Poly(acrylic acid)/SiO2 composite nanofiber membranes functionalized with mercapto groups for removal of humic acid from aqueous solution

2019 ◽  
Vol 141 ◽  
pp. 115-123
Author(s):  
M.A. Zulfikar ◽  
D. Maulina ◽  
M. Nasir ◽  
A. Alni ◽  
M. Zunita ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Humic Acid ◽  
Acrylic Acid ◽  
Composite Nanofiber ◽  
Nanofiber Membranes ◽  
Mercapto Groups ◽  
Poly Acrylic Acid

Sorption of Ag+, Cu2+ on Thiol-Functionalized Poly (Acrylic Acid)/SiO2 Composite Nanofiber Membranes

2011 ◽  
Vol 356-360 ◽  
pp. 488-492
Author(s):  
Ran Xu ◽  
Min Jia ◽  
Feng Ting Li
Keyword(s):  
Acrylic Acid ◽  
Adsorption Capacity ◽  
Removal Rate ◽  
Sol Gel ◽  
Electrospinning Method ◽  
Composite Nanofiber ◽  
Pseudo Second Order ◽  
Nanofiber Membranes ◽  
Kinetics Of ◽  
Poly Acrylic Acid

Thiol-functionalized poly (acrylic acid)/SiO2 (PAA/SiO2) composite nanofiber membranes have been fabricated by a sol-gel electrospinning method and their adsorption capacity for Ag+, Cu2+ was investigated. Results showed the PAA/SiO2 fibers had a diameter between 300 nm-700 nm. FTIR results demonstrated that the mercapto groups have been introduced into the silica skeleton. The adsorption of Ag+, Cu2+ on the membranes fit the Redlich-Peterson isotherm model best. The equilibrium adsorption capacity of Ag+ (575.64 mg/g) on PAA/SiO2 nanofiber membranes is higher than Cu2+ (331.52 mg/g). The desorption rate reached 98% in 30 min. The removal rate of Ag+, Cu2+ still maintained above 75% after six regeneration cycles. Adsorption kinetics of Ag+, Cu2+ followed a pseudo-second-order model.

scholarly journals Thermo-Responsive Behavior of Mixed Aqueous Solution of Hydrophilic Polymer with Pendant Phosphorylcholine Group and Poly(Acrylic Acid)

Polymers ◽  
2021 ◽  
Vol 13 (1) ◽  
pp. 148
Author(s):  
Hirokazu Fukumoto ◽  
Kazuhiko Ishihara ◽  
Shin-Ichi Yusa
Keyword(s):  
Aqueous Solution ◽  
Acrylic Acid ◽  
Solution Temperature ◽  
Interpolymer Complex ◽  
Mixed Aqueous Solution ◽  
Upper Critical Solution Temperature ◽  
Acidic Conditions ◽  
Decreasing Ph ◽  
Increasing Temperature ◽  
Poly Acrylic Acid

A mixed aqueous solution of hydrophilic poly(2-methacryloyloxyethyl phosphorylcholine) (PMPC) and poly(acrylic acid) (PAAc) becomes cloudy under acidic conditions at room temperature. The pendant carboxylic acid groups in PAAc form hydrogen bonds with the ester and phosphate groups in PMPC. While the polymers aggregate under acidic conditions, neither one associate under basic conditions because of the deprotonation of the pendant carboxy groups in PAAc. We observed that the interpolymer complex formed from PMPC, and PAAc was dissociated in aqueous solutions with increasing temperature, which is an upper critical solution temperature behavior. With increasing temperature, the molecular motion increased to dissociate the interpolymer complex. The phase transition temperature increased with increasing polymer and salt concentrations, and with decreasing pH.

Determination of the complexation properties of a crosslinked poly(acrylic acid) gel with copper(II), nickel(II), and lead(II) in dilute aqueous solution

2001 ◽  
Vol 79 (4) ◽  
pp. 370-376 ◽  
Author(s):  
Catherine Morlay ◽  
Yolande Mouginot ◽  
Monique Cromer ◽  
Olivier Vittori
Keyword(s):  
Aqueous Solution ◽  
Ionic Strength ◽  
Acrylic Acid ◽  
Metal Ion ◽  
Conditional Stability ◽  
Binding Properties ◽  
Complex Species ◽  
Complexing Capacity ◽  
Dilute Aqueous Solution ◽  
Poly Acrylic Acid

The possible removal of copper(II), nickel(II), or lead(II) by an insoluble crosslinked poly(acrylic acid) was investigated in dilute aqueous solution. The binding properties of the polymer were examined at pH = 6.0 or 4.0 with an ionic strength of the medium µ = 0.1 or 1.0 M (NaNO3) using differential pulse polarography as an investigation means. The highest complexing capacity of the polyacid was obtained with lead(II) at pH = 6.0 with µ = 0.1 M, 4.8 mmol Pb(II)/g polymer. The conditional stability constants of the complex species formed were determined using the method proposed by Ruzic assuming that only the 1:1 complex species was formed; for lead(II) at pH = 6.0 and µ = 0.1 M, log K' = 5.3 ± 0.2. It appeared that the binding properties of the polymer increased, depending on the metal ion, in the following order: Ni(II) < Cu(II) < Pb(II). The complexing capacity and log K' values decreased with the pH or with an increase of the ionic strength. These results were in agreement with the conclusions of our previous studies of the hydrosoluble linear analogues. Finally, with the insoluble polymer, the log K' values were comparable to those previously obtained with the linear analogue whereas the complexing capacity values expressed in mmol g-1 were slightly lower.Key words: insoluble crosslinked poly(acrylic acid), copper(II), nickel(II), and lead(II) complexation.

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