scholarly journals Electrodialysis of Sulfuric Acid with Cation-Exchange Membranes Prepared by Electron-Beam-Induced Graft Polymerization

2011 ◽  
Vol 22 (2) ◽  
pp. 53-57 ◽  
Author(s):  
Yuki ASARI ◽  
Nobuyoshi SHOJI ◽  
Kazuyoshi MIYOSHI ◽  
Daisuke UMENO ◽  
Kyoichi SAITO
2011 ◽  
Vol 396-398 ◽  
pp. 75-87
Author(s):  
Zai Fu Yang ◽  
Xiao Jing Yang ◽  
Li Hong Sun ◽  
Lian Lian Xu

ABSTRACT: Cation adsorbent was prepared from the Solidago Canadensis(which are abandoned agricultural land of alien invasive plants)by Sulfuric acid esterification modified , isoamyl alcohol as reaction medium. Design L934 orthogonal experiment, the Solidago canadensis cation exchange adsorbent, the optimal preparation conditions. Experimental results show that at 15°C, concentrated sulfuric acid and amyl alcohol volume ratio of 5:6 obtained under conditions of Solidago canadensis cation exchange adsorbent for Pb(II) exchange best. The experimental results of Pb(II) adsorption onto the Solidago Canadensis based cation adsorbent showed that the best conditions are: the initial pH 5, the concentration of Pb(II) 300mg/L,the dosage of cation adsorbent 1.2mg/L and adsorption time 3h. The adsorption data were analyzed by using pseudo-first-order and pseudo-second-order kinetic models were found to follow the pseudo-second-order kinetic model.


2006 ◽  
Vol 284 (1-2) ◽  
pp. 67-78 ◽  
Author(s):  
Le Xuan Tuan ◽  
M. Verbanck ◽  
C. Buess-Herman ◽  
H.D. Hurwitz

2018 ◽  
Vol 74 (7) ◽  
pp. 150-157
Author(s):  
Koji Miyazaki ◽  
Kouji Notoh ◽  
Takuya Honda ◽  
Zhanglian Xu ◽  
Kazumasa Hirogaki ◽  
...  

Polymers ◽  
2020 ◽  
Vol 12 (2) ◽  
pp. 343 ◽  
Author(s):  
Dong Wang ◽  
Wenqiao Meng ◽  
Yunna Lei ◽  
Chunxu Li ◽  
Jiaji Cheng ◽  
...  

To improve sulfuric acid recovery from sodium sulfate wastewater, a lab-scale bipolar membrane electrodialysis (BMED) process was used for the treatment of simulated sodium sulfate wastewater. In order to increase the concentration of sulfuric acid (H2SO4) generated during the process, a certain concentration of ammonium sulfate solution was added into the feed compartment. To study the influencing factors of sulfuric acid yield, we prepared different concentrations of ammonium sulfate solution, different feed solution volumes, and different membrane configurations in this experiment. As it can be seen from the results, when adding 8% (NH4)2SO4 into 15% Na2SO4 under the experimental conditions where the current density was 50 mA/cm2, the concentration of H2SO4 increased from 0.89 to 1.215 mol/L, and the current efficiency and energy consumption could be up to 60.12% and 2.59 kWh/kg, respectively. Furthermore, with the increase of the volume of the feed compartment, the concentration of H2SO4 also increased. At the same time, the configuration also affects the final concentration of the sulfuric acid; in the BP-A-C-BP (“BP” means bipolar membrane, “A” means anion exchange membrane, and “C” means cation exchange membrane; “BP-A-C-BP” means that two bipolar membranes, an anion exchange membrane, and a cation exchange membrane are alternately arranged to form a repeating unit of the membrane stack) configuration, a higher H2SO4 concentration was generated and less energy was consumed. The results show that the addition of the double conjugate salt is an effective method to increase the concentration of acid produced in the BMED process.


2015 ◽  
Vol 26 (49) ◽  
pp. 495301 ◽  
Author(s):  
Lindsay Boehme ◽  
Matthew Bresin ◽  
Aurélien Botman ◽  
James Ranney ◽  
J Todd Hastings

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