Performance of sludge-based activated carbon to remove COD from mature landfill leachate: the influence of carburant and activator

2021 ◽  
Vol 237 ◽  
pp. 88-96
Author(s):  
Fan Zeng ◽  
Keqiang Ding ◽  
Jiawei Lu ◽  
Minghan Luo ◽  
Danping Pan ◽  
...  
2013 ◽  
Vol 448-453 ◽  
pp. 1399-1402 ◽  
Author(s):  
Ling Zhao ◽  
Xiao Gu Cheng ◽  
Ping He Yin ◽  
Gang Lu ◽  
Jun Chang Suo

The aim of this study was to check the effectiveness of microelectrolysis for the pretreatment of a municipal landfill leachate with the objective improving its overall biodegradability, evaluated in terms of BOD5/COD ratio, up to a value compatible with biological treatment. The best microelectrolysis operational conditions for achieving the desired COD values were: pH=2.0; granular activated carbon (GAC) =10 g/L; mass ratio of zero iron (Fe0)/GAC=2:1; reaction time=90 min. The BOD5/COD was significantly improved from 0.12 to 0.31, which allowed an almost 85% removal of COD by a sequential activated sludge process. The results show that the microelectrolysis is a promising technology to improve the biodegradability of mature landfill leachate.


RSC Advances ◽  
2016 ◽  
Vol 6 (2) ◽  
pp. 987-994 ◽  
Author(s):  
Zhijun Li ◽  
Qi Yang ◽  
Yu Zhong ◽  
Xiaoming Li ◽  
Li Zhou ◽  
...  

Fe(ii)-loaded granular activated carbon (GAC) was used as a heterogeneous persulfate catalyst for the pretreatment of mature landfill leachate.


Catalysts ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 337
Author(s):  
Sara Mesa Medina ◽  
Ana Rey ◽  
Carlos Durán-Valle ◽  
Ana Bahamonde ◽  
Marisol Faraldos

Two commercial activated carbon were functionalized with nitric acid, sulfuric acid, and ethylenediamine to induce the modification of their surface functional groups and facilitate the stability of corresponding AC-supported iron catalysts (Fe/AC-f). Synthetized Fe/AC-f catalysts were characterized to determine bulk and surface composition (elemental analysis, emission spectroscopy, XPS), textural (N2 isotherms), and structural characteristics (XRD). All the Fe/AC-f catalysts were evaluated in the degradation of phenol in ultrapure water matrix by catalytic wet peroxide oxidation (CWPO). Complete pollutant removal at short reaction times (30–60 min) and high TOC reduction (XTOC = 80 % at ≤ 120 min) were always achieved at the conditions tested (500 mg·L−1 catalyst loading, 100 mg·L−1 phenol concentration, stoichiometric H2O2 dose, pH 3, 50 °C and 200 rpm), improving the results found with bare activated carbon supports. The lability of the interactions of iron with functionalized carbon support jeopardizes the stability of some catalysts. This fact could be associated to modifications of the induced surface chemistry after functionalization as a consequence of the iron immobilization procedure. The reusability was demonstrated by four consecutive CWPO cycles where the activity decreased from 1st to 3rd, to become recovered in the 4th run. Fe/AC-f catalysts were applied to treat two real water matrices: the effluent of a wastewater treatment plant with a membrane biological reactor (WWTP-MBR) and a landfill leachate, opening the opportunity to extend the use of these Fe/AC-f catalysts for complex wastewater matrices remediation. The degradation of phenol spiked WWTP-MBR effluent by CWPO using Fe/AC-f catalysts revealed pH of the reaction medium as a critical parameter to obtain complete elimination of the pollutant, only reached at pH 3. On the contrary, significant TOC removal, naturally found in complex landfill leachate, was obtained at natural pH 9 and half stoichiometric H2O2 dose. This highlights the importance of the water matrix in the optimization of the CWPO operating conditions.


2011 ◽  
Vol 46 (1) ◽  
pp. 148-153 ◽  
Author(s):  
Susana Cortez ◽  
Pilar Teixeira ◽  
Rosário Oliveira ◽  
Manuel Mota

Author(s):  
Rajani Ghaju Shrestha ◽  
Daisuke Inoue ◽  
Michihiko Ike

Abstract A constructed wetland (CW) is a low-cost, eco-friendly, easy-to-maintain, and widely applicable technology for treating various pollutants in the waste landfill leachate. This study determined the effects of the selection and compiling strategy of substrates used in CWs on the treatment performance of a synthetic leachate containing bisphenol A (BPA) as a representative recalcitrant pollutant. We operated five types of lab-scale vertical-flow CWs using only gravel (CW1), a sandwich of gravel with activated carbon (CW2) or brick crumbs (CW3), and two-stage hybrid CWs using gravel in one column and activated carbon (CW4) or brick crumbs (CW5) in another to treat synthetic leachate containing BPA in a 7-d sequential batch mode for 5 weeks. CWs using activated carbon (CW2 and CW4) effectively removed ammonium nitrogen (NH4-N) (99–100%), chemical oxygen demand (COD) (93–100%), and BPA (100%), indicating that the high adsorption capacity of activated carbon was the main mechanism involved in their removal. CW5 also exhibited higher pollutant removal efficiencies (NH4-N: 94–99%, COD: 89–98%, BPA: 89–100%) than single-column CWs (CW1 and CW3) (NH4-N: 76–100%, COD: 84–100%, BPA: 51–100%). This indicates the importance of the compiling strategy along with the selection of an appropriate substrate to improve the pollutant removal capability of CWs.


2018 ◽  
Vol 76 ◽  
pp. 652-662 ◽  
Author(s):  
Agnieszka Montusiewicz ◽  
Marta Bis ◽  
Sylwia Pasieczna-Patkowska ◽  
Dariusz Majerek

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