scholarly journals Highly Sensing Properties Sensors Based on Ce-doped ZnO and SnO2 Nanoparticles to Ethanol Gas

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R. Yoo ◽  
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Yunji Park ◽  
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Hyun Jun Rim ◽  
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R.K. Shukla ◽  
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Mamta Pandey

2019 ◽  
Vol 124 ◽  
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Author(s):  
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Junli Pan ◽  
Jianghong Tang ◽  
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Shouli Bai ◽  
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Nanomaterials ◽  
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Vol 9 (3) ◽  
pp. 351 ◽  
Author(s):  
Dongping Xue ◽  
Junjun Wang ◽  
Yan Wang ◽  
Guang Sun ◽  
Jianliang Cao ◽  
...  

Methane detection is extremely difficult, especially at low temperatures, due to its high chemical stability. Here, WO3 nanosheets loaded with SnO2 nanoparticles with a particle size of about 2 nm were prepared by simple impregnation and subsequent calcination using SnO2 and WO3·H2O as precursors. The response of SnO2-loaded WO3 nanosheet composites to methane is about 1.4 times higher than that of pure WO3 at the low optimum operating temperature (90 °C). Satisfying repeatability and long-term stability are ensured. The dominant exposed (200) crystal plane of WO3 nanosheets has a good balance between easy oxygen chemisorption and high reactivity at the dangling bonds of W atoms, beneficial for gas-sensing properties. Moreover, the formation of a n–n type heterojunction at the SnO2-WO3 interface and additionally the increase of specific surface area and defect density via SnO2 loading enhance the response further. Therefore, the SnO2-WO3 composite is promising for the development of sensor devices to methane.


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