scholarly journals Effects of Excitation Conditions on Line Intensity in Spectrochemical Analysis of Nitralloy

1961 ◽  
Vol 10 (1) ◽  
pp. 45-56
Author(s):  
Kouichi YOSHINO ◽  
Shoushiro SAKAI ◽  
Masao KANEKO
1987 ◽  
Vol 31 ◽  
pp. 449-454
Author(s):  
James R. Bogert

One of the strongest analytical qualities of energy-dispersive x-ray fluorescence (EDXRF) is the wide range of analyte elements that can be detected and analyzed. Historically, the technique has covered all the elements from sodium (Z=11) and above. A useful measure of specific spectrometer performance is analyte sensitivity. X-ray spectrometric sensitivity is usually expressed in terms of minimum detectable amount of analyte or rate of change of analyte line intensity with change in amount of analyte. Many factors affect analyte sensitivity in EDXRF. These include excitation conditions, specimen conditions, system geometry, atmosphere, detector and readout conditions, and of course the specific analyte line. Typically, EDXRF sensitivity is very good, and low ppm concentrations of analytes are routinely analyzed–until one encounters the light elements.


1975 ◽  
Vol 22 (6) ◽  
pp. 841-843
Author(s):  
R. R. Shvangiradze ◽  
I. L. Vysokova ◽  
O. A. Grishutina

1959 ◽  
Vol 3 ◽  
pp. 109-129
Author(s):  
William J. Campbell

AbstractLine intensity and background measurements were made on the K lines for the elements with atomic numbers 16 to 60, L lines for the elements above atomic number 42, and M lines for elements above atomic number 80. Three general classes of samples were investigated: (1) infinitely thick, (2) microgram deposits, and (3) thin layers.These studies show that longer-wavelength L radiation may be preferable to the K series lines from the same element in the range of elements with atomic numbers 42 to 60, In particular the Lα lines are more intense than the K series lines from Class 2 and 3 samples. With Class 1 samples the Lα lines are weaker than the K series but their line-to-background ratio is superior to the K series.M series lines show little promise for spectrochemical analysis except for elements with atomic numbers 90 to 92; for example, with uranium samples in Class 2 and 3, the very high line-to-background ratio of the UMβ1 line may have limited application.Elements with atomic numbers from 16 to 22 are more sensitive than expected due to the very high line-to-background ratios and the reduced collimation requirements in this longwavelength region.


2014 ◽  
Vol 37 (2) ◽  
pp. 433-452 ◽  
Author(s):  
Ronan Higgins ◽  
David Teyssier ◽  
Colin Borys ◽  
Jonathan Braine ◽  
Claudia Comito ◽  
...  

Author(s):  
G Y Liang ◽  
X L Zhu ◽  
H G Wei ◽  
D W Yuan ◽  
J Y Zhong ◽  
...  

Abstract Charge-exchange has been recognized as a primary source of soft x-ray emission in many astrophysical outflow environments, including cometary and planetary exospheres impacted by solar wind. Some models have been setup by using different data collections of charge-exchange cross-sections. However, multiple electron transfer has not been included in these models. In this paper, we setup a charge exchange model with the inclusion of double-electron capture, and make a detailed investigation of this process on x-ray emissions of highly charged carbon, nitrogen, oxygen and neon ions by using available experimental cross-sections. We also study the effect of different n −selective cross-sections on soft x-ray emission by using available experimental n −distributions. This work reveals that double electron capture enhancement on line intensity is basically linearly proportional to the ratio of ion abundance in the solar wind. It is more obvious for soft x-rays from carbon ions (C4 +) in collision with CO2, and the enhancement on line intensity can be up to 53 per cent with typical ion abundances (ace observation) in solar wind. The synthetic spectra with parameters from the Ulysses mission for solar wind reveals velocity-dependence, target-dependence, as well as the non-negligible contribution from the double-electron capture.


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