Ionic liquid modified magnetic nanoparticles-graphene hybrid (Fe3O4@GO-IL) for the removal of ibuprofen and penicillin G from aqueous solutions

2020 ◽  
Vol 208 ◽  
pp. 355-366
Author(s):  
Bahareh Karimi ◽  
Leila Ma’mani ◽  
Abdulfattah Ahmad Amin ◽  
Hazhir Karimi ◽  
Hooshyar Hossini
2014 ◽  
Vol 16 (2) ◽  
pp. 27-30 ◽  
Author(s):  
Katarzyna Wybieralska ◽  
Anna Wajda

Abstract The paper presents the results of studies on the possibility of using magnetic nanoparticles modified with selected hydrophobic surfactants for model post-production water purification. Colloidal solutions of iron hydroxide (III) and iron oxide (II and III) were obtained and their particles were subjected to surface modification using surfactants. Thus obtained magnetic fluids were used as active agents in the process of removing selected organic dyes from their aqueous solutions. The effectiveness of the modified compounds was analysed using spectrophotometric methods. It has been shown that the effectiveness of the process depends on the type of surfactant used to modify selected magnetic nanoparticles.


2021 ◽  
Vol 65 (4) ◽  
Author(s):  
Sara Khodadadi ◽  
Elaheh Konoz ◽  
Ali Ezabadi ◽  
Ali Niazi

Abstract. In the present study, a new, sensitive, and rapid method was developed for extraction and determination of the trace amounts of Pb (II) and Cd (II) ions in milk samples through magnetic solid-phase extraction using DABCO based-ionic liquid-modified magnetic nanoparticles (Fe3O4/[DABCO-PDO]Cl NPs). Herein, Pb (II) and Cd (II) contents were quantified with flame atomic absorption spectroscopy (FAAS). The effect of different empirical parameters (such as sample pH, adsorbent amount, type and amount of the elution, extraction and desorption times, and the ligand concentration) was evaluated and optimized for simultaneous extraction and pre-concentration Pb (II) and Cd (II) ions. The calibration curve was linear under the optimum condition in the concentration range of 0.4-200 µgL-1 for Cd, and 0.5-120 µgL-1 for Pb, respectively. The pre-concentration factor was 67, with the detection limit of 0.09 and 0.07 µgL-1 for Pb and Cd, respectively. The relative standard deviation values (RSD %) of the proposed method were lower than 2.6 %. The developed method was successfully used to determine lead and cadmium content in milk samples. The information obtained from the method validation has been used to estimate the expanded uncertainty for the determination of Pb (II) and Cd (II) at trace levels in commercial milks.   Resumen. En este trabajo, se ha desarrollado un nuevo, sensible y rápido procedimiento para la extracción y determinación de iones Pb(II) y Cd(II) a nivel de trazas en leche, mediante extracción en fase sólida utilizando nanopartículas magnéticas modificadas con líquido iónico basado en DABCO (Fe3O4/[DABCO-PDO]Cl NPs). La determinación de ambos metales se llevó a cabo por espectrometría de absorción atómica con atomización en llama. Se ha evaluado el efecto de diferentes parámetros empíricos (tales como pH, cantidad de adsorbente, tipo y cantidad de solvente de elución, tiempo de extracción y desorción, y concentración del ligando); estos parametros fueron optimizados enfocándose en la extracción y preconcentración simultanea de ambos iones. Empleando las condiciones establecidas, se obtuvo buena linealidad de las curvas de calibración en el intervalo de concentraciones 0.4-200 µgL-1 para Cd, y 0.5-120 µgL-1 para Pb, respectivamente. Se logró el factor de preconcentración 67, con los límites de detección 0.09 y 0.07 µgL-1 para Pb y Cd, respectivamente. Los valores de desviación estandar relativa (RSD %) en el procedimiento propuesto no sobrepasaron 2.6 %. En el análisis de leche, se obtuvieron resultados satisfactorios. Los datos obtenidos en etapa de validación se utilizaron para estimar la incertidumbre expandida en la determinación de Pb y Cd a nivel de trazas en leche.


RSC Advances ◽  
2018 ◽  
Vol 8 (58) ◽  
pp. 33180-33192 ◽  
Author(s):  
Mohamad Shariff Shahriman ◽  
Nur Nadhirah Mohamad Zain ◽  
Sharifah Mohamad ◽  
Ninie Suhana Abdul Manan ◽  
Suhaila Mohd Yaman ◽  
...  

Schematic diagram of the removal procedure of RB on MNP-PANI-DICAT.


2018 ◽  
Vol 38 (s1) ◽  
pp. S205-S213 ◽  
Author(s):  
Reza Shokoohi ◽  
Zahra Torkshavand ◽  
Mohammad Molla Mahmoudi ◽  
Abbas Moradi Behgoo ◽  
Effat Ghaedrahmati ◽  
...  

2016 ◽  
Vol 40 (12) ◽  
pp. 10325-10332 ◽  
Author(s):  
Nasrin Zohreh ◽  
Maryam Tavakolizadeh ◽  
Seyed Hassan Hosseini ◽  
Mahboobeh Jahani ◽  
Ali Pourjavadi ◽  
...  

A novel magnetically recoverable catalyst was prepared in which magnetic nanoparticles were functionalized by bis-imidazolium tungstate ionic liquid molecules.


2014 ◽  
Vol 6 (20) ◽  
pp. 8358-8367 ◽  
Author(s):  
Jing Chen ◽  
Yuzhi Wang ◽  
Xueqin Ding ◽  
Yanhua Huang ◽  
Kaijia Xu

Hydroxy functional ionic liquids have been first designed and modified on the surface of silica-coated magnetic Fe3O4 nanoparticles (MNPs) for the investigation of the extraction performance of proteins.


2015 ◽  
Vol 39 (6) ◽  
pp. 4591-4600 ◽  
Author(s):  
Ali Pourjavadi ◽  
Mahmood Tajbakhsh ◽  
Maryam Farhang ◽  
Seyed Hassan Hosseini

A novel heterogeneous copper catalyst based on poly(ionic liquid)-coated magnetic nanoparticles was prepared by the polymerization of 3-carboxymethyl-1-vinylimidazolium in the presence of surface-modified magnetic nanoparticles, followed by the coordination of the carboxylate units in the polymer chains with copper sulfate.


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