipelago during summer as part of the NETCARE project. Under stable and clean atmospheric conditions, with low inversion heights, carbon monoxide less than 80 ppbv and black carbon less than 5 ng m−3, we observe growth of small particles, < 20 nm in diameter, into sizes above 50 nm. Aerosol growth was correlated with the presence of organic species, trimethylamine and methanesulfonic acid (MSA) in particles ~ 80 nm and larger, where the organics are similar to those previously observed in marine settings. MSA-to-sulfate ratios as high as 0.15 were observed during aerosol growth, suggesting an important marine influence. The organic-rich aerosol contributes significantly to particles active as cloud condensation nuclei (CCN, supersaturation = 0.6 %), which are elevated in concentration during aerosol growth above background levels of ~ 100 cm3 to ~ 220 cm

scholarly journals Growth of nucleation mode particles in the summertime Arctic: a case study

2016 ◽  
Vol 16 (12) ◽  
pp. 7663-7679 ◽  
Author(s):  
Megan D. Willis ◽  
Julia Burkart ◽  
Jennie L. Thomas ◽  
Franziska Köllner ◽  
Johannes Schneider ◽  
...  
Keyword(s):  
Cloud Condensation Nuclei ◽  
Methanesulfonic Acid ◽  
Lower Troposphere ◽  
Atmospheric Conditions ◽  
Aerosol Formation ◽  
Radiative Balance ◽  
Nucleation Mode ◽  
Cloud Properties ◽  
Marine Influence

Abstract. The summertime Arctic lower troposphere is a relatively pristine background aerosol environment dominated by nucleation and Aitken mode particles. Understanding the mechanisms that control the formation and growth of aerosol is crucial for our ability to predict cloud properties and therefore radiative balance and climate. We present an analysis of an aerosol growth event observed in the Canadian Arctic Archipelago during summer as part of the NETCARE project. Under stable and clean atmospheric conditions, with low inversion heights, carbon monoxide less than 80 ppbv, and black carbon less than 5 ng m−3, we observe growth of small particles,  <  20 nm in diameter, into sizes above 50 nm. Aerosol growth was correlated with the presence of organic species, trimethylamine, and methanesulfonic acid (MSA) in particles ∼ 80 nm and larger, where the organics are similar to those previously observed in marine settings. MSA-to-sulfate ratios as high as 0.15 were observed during aerosol growth, suggesting an important marine influence. The organic-rich aerosol contributes significantly to particles active as cloud condensation nuclei (CCN, supersaturation  =  0.6 %), which are elevated in concentration during aerosol growth above background levels of ∼ 100 to ∼ 220 cm−3. Results from this case study highlight the potential importance of secondary organic aerosol formation and its role in growing nucleation mode aerosol into CCN-active sizes in this remote marine environment.

Arctic fog chemistry induces the unexpected growth of Aitken mode particles to CCN-active particles

2021 ◽  
Author(s):  
Erik H. Hoffmann ◽  
Andreas Tilgner ◽  
Simonas Kecorius ◽  
Hartmut Herrmann
Keyword(s):  
Growth Mechanism ◽  
Marine Boundary Layer ◽  
Cloud Condensation Nuclei ◽  
Methanesulfonic Acid ◽  
Particle Growth ◽  
High Water ◽  
The Arctic ◽  
Radiative Balance ◽  
Active Particles ◽  
Aitken Mode

&lt;p&gt;New particle formation (NPF) and early growth are efficient processes producing high concentrations of cloud condensation nuclei (CCNs) precursors in the Arctic marine boundary layer (AMBL). However, due to short lifetime and lack of condensable vapors, newly formed particles do often not grow beyond 50 nm and cause low CCN particle concentrations in the AMBL. Thus, even the smallest amount of Aitken mode particle growth is capable to significantly increase the CCN budget. However, the growth mechanism of Aitken-mode particles from NPF into CCN range in the Arctic is still rather unclear and was therefore investigated during the cruise campaign PASCAL in 2017.&lt;/p&gt; &lt;p&gt;During PASCAL, aerosol particles measurements were performed and an unexpected rapid growth of Aitken mode particles was observed right after fog episodes. Combined field data analyses and detailed multiphase chemistry box model simulations with the CAPRAM mechanism were performed to study the underlying processes. Resulting, a new mechanism is proposed explaining how particles with d &lt; 50 nm are able to grow into CCN size range in the Arctic without requiring high water vapor supersaturation (SS). The investigations demonstrated that the rapid post-fog particle growth of Aitken mode is related to chemical processes within the Arctic fog. The redistribution of semi-volatile acidic (e.g., methanesulfonic acid) and basic (e.g., ammonia) compounds from processed CCN-active particles to smaller CCN-inactive particles can cause a rapid particle growth of Aitken mode particles after fog evaporation enabling them to grow towards CCN size. Comparisons of the model results with Berner impactor measurements supports the proposed growth mechanism.&lt;/p&gt; &lt;p&gt;Overall, this study provided new insights on how the increasing frequency of NPF and fog-related particle processing can increase in the number of CCNs and cloud droplets leading to an increased albedo of Arctic clouds and thus affect the radiative balance in the Arctic. Since fogs will occur more frequently in the Arctic as a result of climate change, this growth mechanism and a deeper knowledge on its feedbacks can be essential to understand Arctic warming.&lt;/p&gt;

scholarly journals Ocean Aerobiology

2021 ◽  
Vol 12 ◽  
Author(s):  
Alyssa N. Alsante ◽  
Daniel C. O. Thornton ◽  
Sarah D. Brooks
Keyword(s):  
Organic Matter ◽  
Atmospheric Transport ◽  
Cloud Condensation Nuclei ◽  
Marine Microorganisms ◽  
Atmospheric Conditions ◽  
Cloud Properties ◽  
Marine Organic Matter ◽  
Living Organisms ◽  
Earth’S Climate ◽  
Microbial Habitat

Ocean aerobiology is defined here as the study of biological particles of marine origin, including living organisms, present in the atmosphere and their role in ecological, biogeochemical, and climate processes. Hundreds of trillions of microorganisms are exchanged between ocean and atmosphere daily. Within a few days, tropospheric transport potentially disperses microorganisms over continents and between oceans. There is a need to better identify and quantify marine aerobiota, characterize the time spans and distances of marine microorganisms’ atmospheric transport, and determine whether microorganisms acclimate to atmospheric conditions and remain viable, or even grow. Exploring the atmosphere as a microbial habitat is fundamental for understanding the consequences of dispersal and will expand our knowledge of biodiversity, biogeography, and ecosystem connectivity across different marine environments. Marine organic matter is chemically transformed in the atmosphere, including remineralization back to CO2. The magnitude of these transformations is insignificant in the context of the annual marine carbon cycle, but may be a significant sink for marine recalcitrant organic matter over long (∼104 years) timescales. In addition, organic matter in sea spray aerosol plays a significant role in the Earth’s radiative budget by scattering solar radiation, and indirectly by affecting cloud properties. Marine organic matter is generally a poor source of cloud condensation nuclei (CCN), but a significant source of ice nucleating particles (INPs), affecting the formation of mixed-phase and ice clouds. This review will show that marine biogenic aerosol plays an impactful, but poorly constrained, role in marine ecosystems, biogeochemical processes, and the Earth’s climate system. Further work is needed to characterize the connectivity and feedbacks between the atmosphere and ocean ecosystems in order to integrate this complexity into Earth System models, facilitating future climate and biogeochemical predictions.

scholarly journals Summertime observations of ultrafine particles and cloud condensation nuclei from the boundary layer to the free troposphere in the Arctic

2016 ◽  
Author(s):  
Julia Burkart ◽  
Megan D. Willis ◽  
Heiko Bozem ◽  
Jennie L. Thomas ◽  
Kathy Law ◽  
...  
Keyword(s):  
Boundary Layer ◽  
Ultrafine Particles ◽  
Cloud Condensation Nuclei ◽  
Particle Diameter ◽  
Open Ocean ◽  
The Arctic ◽  
Condensation Nuclei ◽  
Aerosol Composition ◽  
Low Level ◽  
20 Nm

Abstract. The Arctic is extremely sensitive to climate change. Shrinking sea ice extent increases the area covered by open ocean during Arctic summer, which impacts the surface albedo and aerosol and cloud properties among many things. In this context extensive aerosol measurements (aerosol composition, particle number and size, cloud condensation nuclei, and trace gases) were made during 11 flights of the NETCARE July, 2014 airborne campaign conducted from Resolute Bay, Nunavut (74N, 94W). Flights routinely included vertical profiles from about 60 to 3000 m a.g.l. as well as several low-level horizontal transects over open ocean, fast ice, melt ponds, and polynyas. Here we discuss the vertical distribution of ultrafine particles (UFP, particle diameter, dp: 5–20 nm), size distributions of larger particles (dp: 20 nm to 1 μm), and cloud condensation nuclei (CCN, supersaturation = 0.6 %) in relation to meteorological conditions and underlying surfaces. UFPs were observed predominantly within the boundary layer, where concentrations were often several hundreds to a few thousand particles per cubic centimeter. Occasionally, particle concentrations below 10 cm−3 were found. The highest UFP concentrations were observed above open ocean and at the top of low-level clouds, whereas numbers over ice-covered regions were substantially lower. Overall, UFP formation events were frequent in a clean boundary layer with a low condensation sink. In a few cases this ultrafine mode extended to sizes larger than 40 nm, suggesting that these UFP can grow into a size range where they can impact clouds and therefore climate.

scholarly journals Molecular-level evidence for marine aerosol nucleation of iodic acid and methanesulfonic acid

2021 ◽  
Author(s):  
An Ning ◽  
Ling Liu ◽  
Lin Ji ◽  
Xiuhui Zhang
Keyword(s):  
Molecular Level ◽  
Methanesulfonic Acid ◽  
Field Studies ◽  
Nucleation Mechanism ◽  
Polar Regions ◽  
Atmospheric Conditions ◽  
Iodic Acid ◽  
Quantum Chemical Approach ◽  
Marine Areas ◽  
First Time

Abstract. Both iodic acid (HIO3, IA) and methanesulfonic acid (CH3S(O)2OH, MSA) have been identified by field studies as important precursors of new particle formation (NPF) in marine areas. However, the mechanism of NPF in which IA and MSA are jointly involved is still unclear. Hence, we investigated the IA-MSA nucleation system under different atmospheric conditions and uncovered the corresponding nucleating mechanism at a molecular level for the first time using quantum chemical approach and Atmospheric Cluster Dynamics Code (ACDC). The findings showed that MSA can stabilize IA clusters via both hydrogen and halogen bonds. Moreover, the joint nucleation rate of IA-MSA system is significantly higher than that of IA self-nucleation, particularly in relatively cold marine regions with sparse IA and rich MSA. For the IA-MSA nucleation mechanism, in addition to self-nucleation of IA, the IA-MSA-involved clusters can also directly participate in the nucleation process, and their contribution is particularly prominent in the polar regions with rich MSA and sparse IA. The IA-MSA nucleation mechanism revealed in this work may help to elucidate some missing sources of marine NPF.

scholarly journals Effects of cosmic ray decreases on cloud microphysics

2012 ◽  
Vol 12 (2) ◽  
pp. 3595-3617 ◽  
Author(s):  
J. Svensmark ◽  
M. B. Enghoff ◽  
H. Svensmark
Keyword(s):  
Cloud Condensation Nuclei ◽  
Cosmic Ray ◽  
Liquid Water Content ◽  
Total Solar Irradiance ◽  
Cloud Microphysics ◽  
Forbush Decreases ◽  
Cloud Data ◽  
Sigma Level ◽  
Cloud Properties ◽  
Simple Equations

Abstract. Using cloud data from MODIS we investigate the response of cloud microphysics to sudden decreases in galactic cosmic radiation – Forbush decreases – and find responses in effective emissivity, cloud fraction, liquid water content, and optical thickness above the 2–3 sigma level 6–9 days after the minimum in atmospheric ionization and less significant responses for effective radius and cloud condensation nuclei (<2 sigma). The magnitude of the signals agree with derived values, based on simple equations for atmospheric parameters. Furthermore principal components analysis gives a total significance of the signal of 3.1 sigma. We also see a correlation between total solar irradiance and strong Forbush decreases but a clear mechanism connecting this to cloud properties is lacking. There is no signal in the UV radiation. The responses of the parameters correlate linearly with the reduction in the cosmic ray ionization. These results support the suggestion that ions play a significant role in the life-cycle of clouds.

scholarly journals Atmospheric ionization and cloud radiative forcing

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Henrik Svensmark ◽  
Jacob Svensmark ◽  
Martin Bødker Enghoff ◽  
Nir J. Shaviv
Keyword(s):  
Radiative Forcing ◽  
Cloud Condensation Nuclei ◽  
Short Wave ◽  
Satellite Observations ◽  
Cloud Formation ◽  
Wave Radiation ◽  
Substantial Impact ◽  
Radiative Balance ◽  
Cloud Radiative Forcing ◽  
Atmospheric Ionization

AbstractAtmospheric ionization produced by cosmic rays has been suspected to influence aerosols and clouds, but its actual importance has been questioned. If changes in atmospheric ionization have a substantial impact on clouds, one would expect to observe significant responses in Earth’s energy budget. Here it is shown that the average of the five strongest week-long decreases in atmospheric ionization coincides with changes in the average net radiative balance of 1.7 W/m$$^2$$ 2 (median value: 1.2 W/m$$^2$$ 2 ) using CERES satellite observations. Simultaneous satellite observations of clouds show that these variations are mainly caused by changes in the short-wave radiation of low liquid clouds along with small changes in the long-wave radiation, and are almost exclusively located over the pristine areas of the oceans. These observed radiation and cloud changes are consistent with a link in which atmospheric ionization modulates aerosol's formation and growth, which survive to cloud condensation nuclei and ultimately affect cloud formation and thereby temporarily the radiative balance of Earth.

scholarly journals Variation of diurnal Turbulence Kinetic Energy using sonic anemometer observation: a case study Ledeng, Bandung

2018 ◽  
Author(s):  
Sandy Hardian Susanto Herho ◽  
Dasapta Erwin Irawan
Keyword(s):  
Kinetic Energy ◽  
Diurnal Variation ◽  
Wind Velocity ◽  
Sonic Anemometer ◽  
Diurnal Variations ◽  
Turbulence Kinetic Energy ◽  
Atmospheric Conditions

Sonic anemometer observation was performed on 29 - 30 September 2014 in Ledeng, Bandung to see diurnal variations of Turbulence Kinetic Energy (TKE) that occurred in this area. The measured sonic anemometer was the wind velocity components u, v, and w. From the observation result, it can be seen that the diurnal variation that happened was quite significant. The maximum TKE occurs during the daytime when atmospheric conditions tend to be unstable. TKE values were small at night when atmospheric conditions are more stable than during the daytime.

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