Corrosion Behavior of SiCp/6061 Al Metal Matrix Composites

CORROSION ◽  
1991 ◽  
Vol 47 (10) ◽  
pp. 741-753 ◽  
Author(s):  
H. Sun ◽  
E. Y. Koo ◽  
H. G. Wheat

Abstract The corrosion behavior of silicon carbide/aluminum (SiCp/Al) metal matrix composites was studied in chloride solution by means of electrochemical techniques, scanning electron microscopy (SEM), Auger electron spectroscopy (AES), energy dispersive spectroscopy (EDS), and X-ray diffraction. The materials under investigation were powder metallurgy (P/M) processed 6061 Al reinforced with increasing amounts of SiC particles (15 to 40 vol%). Electrochemical tests such as potentiodynamic polarization were done in 0.035, 0.35, and 3.5% NaCl solutions that were open to air, aerated, or deaerated to observe overall corrosion behavior. In addition, pit morphology was observed after anodic polarization to a number of potentials. It was seen that the corrosion potentials did not vary greatly or show definite trends in relation to the amounts of SiCp reinforcement. However, the degree of corrosion increased with increasing SiCp content and the presence or absence of oxygen as well as the concentration of the NaCl solution did affect corrosion potentials. Microscopic analysis techniques were used to study the corroded samples and the extensive pitting and exfoliation of the surfaces. X-ray diffraction was used to identify the compounds on the surface of the corroded samples as well as the flakes due to exfoliation.

2017 ◽  
Vol 51 (30) ◽  
pp. 4165-4175 ◽  
Author(s):  
Klaudia Lichtenberg ◽  
Eric Orsolani-Uhlig ◽  
Ralf Roessler ◽  
Kay André Weidenmann

The reinforcement of a soft matrix material with hard particles is an established strategy to develop materials with tailored properties. In this regard, using metallic glasses with high crystallization temperatures, e.g. in the system NiNbX (X = Sn, Ta), for composites produced by liquid metal infiltration is a novel approach. The current work deals with the characterization of such metallic glass particle-reinforced AlSi10Mg-based metal matrix composites manufactured by gas pressure infiltration. Processing–structure–property relations were investigated with a special focus on the influence of an additional heat treatment on the metal matrix composite’s properties. Metallographic methods were used to investigate infiltration quality, particle distribution within the composite and the composite’s microstructure. Moreover, X-ray diffraction measurements, elastic analysis using ultrasonic spectroscopy and compression tests were performed to analyze its properties. The X-ray diffraction results indicate that there is no crystallization of the glass during processing. Metallographic investigations show that the flakes are arranged in a layered structure within the composite. The embedding of metallic glass flakes leads to an increase in Young’s modulus and compressive strength in comparison to the unreinforced material. The composite’s strength can be further increased by a heat treatment.


2012 ◽  
Vol 191 ◽  
pp. 189-198 ◽  
Author(s):  
Anita Olszówka-Myalska ◽  
Sam A. McDonald ◽  
Philip J. Withers ◽  
Hanna Myalska ◽  
Grzegorz Moskal

Metal matrix composites comprising a magnesium matrix and Mg2Si/MgO dispersoids obtained by hot pressing silica nanoparticle agglomerates and metal powder in a Degussa press were characterized. Two powder mixtures having weight proportions of Mg:SiO2 of 10:0.3 and 10:1 were identically sintered. Their microstructures were characterized by optical microscopy and X-ray diffraction. The size and distribution of the Mg2Si and MgO dispersoids formed in situ were assessed as a function of the original nanosilica content. The behaviour of the composites under compression testing was assessed in 3D by X-ray microtomography using 225kV Nikon X-tek and 150kV Xradia MicroXCT scanners. This provided insights into composite strengthening mechanisms and matrix particle decohesion.


Materials ◽  
2018 ◽  
Vol 11 (10) ◽  
pp. 1979 ◽  
Author(s):  
Jing Zhang ◽  
Shibo Li ◽  
Shujun Hu ◽  
Yang Zhou

Ti3C2Tx MXene, a new 2D nanosheet material, is expected to be an attractive reinforcement of metal matrix composites because its surfaces are terminated with Ti and/or functional groups of –OH, –O, and –F which improve its wettability with metals. Thus, new Ti3C2Tx/Al composites with strong interfaces and novel properties are desired. To prepare such composites, the chemical stability of Ti3C2Tx with Al at high temperatures should be investigated. This work first reports on the chemical stability of Ti3C2Tx MXene with Al in the temperature range 500–700 °C. Ti3C2Tx is thermally stable with Al at temperatures below 700 °C, but it reacts with Al to form Al3Ti and TiC at temperatures above 700 °C. The chemical stability and microstructure of the Ti3C2Tx/Al samples were investigated by differential scanning calorimeter, X-ray diffraction analysis, scanning electron microscopy, and transmission electron microscopy.


2020 ◽  
Vol 1002 ◽  
pp. 161-174
Author(s):  
Nawal Mohammed Dawood

Aluminium as matrix in particulars have been vastlys investigateds, this is becauses of the diverses applicationss of aluminium dues to its exceptional propertiess. Material scientistss alwayss face a challenges when it comess to the tribologicals and mechanicals propertiess of aluminium, as it exudess rather poors behaviours in these aspectss. Hences this works aims to improves the mechanicals and corrosives resistances of Aluminiums by reinforcings with aluminum oxides and Nickel throughs stir casting usings vortex techniques. Al-Ni-Al2O3 composites with percentages of Ni fixed at 20 % and Al2O3 differed through 4-8% in incrementss of 2 wt. % . Composites material was prepareds by stir castings using vortex techniques. The hardness value of the aluminiums matrix composites improved with increaseds percentages of Al2O3, maximums increase was obtaineds for 8% Al2O3 composite, viewing an increases of about 55%. A generals corrosions and erosion-corrosions for the Al-20%Ni bases alloys and the prepareds composites were carrieds out in 3.5wt% NaCl solutions as corrosives mediums for general corrosions while in erosion-corrosions with impacts angles 90° in slurry solutions ( 1wt%SiO2 sand in 3.5wt% NaCl solution as the erodent). It was founds that the general corrosions rates for composite specimens is lower than thats of the bases alloy (Al-20%Ni). In case of erosion-corrosion resultss, it was founds that the erosion corrosions resistances property of the prepareds composites improveds significantlys with the increaseds percentages of Al2O3. There wass a noticeable improvements in the corrosion resistances of the aluminiums composites compareds to its purest forms, owing to the presences of nickel. Howevers, the increases in Al2O3 percentages decrease the corrosions rates. The extreme decreases was obtaineds for 8% Al2O3 composites, with a decreases of 26% corrosion rates in (mpy) unit for composites material is lowers than that of the bases alloys.


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