Effects of Chloride Ion Addition on the Pickling of Hot-Rolled Steels in Fluoboric Acid Solution

CORROSION ◽  
2003 ◽  
Vol 59 (2) ◽  
pp. 146-154 ◽  
Author(s):  
K.-H. Na ◽  
S.-I. Pyun ◽  
J.-J. Park ◽  
J.-H. Ryu ◽  
Y.-S. Jin
Keyword(s):  
Acid Solution ◽  
Chloride Ion ◽  
Fluoboric Acid ◽  
Hot Rolled

Surface-Enhanced Raman Scattering and Atomic Force Microscopy of Brass Electrodes in Sulfuric Acid Solution Containing Benzotriazole and Chloride Ion

1993 ◽  
Vol 47 (1) ◽  
pp. 80-84 ◽  
Author(s):  
Joel C. Rubim ◽  
Jae-Ho Kim ◽  
Eric Henderson ◽  
Therese M. Cotton
Keyword(s):  
Atomic Force Microscopy ◽  
Sulfuric Acid ◽  
Raman Scattering ◽  
Acid Solution ◽  
Chloride Ion ◽  
Force Microscopy ◽  
Atomic Force ◽  
Surface Enhanced ◽  
Surface Enhanced Raman ◽  
Enhanced Raman Scattering

Three different methods were used to roughen brass (Cu/Zn = 67/33) electrodes in 0.5 M H2SO4 containing 1.0 mM benzotriazole (BTAH): (1) polarization at +0.05 V vs. saturated calomel for 5 min; (2) immersion in the above solution for six hours; and (3) oxidation-reduction cycling in the presence of chloride ion. The surfaces prepared by the first two methods exhibited surface-enhanced Raman scattering (SERS) spectra of the polymeric complex [Cu(I)BTA] n. The SERS spectrum obtained from electrodes prepared by the third method is very similar to that of [CU(I)C1BTAH]4. Examination of the electrodes by atomic force microscopy (AFM) showed that a large number of grain boundary sites are formed by the roughening processes. This effect is attributed to the loss of zinc, which occurs during corrosion of the mirror-like, polished brass electrode surface in the sulfuric acid solution.

Influence of Recycled Aggregate Defects on the Durability of Recycled Aggregate Concrete

2014 ◽  
Vol 629-630 ◽  
pp. 173-182 ◽  
Author(s):  
Gai Fei Peng ◽  
Juan Yang ◽  
Jing Yan Wang
Keyword(s):  
Sulfuric Acid ◽  
Acid Solution ◽  
Sulfuric Acid Solution ◽  
Chloride Ion ◽  
Penetration Resistance ◽  
Recycled Aggregate Concrete ◽  
Recycled Aggregate ◽  
Water Penetration ◽  
Aggregate Concrete ◽  
Chloride Ion Penetration

An experimental investigation was conducted on the durability of recycled aggregate concretes with the water to binder ratios of 0.26 and 0.60, including chloride ion penetration resistance test, freezing-thawing resistance test and water penetration resistance. Natural aggregate, recycled aggregate untreated and recycled aggregate treated by sulfuric acid solution, were employed. Results indicated that, 3 mol/L acid concentration and the 7 days soaking duration was the optimum to remove the attached mortars in recycled aggregate, and its removal rate could reach to 90.8%. Water penetration resistance, chloride ion penetration resistance and freezing-thawing resistance of concrete with 0.26 W/B was superior to that of concrete with 0.60 W/B. The more pores in the internal of concrete with 0.60 W/B could be attributed to that. Durability of recycled aggregate concrete, incorporating recycled aggregate treated by sulfuric acid solution, was improved. In particular, the improvement in recycled high strength concrete was significant.

scholarly journals Possibility of High Speed Pickling of Hot Rolled Strip by High Speed Turbulent Flow of Acid Solution

1989 ◽  
Vol 75 (12) ◽  
pp. 2272-2274
Author(s):  
Masahiko ITOH ◽  
Heihachiro MIDORIKAWA ◽  
Tomoaki KIMURA ◽  
Teruo YAMAGUCHI ◽  
Yuji KIKUCHI
Keyword(s):  
Acid Solution ◽  
Turbulent Flow ◽  
High Speed ◽  
Rolled Strip ◽  
Hot Rolled Strip ◽  
Hot Rolled

Spezielle Alkylammoniumhexachlorometallate, II [1] Synthese und Kristallstruktur von Bis(1,2-diammoniopropan)hexachlororhodat(III)-chlorid, [H3N-CH(CH3)-CH2-NH3]2[RhCl6]Cl/ Alkylammonium Hexachlorometallates, II [1] Synthesis, and Crystal Structure of Bis(1,2-diammoniopropane) Hexachlororhodate(III) Chloride, (H3N-CH(CH3)-CH2-NH3]-[RhCl6]Cl

1996 ◽  
Vol 51 (10) ◽  
pp. 1459-1463 ◽  
Author(s):  
Walter Frank ◽  
Guido J. Reiß
Keyword(s):  
Crystal Structure ◽  
Hydrochloric Acid ◽  
Hydrogen Bonds ◽  
Acid Solution ◽  
Crystal Lattice ◽  
Ternary Compound ◽  
Chloride Ion ◽  
Orthorhombic Space Group ◽  
Synthesis And Crystal Structure ◽  
Packing Scheme

Bis(1,2-diammoniopropane) hexachlororhodate(III) chloride, [H3N-CH(CH3)-CH2-NH3]2 [RhCl6]Cl (1) has been obtained by the reaction of rhodium(III) chloride with rac-1,2- diammoniopropane dihydrochloride in hydrochloric acid solution. The quasi-ternary compound, which crystallizes in the orthorhombic space group Pbca (a - 11.0007(13) Å, b = 22.181(2) A, c = 14.638(2) A, V = 3571.7(7) Å3, \ T = -120 °C, Z - 8) contains two crystallographically independent 1,2-diammoniopropane ions beside one hexachlororhodate and one chloride ion. One of the cations shows a R/S-S/R-disorder of enantiomeric pairs in the centrosymmetric crystal lattice. The packing scheme is determined by a complex framework of hydrogen bonds.

KINETICS AND MECHANISM OF COMPLEX FORMATION BETWEEN ETHYLENE AND RUTHENIUM(II) CHLORIDE IN AQUEOUS SOLUTION

1966 ◽  
Vol 44 (4) ◽  
pp. 495-500 ◽  
Author(s):  
Jack Halpern ◽  
Brian R. James
Keyword(s):  
Aqueous Solution ◽  
Hydrochloric Acid ◽  
Complex Formation ◽  
Acid Solution ◽  
Chloride Ion ◽  
Initial Step ◽  
Hydrogen Ion ◽  
Π Complex ◽  
Kinetics Of ◽  
Aqueous Hydrochloric Acid Solution

The formation of a 1:1 π-complex between ethylene and ruthenium(II) in aqueous hydrochloric acid solution is described. The kinetics of the reaction were examined over a range of temperatures and of concentrations of ruthenium(II), ethylene, hydrogen ion, and chloride ion. The results suggest that complex formation proceeds through a stepwise (SN1) mechanism in which the initial step involves the dissociation of a chlororuthenate(II) complex.

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