Insight into the Effect of Mg(OH)2 Films versus Nobel Element Enrichment on the Global and Local Cathodic Activation of Corroding Mg

CORROSION ◽  
10.5006/3634 ◽  
2020 ◽  
Author(s):  
Taylor Cain ◽  
Carol Glover ◽  
Jamie Laird ◽  
Nick Birbilis ◽  
John Scully
Keyword(s):  
Noble Metal ◽  
High Purity ◽  
Metal Enrichment ◽  
X Ray ◽  
Aqueous Environments ◽  
Element Enrichment ◽  
Global And Local ◽  
Insight Into ◽  
Selection Of ◽  
Dissolution Product

The anodically enhanced cathodic activation of high purity Mg was studied by global and local electrochemical measurements in unbuffered 0.6 M NaCl, 0.6 M NaCl saturated in Mg(OH)2, 0.1 M MgCl2, 0.1 M Na2SO4 and 0.1 M Tris(hydroxymethyl)aminomethane hydrochloride (TRIS). The selection of diverse aqueous environments was deliberate, in order to explore the effect of dissolution product upon subsequent cathodic activation. Cathodic activation was found to be strong in all of the chloride-containing environments where a porous hydroxide forms, weak in Na2SO4 where a denser more compact hydroxide forms, and negligible in TRIS where no hydroxide forms. Elemental enrichment, mapped using micro particle induced X-ray emission (PIXE), revealed the enrichment of Fe only in Cl- containing environments suggesting that noble metal enrichment provides a stronger influence on cathodic activation than that of Mg(OH)2 films.

Experiments using a light gas gun to investigate the impact melting of gunshot residue analogues

2019 ◽  
Author(s):  
V. Spathis ◽  
M. C. Price
Keyword(s):  
Physical State ◽  
Gunshot Residue ◽  
Ignition Process ◽  
X Ray ◽  
Gas Gun ◽  
High Purity Silicon ◽  
The University ◽  
The Impact ◽  
Insight Into ◽  
Selection Of

Abstract In this set of experiments, the versatility of the University of Kent's light gas gun was utilised to obtain a selection of corroborative data regarding the formation and impact of metallic gunshot residues onto high purity silicon wafers. The results from the two experiments are presented. The first experiment investigated how the formation of metallic residues varied as gunshot residue analogues traversed through air under a range of pressures from 0.056 millibar (5.6 Pa) to 1 bar (100 kPa), using solely the energy released during primer ignition; the second involved firing a metallic powder mix of pre-determined composition (via a split-sabot) under vacuum at two velocities- 500 ms-1 and 2000 ms-1. This ensured that there was no ignition or heating of the powders, unlike the first experiment, and so the morphology of the particles collected would be solely due to impact. The residues on the substrates were then analysed using a cold Field Emission Gun Scanning Electron Microscope (FEG) and Energy Dispersive X-ray (EDX) detector. By separating the ignition process of the primers from the residue impacts, it allows for a closer look into the formation of these particles and helps determine whether their varied morphologies are due to the heating caused during the activation and combustion of the primer or whether its due to impact melting. This information can aid in the understanding of metallic particle formation in different pressure environments and give insight into the physical state of firearm residues when they impact a surface. Hydrocode modelling was also incorporated to corroborate the results observed during these experiments and gave results which mimicked the experimental data.

Characterization of Perovskite-Like Substrates for Thin Film Superconductors using Synchrotron X-Ray Topography

1991 ◽  
Vol 35 (A) ◽  
pp. 255-261
Author(s):  
G.-D. Yao ◽  
S.Y. Hon ◽  
M. Dudley ◽  
Julia M. Phillips
Keyword(s):  
Defect Formation ◽  
Chemical Properties ◽  
Substrate Material ◽  
Formation Mechanisms ◽  
X Ray ◽  
Physical And Chemical ◽  
Insight Into ◽  
Selection Of ◽  
Potential Substrate

AbstractThe characterization of defect configurations in various perovskite-like substrate materials for high Tc superconductor epitaxial films has been conducted using white beam synchrotron X-ray topography. The substrates were found to contain crystal lattice defects such as twins, dislocations and grain boundaries. It is shown that characterization of substrates can potentially afford insight into factors controlling the properties of the high Tc superconductor tilms supported on them. This can help in the selection of optimum substrate material. Defect formation mechanisms in individual materials as well as their respective influences on the films are discussed. Comparisons between the physical and chemical properties of several potential substrate materials are presented.

High-purity Ge x-ray detectors: Sensitivity factors and usefulness

1990 ◽  
Vol 48 (2) ◽  
pp. 548-548
Author(s):  
E. B. Steel
Keyword(s):  
High Purity ◽  
High Energy ◽  
Quantitative Chemical Analysis ◽  
Detector Performance ◽  
X Ray ◽  
Detector Sensitivity ◽  
Specimen Holder ◽  
Many Instruments ◽  
Charge Resolution ◽  
Sensitivity Factors

High Purity Germanium (HPGe) x-ray detectors are now commercially available for the analytical electron microscope (AEM). The detectors have superior efficiency at high x-ray energies and superior resolution compared to traditional lithium-drifted silicon [Si(Li)] detectors. However, just as for the Si(Li), the use of the HPGe detectors requires the determination of sensitivity factors for the quantitative chemical analysis of specimens in the AEM. Detector performance, including incomplete charge, resolution, and durability has been compared to a first generation detector. Sensitivity factors for many elements with atomic numbers 10 through 92 have been determined at 100, 200, and 300 keV. This data is compared to Si(Li) detector sensitivity factors.The overall sensitivity and utility of high energy K-lines are reviewed and discussed. Many instruments have one or more high energy K-line backgrounds that will affect specific analytes. One detector-instrument-specimen holder combination had a consistent Pb K-line background while another had a W K-line background.

Quantitative Analysis Of X-Ray Images From Geological Materials

1990 ◽  
Vol 48 (2) ◽  
pp. 244-245
Author(s):  
J. M. Paque ◽  
R. Browning ◽  
P. L. King ◽  
P. Pianetta
Keyword(s):  
Quantitative Analysis ◽  
Bulk Composition ◽  
Principal Component ◽  
Analytical Description ◽  
Bulk Sample ◽  
Geological Samples ◽  
X Ray ◽  
Software And Hardware ◽  
And Storage ◽  
Insight Into

Geological samples typically contain many minerals (phases) with multiple element compositions. A complete analytical description should give the number of phases present, the volume occupied by each phase in the bulk sample, the average and range of composition of each phase, and the bulk composition of the sample. A practical approach to providing such a complete description is from quantitative analysis of multi-elemental x-ray images.With the advances in recent years in the speed and storage capabilities of laboratory computers, large quantities of data can be efficiently manipulated. Commercial software and hardware presently available allow simultaneous collection of multiple x-ray images from a sample (up to 16 for the Kevex Delta system). Thus, high resolution x-ray images of the majority of the detectable elements in a sample can be collected. The use of statistical techniques, including principal component analysis (PCA), can provide insight into mineral phase composition and the distribution of minerals within a sample.

Copper–oxygen Dynamics in Tyrosinase

2019 ◽  
Author(s):  
Nobutaka Fujieda ◽  
Sachiko Yanagisawa ◽  
Minoru Kubo ◽  
Genji Kurisu ◽  
Shinobu Itoh
Keyword(s):  
Catalytic Mechanism ◽  
Substrate Binding ◽  
Active Form ◽  
Copper Ion ◽  
Atomic Resolution ◽  
Oxygen Species ◽  
X Ray ◽  
Oxygen Dynamics ◽  
Insight Into ◽  
Copper Centre

To unveil the activation of dioxygen on the copper centre (Cu<sub>2</sub>O<sub>2</sub>core) of tyrosinase, we performed X-ray crystallograpy with active-form tyrosinase at near atomic resolution. This study provided a novel insight into the catalytic mechanism of the tyrosinase, including the rearrangement of copper-oxygen species as well as the intramolecular migration of copper ion induced by substrate-binding.<br>

An Insight into Oligopeptide Transporter 3 (OPT3) family proteins

2020 ◽  
Vol 27 ◽  
Author(s):  
Fırat Kurt
Keyword(s):  
Stress Responses ◽  
Chelating Agent ◽  
Biological Processes ◽  
Biotic And Abiotic Stress ◽  
Oligopeptide Transporter ◽  
Binding Residues ◽  
Fe Homeostasis ◽  
Proteins Interactions ◽  
Insight Into ◽  
Selection Of

: Oligopeptide transporter 3 (OPT3) proteins are one of the subsets of OPT clade, yet little is known about these transporters. Therefore, homolog OPT3 proteins in several plant species were investigated and characterized using bioinformatical tools. Motif and co-expression analyses showed that OPT3 proteins may be involved in both biotic and abiotic stress responses as well as growth and developmental processes. AtOPT3 usually seemed to take part in Fe homeostasis whereas ZmOPT3 putatively interacted with proteins involved in various biological processes from plant defense system to stress responses. Glutathione (GSH), as a putative alternative chelating agent, was used in the AtOPT3 and ZmOPT3 docking analyses to identify their putative binding residues. The information given in this study will contribute to the understanding of OPT3 proteins’ interactions in various pathways and to the selection of potential ligands for OPT3s.

scholarly journals Chemical Recycling of WEEE Plastics—Production of High Purity Monocyclic Aromatic Chemicals

Processes ◽  
2021 ◽  
Vol 9 (3) ◽  
pp. 530
Author(s):  
Tobias Rieger ◽  
Jessen C. Oey ◽  
Volodymyr Palchyk ◽  
Alexander Hofmann ◽  
Matthias Franke ◽  
...  
Keyword(s):  
High Purity ◽  
Fractional Distillation ◽  
Gas Chromatography Mass Spectrometry ◽  
Thermochemical Conversion ◽  
Chemical Recycling ◽  
Pyrolysis Oil ◽  
X Ray ◽  
Benzene Toluene ◽  
Halogen Content ◽  
Methyl Styrene

More than 200 kg real waste electrical and electronic equipment (WEEE) shredder residues from a German dismantling plant were treated at 650 °C in a demonstration scale thermochemical conversion plant. The focus within this work was the generation, purification, and analysis of pyrolysis oil. Subsequent filtration and fractional distillation were combined to yield basic chemicals in high purity. By means of fractional distillation, pure monocyclic aromatic fractions containing benzene, toluene, ethylbenzene, and xylene (BTEX aromatics) as well as styrene and α-methyl styrene were isolated for chemical recycling. Mass balances were determined, and gas chromatography–mass spectrometry (GC-MS) as well as energy dispersive X-ray fluorescence (EDXRF) measurements provided data on the purity and halogen content of each fraction. This work shows that thermochemical conversion and the subsequent refining by fractional distillation is capable of recycling WEEE shredder residues, producing pure BTEX and other monocyclic aromatic fractions. A significant decrease of halogen content (up to 99%) was achieved with the applied methods.

scholarly journals Suppression of X-ray-Induced Radiation Damage to Biomolecules in Aqueous Environments by Immediate Intermolecular Decay of Inner-Shell Vacancies

2021 ◽  
pp. 7146-7150
Author(s):  
Andreas Hans ◽  
Philipp Schmidt ◽  
Catmarna Küstner-Wetekam ◽  
Florian Trinter ◽  
Sascha Deinert ◽  
...  
Keyword(s):  
Radiation Damage ◽  
X Ray ◽  
Aqueous Environments
Sign in / Sign up

Export Citation Format

Share Document