scholarly journals The Determination of Temperatures of Light Sources for the Spectroscopic Analysis from Spectra

1964 ◽  
Vol 13 (1) ◽  
pp. 1-6 ◽  
Author(s):  
Research Group Concerning Spectrosc ◽  
Hiroshi KAWAGUCHI
Keyword(s):  
Spectroscopic Analysis ◽  
Light Sources

Structure determination of altemicidin by nmr spectroscopic analysis

Tetrahedron ◽  
1991 ◽  
Vol 47 (22) ◽  
pp. 3621-3632 ◽  
Author(s):  
Atsushi Takahashi ◽  
Hiroshi Naganawa ◽  
Daishiro Ikeda ◽  
Yoshiro Okami
Keyword(s):  
Structure Determination ◽  
Spectroscopic Analysis

scholarly journals PTPS Candidate Exoplanet Host Star Radii Determination with CHARA Array

2011 ◽  
Vol 7 (S282) ◽  
pp. 203-204
Author(s):  
Paweł Zieliński ◽  
Martin Vaňko ◽  
Ellyn Baines ◽  
Andrzej Niedzielski ◽  
Aleksander Wolszczan
Keyword(s):  
Effective Temperature ◽  
Critical Parameter ◽  
Spectroscopic Analysis ◽  
Evolutionary Model ◽  
Stellar Mass ◽  
Surface Temperatures ◽  
Penn State ◽  
Chara Array ◽  
Model Dependency

AbstractWe propose to measure the radii of the Penn State - Toruń Planet Search (PTPS) exoplanet host star candidates using the CHARA Array. Stellar radii estimated from spectroscopic analysis are usually inaccurate due to indirect nature of the method and strong evolutionary model dependency. Also, the so-called degeneracy of stellar evolutionary tracks due to convergence of many tracks in the giant branch decreases the precision of such estimates. However, the radius of a star is a critical parameter for the calculation of stellar luminosity and mass, which are often not well known especially for giants. With well determined effective temperature (from spectroscopy) and radius, the luminosity may be calculated precisely. In turn also stellar mass may be estimated much more precisely. Therefore, direct radii measurements increase precision in the determination of planetary candidates masses and the surface temperatures of the planets.

scholarly journals New palladium–oxazoline complexes: Synthesis and evaluation of the optical properties and the catalytic power during the oxidation of textile dyes

2015 ◽  
Vol 11 ◽  
pp. 1175-1186 ◽  
Author(s):  
Rym Hassani ◽  
Mahjoub Jabli ◽  
Yakdhane Kacem ◽  
Jérôme Marrot ◽  
Damien Prim ◽  
...  
Keyword(s):  
Optical Properties ◽  
Spectroscopic Analysis ◽  
Palladium Complexes ◽  
X Ray Diffraction ◽  
Factors Affecting ◽  
Enantiomerically Pure ◽  
One Step ◽  
Uv Visible ◽  
High Yields

The present paper describes the synthesis of new palladium–oxazoline complexes in one step with good to high yields (68–95%). The oxazolines were prepared from enantiomerically pure α-aminoalcohols. The structures of the synthesized palladium complexes were confirmed by NMR, FTIR, TOFMS, UV–visible spectroscopic analysis and X–ray diffraction. The optical properties of the complexes were evaluated by the determination of the gap energy values (E g) ranging between 2.34 and 3.21 eV. Their catalytic activities were tested for the degradation of Eriochrome Blue Black B (a model of azo dyes) in the presence of an ecological oxidant (H2O2). The efficiency of the decolorization has been confirmed via UV–visible spectroscopic analysis and the factors affecting the degradation phenomenon have been studied. The removal of the Eriochrome reached high yields. We have found that the complex 9 promoted 84% of color elimination within 5 min (C 0 = 30 mg/L, T = 22 °C, pH 7, H2O2 = 0.5 mL) and the energetic parameters have been also determined.

scholarly journals Multivariate Analysis of Photoacoustic Spectra for the Detection of Short-Chained Hydrocarbon Isotopologues

Molecules ◽  
2020 ◽  
Vol 25 (9) ◽  
pp. 2266 ◽  
Author(s):  
Alain Loh ◽  
Marcus Wolff
Keyword(s):  
Multivariate Analysis ◽  
Continuous Wave ◽  
Light Sources ◽  
Least Squares Regression ◽  
Detection Scheme ◽  
Concentration Determination ◽  
Multiple Measurements ◽  
Interband Cascade Lasers ◽  
Cascade Lasers

We report, to our knowledge, the first optical detection scheme for short-chained hydrocarbon isotopologues. The sensor system is based on photoacoustic spectroscopy (PAS). Two continuous wave, thermoelectrically cooled, distributed feedback interband cascade lasers (DFB-ICLs) with emission wavelengths around 3.33 and 3.38 μm, respectively, served as light sources. The investigations comprised the main stable carbon isotopologues of methane (12CH4, 13CH4), ethane (12CH3-12CH3, 13CH3-12CH3, 13CH3-13CH3), and propane (12CH3-12CH2-12CH3, 13CH3-12CH2-12CH3). They were selected because of their importance for numerous applications from climate and planetary research to natural gas exploration. Multiple measurements of single components in nitrogen and synthetic mixtures were conducted at room temperature and atmospheric pressure. Depending on the investigated hydrocarbon isotopologue, detection limits ranging from 0.043 ppmv to 3.4 ppmv were achieved. For a selective concentration determination, multivariate analysis (MVA) was applied. Partial least-squares regression (PLSR) was used to calculate concentrations from the PA spectra. The implementation of MVA has shown that the PA setup in principle works reliably and that the selective concentration determination of short-chained hydrocarbon isotopologues is possible.

scholarly journals Determination of Cr (VI) Content in Water-Soluble Dyes

2020 ◽  
Vol 59 (1) ◽  
pp. 88-94
Author(s):  
M P Sathianarayanan ◽  
Rina Nayak ◽  
Yogesh Hande
Keyword(s):  
Spectroscopic Analysis ◽  
Extraction Procedure ◽  
Cost Effective ◽  
High Load ◽  
Water Soluble ◽  
Recovery Study ◽  
Good Repeatability ◽  
Repeatability And Reproducibility ◽  
Standard Solution

Abstract Hexavalent chromium detection in the presence of high load of colorants is a challenge, and it is an important area of study. Colorants are a class of interfering substance in many spectroscopic analysis and chromatographic separation and detection. In this study, a method has been developed to separate out Cr (VI) and water-soluble dyes by using activated charcoal as an absorption medium. The extraction procedure was optimized with Cr (VI) standard solution for quantification. The efficacy of the extraction procedure for the removal of water-soluble dyes and detection of Cr (VI) was checked with a spike recovery study. Based on the spike recovery study, the method has been validated as per the international validation protocol. The method is simple, cost effective and has a detection limit down up to 3.0 mg/kg. The recovery rate of Cr (VI) in water-soluble dyes like reactive yellow HE 6G, reactive red 218, turquoise blue HGN, reactive navy blue RX and reactive black 5A was found to be more than 90% with a good repeatability and reproducibility.

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