Effect of nitrogen loading on the nitrogen removal performance in membrane bioreactor coupled with elemental sulfur-based carriers

2020 ◽  
Vol 205 ◽  
pp. 124-130
Author(s):  
Thi-Kim-Quyen Vo ◽  
Soyeon Kang ◽  
Jeong-Eun Lee ◽  
Sun-A An ◽  
Ahyoung Jeong ◽  
...  
2010 ◽  
Vol 61 (3) ◽  
pp. 671-676 ◽  
Author(s):  
W. Chen ◽  
F. Y. Sun ◽  
X. M. Wang ◽  
X. Y. Li

A hybrid system has been developed for biological nitrogen removal through nitrification-denitrification. The system includes an aerobic tank and an anoxic tank with an intermediate sludge settler connected to a membrane bioreactor (MBR) with a submerged 0.4 μm hollow-fiber membrane module. The laboratory system has a total working volume of 6.5 L treating a glucose-based synthetic wastewater. The experimental results demonstrate that the new process is highly effective for simultaneous organic and nitrogen removal. During the stationary operation, a sludge SS (suspended solids) concentration of 6 g/L or higher can be maintained in the reactors. The system has a COD (chemical oxygen demand) loading rate of up to 2,100 mg/L-d and a total nitrogen loading rate of up to 170 mg N/L-d. More than 95% COD can be degraded, and the total nitrogen removal efficiency can be 90% or higher as the nitrogen is reduced from 100 to around 7.5 mg/L. A high quality effluent is produced with a SS of less than 1 mg/L. With the MBR, organic degradation, nitrogen removal and sludge-liquid separation can be well achieved within a short HRT of about 10 hr.


2017 ◽  
Author(s):  
S. Suneethi ◽  
Kurian Joseph

Anaerobic Membrane Bioreactor (AnMBR) is an innovative high cell density system having complete biomass retention, high reactor loading and low sludge production and suitable for developing slow growing autotrophic bacterial cultures such as ANAMMOX. The Anaerobic Ammonium Oxidation (ANAMMOX) process is an advanced biological nitrogen removal removes ammonia using nitrite as the electron acceptor without oxygen. The NH4+-N in the landfill leachate that is formed due to the release of nitrogen from municipal solid waste (MSW), when discharged untreated, into the surface water can result in eutrophication, aquatic toxicity and emissions of nitrous oxide (N2O) to atmosphere. Besides, NH4+-N accumulation in landfills poses long term pollution issue with significant interference during post closure thereby requiring its removal prior to ultimate disposal into inland surface waters. The main objective of this study was to investigate the feasibility and treatment efficiency of treating landfill leachate (to check) for removing NH4+-N by adopting ANAMMOX process in AnMBR. The AnMBR was optimized for Nitrogen Loading Rate (NLR) varying from 0.025 to 5 kg NH4+-N/ m3/ d with hydraulic retention time (HRT) ranging from 1 to 3 d. NH4+-N removal efficacy of 85.13 ± 9.67% with the mean nitrogen removal rate (NRR) of 5.54 ± 0.63 kg NH4+-N/ m3/ d was achieved with nitrogen loading rate (NLR) of 6.51 ± 0.20 kg NH4+- N/ m3/ d at 1.5 d HRT. The nitrogen transformation intermediates in the form of hydrazine (N2H4) and hydroxylamine (NH2OH) were 0.008 ± 0.005 mg/L and 0.006 ± 0.001 mg/L, respectively, indicating co-existence of aerobic ammonia oxidizers (AOB) and ANAMMOX. The free ammonia (NH3) and free nitrous acid (HNO2) concentrations were 26.61 ± 16.54 mg/L and (1.66 ± 0.95) x 10-5 mg/L, preventing NO2--N oxidation to NO3--N enabling sustained NH4+- N removal.


2016 ◽  
Vol 74 (4) ◽  
pp. 805-815 ◽  
Author(s):  
Jinyoung Moon ◽  
Yongwoo Hwang ◽  
Junbeum Kim ◽  
Inho Kwak

Recent toughened water quality standards have necessitated improvements for existing sewer treatment facilities through advanced treatment processes. Therefore, an advanced treatment process that can be installed through simple modification of existing sewer treatment facilities needs to be developed. In this study, a new submerged membrane bioreactor process packed with granular sulfur (MBR-GS) was developed and operated to determine the biological nitrogen removal behaviors of plating wastewater containing a high concentration of NO3−. Continuous denitrification was carried out at various nitrogen loading rates at 20 °C using synthetic wastewater, which was comprised of NO3− and HCO3−, and actual plating wastewater, which was collected from the effluent water of a plating company called ‘H Metals’. High-rate denitrification in synthetic plating wastewater was accomplished at 0.8 kg NO3−-N/m3·day at a nitrogen loading rate of 0.9 kg NO3−-N/m3·day. The denitrification rate further increased in actual plating wastewater to 0.91 kg NO3−-N/m3·day at a nitrogen loading rate of 1.11 kg NO3−-N/m3·day. Continuous filtration was maintained for up to 30 days without chemical cleaning with a transmembrane pressure in the range of 20 cmHg. Based on stoichiometry, SO42− production and alkalinity consumption could be calculated theoretically. Experimental alkalinity consumption was lower than the theoretical value. This newly proposed MBR-GS process, capable of high-rate nitrogen removal by compulsive flux, is expected to be applicable as an alternative renovation technique for nitrogen treatment of plating wastewater as well as municipal wastewater with a low C/N ratio.


2014 ◽  
Vol 17 (2) ◽  
pp. 69-79
Author(s):  
Linh Van Tran ◽  
Phuoc Van Nguyen ◽  
Phuong Thi Thanh Nguyen

The SBMBMBR technology (sequencing batch moving bed membrane bioreactor), a combiantion of membrane filtration MF process in activated sludge with sequencing batch (SBR) moving bed using Anox Kaldnes K2 (MBBR), has been studied for the removal of organic and total nitrogen in tannery wastewater. After 170 days, reasearch results showed that the COD removal efficiency was ranged from 89,2±0,6 to 95,9±0,3% when the organic loading rate changed from 0,564±0,019 to 1.207±99 kgCOD/m3/day. The total nitrogen removal efficiency reached 30,0±4,9 to 65,9±13,3. The highest COD removal efficiency was 0,72±0,02 kgCOD/m3/day. The lowest nitrogen removal efficiency was 10,8±5,4% at 0,327±0,020 kgTN/m3/day of nitrogen loading rate. During the research, the adhensional tension of microorganism was insignificant. The biomass remained unchanged with 6.808±226 mg/L of Mixed liquor suspended solids (MLSS). When the salinity went up from 3.500 to 8.000 mgCl/l, the COD and nitrogen removal efficiency decreased. However, the conversion of nitrogen was improved and the recovery of biomass following the changed loading rate was quite fast.


2010 ◽  
Vol 5 (3) ◽  
Author(s):  
Cheng-Nan Chang ◽  
Li-Ling Lee ◽  
Han-Hsien Huang ◽  
Ying-Chih Chiu

The performance of a real-time controlled Sequencing Batch Membrane Bioreactor (SBMBR) for removing organic matter and nitrogen from synthetic wastewater has been investigated in this study under two specific ammonia loadings of 0.0086 and 0.0045g NH4+-N gVSS−1 day−1. Laboratory results indicate that both COD and DOC removal are greater than 97.5% (w/w) but the major benefit of using membrane for solid-liquid separation is that the effluent can be decanted through the membrane while aeration is continued during the draw stage. With a continued aeration, the sludge cake layer is prevented from forming thus alleviating the membrane clogging problem in addition to significant nitrification activities observed in the draw stage. With adequate aeration in the oxic stage, the nitrogen removal efficiency exceeding 99% can be achieved with the SBMBR system. Furthermore, the SBMBR system has also been used to study the occurrence of ammonia valley and nitrate knee that can be used for real-time control of the biological process. Under appropriate ammonia loading rates, applicable ammonia valley and nitrate knee are detected. The real-time control of the SBMBR can be performed based on on-line ORP and pH measurements.


2015 ◽  
Vol 277 ◽  
pp. 209-218 ◽  
Author(s):  
P. Reboleiro-Rivas ◽  
J. Martín-Pascual ◽  
B. Juárez-Jiménez ◽  
J.M. Poyatos ◽  
R. Vílchez-Vargas ◽  
...  

2021 ◽  
Vol 26 (1) ◽  
pp. 25
Author(s):  
Zulkarnaini Zulkarnaini ◽  
Puti Sri Komala ◽  
Arief Almi

The anaerobic ammonium oxidation (anammox) biofilm process commonly uses various inorganic carriers to enhance nitrogen removal under anaerobic conditions. This study aims to analyze the performance of nitrogen removal in anammox process using sugarcane bagasse as an organic carrier. The experiment was carried out by using an up‐flow anaerobic sludge blanket (UASB) reactor for treating artificial wastewater at room temperature. The reactor was fed with ammonium and nitrite with the concentrations of 70‐150 mg–N/L and variations in the hydraulic retention time of 24 and 12 h. The granular anammox belongs to the genus Candidatus Brocadia sinica that was added as an inoculum of the reactor operation. The experimental stoichiometric of anammox for ΔNO2‐–N: ΔNH4+–N and ΔNO3‐: ΔNH4+ were 1.24 and 0.18, respectively, which is similar to anammox stoichiometry. The maximum Nitrogen Removal Rate (NRR) has achieved 0.29 kg–N/m3.d at Nitrogen Loading Rate (NLR) 0.6 kg–N/m3.d. The highest ammonium conversion efficiency (ACE) and nitrogen removal efficiency (NRE) were 88% and 85%, respectively. Based on this results, it indicated that sugarcane bagasse as organic carriers could increase the amount of total nitrogen removal by provided of denitrification process but inhibited the anammox process at a certain COD concentration.


2011 ◽  
Vol 63 (4) ◽  
pp. 710-718 ◽  
Author(s):  
S. Q. Ni ◽  
J. Meng

In order to study the performance, inhibition and recovery processes of different types of anammox sludge, three up-flow anaerobic sludge blanket reactors were inoculated with flocculent sludge, granular sludge, and cultured inactive methanogenic granules. During stable period, with nitrogen loading rates of 0.9–1.1 kg/m3/d, the total nitrogen removal efficiencies of these reactors averaged at 86.5%, 90.8% and 93.5%, respectively. The kinetics study indicated that the reactor seeded with cultured inactive methanogenic granules possessed the highest nitrogen removal potential, followed by the granular anammox reactor and the flocculent anammox reactor. The study suggested that a concentration as high as 988.3 mg NH4+-N/L and 484.4 mg NO2−-N/L could totally inhibit granular anammox bacteria and result in a inhibition of 50% flocculent anammox activity. In addition, reactors seeded with flocculent sludge and anammox granules could be fully recovered by decreasing their influent substrate concentrations. However, the decrease of influent substrate concentration for the reactor with cultured inactive methanogenic granules could only restore about 75% of its bacterial activity. In this study, anammox bacteria purity was the major factor to evaluate the recovery ability in comparison with sludge type. Free ammonia was a more appropriate indicator for the anammox recovery process compared to free nitric acid.


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