A Study of the Inhibiting Action of Benzene Thiols and Related Compounds on the Corrosion of Zinc in Acidic Media

CORROSION ◽  
1981 ◽  
Vol 37 (10) ◽  
pp. 557-563 ◽  
Author(s):  
M. S. Abdel Aal ◽  
A. A. Abdel Wahab ◽  
A. El Saied

Abstract The effect of benzenethiol and its methyl, amino, and carboxylic ring substituted derivatives, benzylthiol and thioglycollic acid on the electrochemical and corrosion behavior of zinc in CH3COOH, H2SO4, and HCl solutions was studied using the galvanostatic technique. In CH3COOH, compounds which function by an adsorption mechanism were found to have inhibitive effects on the corrosion of zinc, while those functioning by surface chelation were ineffective. In H2SO4 and HCl, with the exception of o-methylbenzenethiol (H2SO4 and HCl) and benzylthiol (H2SO4), all investigated compounds were found to accelerate zinc dissolution. Adsorption of the inhibitors followed the Langmuir isotherm, and the mechanism of both the hydrogen evolution reaction and zinc dissolution were found to be the same in the uninhibited and inhibited states.

2020 ◽  
Vol 525 ◽  
pp. 146623 ◽  
Author(s):  
Hongjiao Huang ◽  
Junnan Song ◽  
Deshuang Yu ◽  
Yanan Hao ◽  
Yonghan Wang ◽  
...  

2020 ◽  
Vol 8 (32) ◽  
pp. 16582-16589 ◽  
Author(s):  
Xulei Sui ◽  
Lei Zhang ◽  
Junjie Li ◽  
Kieran Doyle-Davis ◽  
Ruying Li ◽  
...  

A facile in situ ion-exchanging strategy directly enhances metal–support interactions between Pt and support and promotes HER electrocatalytic performance in acidic media.


Author(s):  
Karthi keyan Arjunan ◽  
Rajakumaran Ramachandran ◽  
Sakthinathan Subramanian ◽  
Shen-Ming Chen ◽  
Te-Wei Chiu ◽  
...  

ACS Catalysis ◽  
2018 ◽  
Vol 8 (10) ◽  
pp. 9456-9462 ◽  
Author(s):  
Sebastian Watzele ◽  
Johannes Fichtner ◽  
Batyr Garlyyev ◽  
Jan N. Schwämmlein ◽  
Aliaksandr S. Bandarenka

RSC Advances ◽  
2021 ◽  
Vol 11 (14) ◽  
pp. 8073-8079
Author(s):  
Jack. P. Hughes ◽  
Samuel Rowley-Neale ◽  
Craig Banks

We report the fabrication and optimisation of Fe3P bulk modified screen-printed electrochemical platforms (SPEs), enhancing their performance towards the hydrogen evolution reaction (HER), within acidic media, by the application of a magentic field.


2018 ◽  
Vol 9 (25) ◽  
pp. 5640-5645 ◽  
Author(s):  
Zhaomin Hao ◽  
Shishuai Yang ◽  
Jingyang Niu ◽  
Zhiqiang Fang ◽  
Liangliang Liu ◽  
...  

Transition-metal Mo-based materials have been considered to be among the most effective hydrogen evolution reaction (HER) electrocatalysts.


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