Kinetics of Corrosion Layer Formation: Part 1—Iron Carbonate Layers in Carbon Dioxide Corrosion

CORROSION ◽  
2008 ◽  
Vol 64 (4) ◽  
pp. 334-346 ◽  
Author(s):  
W. Sun ◽  
S. Nešić
Keyword(s):  
Carbon Dioxide ◽  
Corrosion Layer ◽  
Carbon Dioxide Corrosion ◽  
Layer Formation ◽  
Iron Carbonate ◽  
Kinetics Of

scholarly journals Iron carbonate formation kinetics onto corroding and pre-filmed carbon steel surfaces in carbon dioxide corrosion environments

2019 ◽  
Vol 469 ◽  
pp. 135-145 ◽  
Author(s):  
R. Barker ◽  
I. Al Shaaili ◽  
R.A. De Motte ◽  
D. Burkle ◽  
T. Charpentier ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Carbon Steel ◽  
Carbon Dioxide Corrosion ◽  
Iron Carbonate ◽  
Carbonate Formation ◽  
Formation Kinetics ◽  
Steel Surfaces

Kinetics of compact layer formation and growth of 1,10-phenanthroline at the electrode surface

1990 ◽  
Vol 87 ◽  
pp. 1597-1607 ◽  
Author(s):  
L Benedetti ◽  
M Borsari ◽  
C Fontanesi ◽  
G Battistuzzi Gavioli
Keyword(s):  
Electrode Surface ◽  
Layer Formation ◽  
Compact Layer ◽  
Kinetics Of

Kinetics of temperature-programmed reactivation of a hydrodesulphurization catalyst

1983 ◽  
Vol 48 (12) ◽  
pp. 3340-3355 ◽  
Author(s):  
Pavel Fott ◽  
Pavel Šebesta
Keyword(s):  
Carbon Dioxide ◽  
Thermal Analysis ◽  
Differential Thermal Analysis ◽  
Thin Layer ◽  
Kinetic Parameters ◽  
Diffusion Region ◽  
Reaction Heat ◽  
Gaseous Products ◽  
Temperature Programmed ◽  
Kinetics Of

The kinetic parameters of reactivation of a carbonized hydrodesulphurization (HDS) catalyst by air were evaluated from combined thermogravimetric (TG) and differential thermal analysis (DTA) data. In addition, the gaseous products leaving a temperature-programmed reactor with a thin layer of catalyst were analyzed chromatographically. Two exothermic processes were found to take part in the reactivation, and their kinetics were described by 1st order equations. In the first process (180-400 °C), sulphur in Co and Mo sulphides is oxidized to sulphur dioxide; in the second process (300-540 °C), in which the essential portion of heat is produced, the deposited carbon is oxidized to give predominantly carbon dioxide. If the reaction heat is not removed efficiently enough, ignition of the catalyst takes place, which is associated with a transition to the diffusion region. The application of the obtained kinetic parameters to modelling a temperature-programmed reactivation is illustrated on the case of a single particle.

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