Adsorption of anionic dyes from aqueous solution using polyelectrolyte PDADMAC-modified-montmorillonite clay

2020 ◽  
Vol 208 ◽  
pp. 407-422
Author(s):  
Rachid Ait Akbour ◽  
Jamila El Gaayda ◽  
Fatima Ezzahra Titchou ◽  
Aïcha Khenifi ◽  
Hanane Afanga ◽  
...  
BioResources ◽  
2021 ◽  
Vol 16 (2) ◽  
pp. 2644-2654
Author(s):  
Zicheng Chen ◽  
Huiwen Zhang ◽  
Xiangyang He ◽  
Guangyuan Fan ◽  
Xiaosong Li ◽  
...  

The combination of metal organic frameworks (MOFs) with other functional materials is a potential strategy for the preparation of advanced MOF-based materials. In this study, a simple approach is reported for the fabrication of cellulosic paper containing zeolitic imidazolate framework (ZIF-8) through in-situ loading in the papermaking process. The results showed that the ZIF-8 was evenly distributed in the paper substrate owing to the multi-layers structure of the cellulosic fibers, although the loading of the ZIF-8 particles on the single cellulosic fiber was nonuniform. The as-prepared ZIF-8 composites can be used as a highly efficient adsorbent material for anionic dyes in aqueous solution thanks to the positive charge on the surface of the ZIF-8 particles. More than 92% of the methyl orange (MO-) dye in the aqueous solution was rapidly removed through a simple filtration process using the ZIF-8 composite cellulosic paper (hand-sheets made in lab) when the content of ZIF-8 in cellulosic paper was high as 25.1%. In addition, the ZIF-8 composite paper had acceptable flexibility and could be reused at least 4 cycles by washing out the adsorbed dye.


e-Polymers ◽  
2011 ◽  
Vol 11 (1) ◽  
Author(s):  
Sugata Chakraborty ◽  
Saptrashi Kar ◽  
Saikat Dasgupta ◽  
Rabindra Mukhopadhyay ◽  
Samar Bandyopadhyay

AbstractPresent study describes the preparation and characterization of crystal violet modified-montmorillonite clay nanocomposites by latex blending technique. Coagulation of the latex-clay slurry produced nanocomposites master batch. The master batch was compounded with Styrene Butadiene rubber (SBR). WAXD and TEM provided the evidences of formation of nanocomposite. Remarkable improvements in the mechanical properties were found by addition of small amount of modified clay.


2020 ◽  
Vol 82 (10) ◽  
pp. 2159-2167
Author(s):  
Ru-yi Zhou ◽  
Jun-xia Yu ◽  
Ru-an Chi

Abstract Double functional groups modified bagasse (DFMBs), a series of new zwitterionic groups of carboxyl and amine modified adsorbents, were prepared through grafting tetraethylenepentamine (TEPA) onto the pyromellitic dianhydride (PMDA) modified bagasse using the DCC/DMAP method. DFMBs' ability to simultaneously remove basic magenta (BM, cationic dye) and Congo red (CR, anionic dye) from aqueous solution in single and binary dye systems was investigated. FTIR spectra and Zeta potential analysis results showed that PMDA and TEPA were successfully grafted onto the surface of bagasse, and the ratio of the amount of carboxyl groups and amine groups was controlled by the addition of a dosage of TEPA. Adsorption results showed that adsorption capacities of DFMBs for BM decreased while that for CR increased with the increase of the amount of TEPA in both single and binary dye systems, and BM or CR was absorbed on the modified biosorbents was mainly through electrostatic attraction and hydrogen bond. The adsorption for BM and CR could reach equilibrium within 300 min, both processes were fitted well by the pseudo-second-order kinetic model. The cationic and anionic dyes removal experiment in the binary system showed that DMFBs could be chosen as adsorbents to treat wastewater containing different ratios of cationic and anionic dyes.


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