Initiation of stress corrosion cracking in cold-drawn prestressing steel in hardened cement mortar exposed to chlorides

CORROSION ◽  
10.5006/3730 ◽  
2021 ◽  
Author(s):  
Dyana Joseline ◽  
Radhakrishna Pillai ◽  
Lakshman Neelakantan

Cold-drawn, high strength, prestressing (PS) steel strands are widely used in pretensioned concrete (PTC) structures. This paper discusses the stress corrosion cracking (SCC) of PS steel embedded in cement mortar and gradually exposed to chlorides. Various stages of the passive to active (P-to-A) transition, which marks the onset of SCC, were investigated using EIS technique. The key mechanisms were identified and confirmed using SEM/EDAX, XRD and Confocal Raman Spectroscopy. It was found that the passive film on unstressed PS steel has better electrochemical characteristics than that on conventional steel rebars. However, the residual tensile stress at the surface of PS steels can assist passive film cracking after chloride attack - contrary to the pitting corrosion without cracking of passive film in conventional steels. Further, tests indicated that the concentration of chlorides required to crack the passive film in PS steels can reduce by about 50% when prestressed – as in field structures. Chemical composition, stress state and microstructural features at the PS steel surface were identified as possible factors influencing the initiation of SCC in PTC structures.

1993 ◽  
Vol 34 (6) ◽  
pp. 961-973 ◽  
Author(s):  
M.C. Alonso ◽  
R.P.M. Procter ◽  
C. Andrade ◽  
M. Sáenz de Santa María

CORROSION ◽  
10.5006/3822 ◽  
2021 ◽  
Author(s):  
yang Zhao ◽  
Yuchen Liu ◽  
Xin Gai ◽  
Yun Bai ◽  
Tao Zhang ◽  
...  

The stress corrosion cracking (SCC) susceptibility of electron beam melted Ti-6Al-4V alloy (ET) was compared with the conventional wrought alloy (WT). The electrochemical and slow strain rate tensile (SSRT) tests, as well as surface analysis, were conducted under simulated shallow and deep-sea environment. Under shallow conditions, the SCC susceptibility of both alloys was almost the same because of consistent passivation and re-passivation performance of the passivating film. However, under deep-sea conditions, SCC susceptibility of ET was higher than that of WT due to stronger textured-like surface that appeared on ET alloy, where early developed passive film broke down, demonstrating lower passivation and re-passivation rate.


2015 ◽  
Vol 24 (10) ◽  
pp. 3773-3782
Author(s):  
R. Rihan ◽  
M. Basha ◽  
A. Al-Meshari ◽  
A. Bayramov ◽  
G. van Zyl ◽  
...  

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