Gamma radiolytic synthesis of poly(2, 3-Epoxy-propylmethacrylate)-stabilized-gold nanoparticles: an efficient catalyst for p-nitrophenol reduction

2018 ◽  
Vol 3 (4) ◽  
pp. 199-205
Author(s):  
Nilanjal Misra
2016 ◽  
Vol 3 (4) ◽  
pp. 629-637 ◽  
Author(s):  
Adriana Both Engel ◽  
Mikhael Bechelany ◽  
Olivier Fontaine ◽  
Aziz Cherifi ◽  
David Cornu ◽  
...  

ChemCatChem ◽  
2014 ◽  
Vol 7 (1) ◽  
pp. 99-106 ◽  
Author(s):  
Yasushi Imada ◽  
Motonari Osaki ◽  
Mikiko Noguchi ◽  
Takatoshi Maeda ◽  
Misa Fujiki ◽  
...  

RSC Advances ◽  
2020 ◽  
Vol 10 (33) ◽  
pp. 19419-19424
Author(s):  
Yue Zhu ◽  
Juan Du ◽  
Qianqian Peng ◽  
Fengyi Wang ◽  
Jing Hu ◽  
...  

Due to the serious pollution issue caused by 4-nitrophenol (4-NP), it is of great importance to design effective catalysts for its reduction.


2014 ◽  
Vol 1641 ◽  
Author(s):  
Maolin Li ◽  
Vivian Zhong ◽  
Guofang Chen

ABSTRACTRaspberry-like composite spheres based on chemically-reactive poly(glycidyl methacrylate) (PGMA) colloids as the cores coated with tunable size of gold nanoparticles were synthesized via a controlled assembly method. Kinetic study of 4-nitrophenol reduction by NaBH4 in the presence of poly(allylamine hydrochloride)-modified PGMA composite with tunable size of AuNPs (PGMA@PAH@AuNPs) was demonstrated. Effects of gold nanoparticles size and PGMA colloid diameter on the reaction time, average reaction rate and average turnover frequency (TOF), order of reaction (n) and apparent rate constant (kapp) were systematically investigated. Experimental results of our study showed composites with 3.4 ± 0.9 nm AuNPs have the best catalytic efficiency with the highest reaction order and apparent rate constant. The poisoning of product 4-aminophenol on PAH-modified PGMA colloid-supported gold nanocatalysts was evaluated using 4-nitrophenol/NaBH4 reduction reaction for the reaction time, average reaction rate, average TOF, order of reaction and apparent rate constant.


2015 ◽  
Vol 5 (7) ◽  
pp. 3682-3692 ◽  
Author(s):  
Yuchao Li ◽  
Lei Wang ◽  
Ruiyi Yan ◽  
Junxing Han ◽  
Suojiang Zhang

Au nanoparticles supported on Ce0.6Zr0.4O2solid solution with high reducibility and basicity is an efficient catalyst for oxidative esterification.


2020 ◽  
Vol 13 (07) ◽  
pp. 2051040
Author(s):  
Vahid Rahimkhoei ◽  
Ali Akbari ◽  
Maryam Zirak ◽  
Bagher Eftekhari-Sis

Ag nanoparticles were synthesized and stabilized on a polymeric support, poly([Formula: see text]-isopropyl acrylamide-co-itaconic acid)/POSS, by simply reducing Ag[Formula: see text] ions adsorbed in the interior of the polymeric network. The prepared Ag@p(NIPAM-IA)/POSS was used as an efficient and recyclable catalyst for removal of the 4-nitrophenol (4-NP) contaminant by NaBH4-induced reduction to 4-aminophenol (4-AP) in aqueous solution. Different conditions including Ag content and amount of the nanocomposite, and also temperature of the 4-NP reduction were investigated. Also, two kinetic models, zero-order and first-order kinetics, were studied for the reduction of 4-NP to 4-AP.


2015 ◽  
Vol 10 (1) ◽  
Author(s):  
Shufen Wu ◽  
Songjing Yan ◽  
Wei Qi ◽  
Renliang Huang ◽  
Jing Cui ◽  
...  

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