Long-Term Prediction of Localized Corrosion of Alloy 825 in High-Level Nuclear Waste Repository Environments

CORROSION ◽  
1996 ◽  
Vol 52 (2) ◽  
pp. 115-124 ◽  
Author(s):  
D. S. Dunn ◽  
N. Sridhar ◽  
G. A. Cragnolino
Keyword(s):  
Nuclear Waste ◽  
Localized Corrosion ◽  
Nuclear Waste Repository ◽  
Term Prediction ◽  
High Level Nuclear Waste ◽  
Waste Repository ◽  
High Level ◽  
Long Term Prediction

Comparison of Granite, Tuff, and Basalt as Geologic Media for Long-Term Storage of High-Level Nuclear Waste

1990 ◽  
Vol 212 ◽  
Author(s):  
D. E. Grandstaff ◽  
V. J. Grassi ◽  
A. C. Lee ◽  
G. C. Ulmer
Keyword(s):  
Nuclear Waste ◽  
Nuclear Waste Repository ◽  
Long Term Storage ◽  
Hydrothermal Experiments ◽  
Ion Activity ◽  
Activity Ratios ◽  
High Level Nuclear Waste ◽  
High Level ◽  
Term Storage

ABSTRACTSystematic differences in pH, cation/proton ion activity ratios, and redox have been observed between solutions produced in rock-water hydrothermal experiments with tuff, granite, and basalt. Stable pH values in tuff-water experiments may be as much as 1.5 pH units more acidic than basalt-water experiments at the same temperature and ionic strength. Redox (log fO2) values in 300°C tuff experiments are 4–7 orders of magnitude more oxidizing than basalt experiments and ca. 4 log units more oxidizing than the magnetite-hematite buffer. Such fluid differences could significantly affect the performance of a high-level nuclear waste repository and should be considered in repository design and siting.

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