Optimization of Fe2+ catalyzed hydrogen peroxide/persulfate and its application in activated carbon regeneration

2019 ◽  
Vol 142 ◽  
pp. 167-178
Author(s):  
Shengpin Li ◽  
Wenpeng Li ◽  
Boyang Liu ◽  
Fei Liu ◽  
Honghan Chen ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Activated Carbon ◽  
Carbon Regeneration

Supercritical CO2 regeneration of activated carbon loaded with organic adsorbates

1997 ◽  
Vol 35 (7) ◽  
pp. 261-268 ◽  
Author(s):  
Kazuyuki Chihara ◽  
Kanji Oomori ◽  
Takao Oono ◽  
Yosuke Mochizuki
Keyword(s):  
Activated Carbon ◽  
Cost Estimation ◽  
Supercritical Co2 ◽  
Adsorption Equilibrium ◽  
Equilibrium Constants ◽  
Adsorption Dynamics ◽  
Boiling Points ◽  
Organic Adsorbates ◽  
Carbon Regeneration ◽  
Co2 Density

Supercritical CO2 regeneration is one of the possibilities for spent carbon regeneration loaded with some organics. Here, adsorption equilibrium and adsorption dynamics were evaluated for some typical organic pollutants under some supercritical CO2 conditions. A supercritical CO2 chromatograph packed with activated carbon (F-400, CAL) was used to detect the pulse responses of organics, which were analyzed by moment analysis. Adsorption equilibrium constants of some organics varied with CO2 density and their boiling points. Possibility of regeneration of each substance was discussed. Cost estimation was necessary and was the key point of this technique.

Kinetics of spent activated carbon regeneration

AIChE Journal ◽  
1988 ◽  
Vol 34 (10) ◽  
pp. 1656-1662 ◽  
Author(s):  
Peter Harriott ◽  
Alan Tat-Yan Cheng
Keyword(s):  
Activated Carbon ◽  
Carbon Regeneration ◽  
Kinetics Of

Study on Thermal Regeneration for Caffeine-Saturated Activated Carbon

2013 ◽  
Vol 781-784 ◽  
pp. 1941-1944 ◽  
Author(s):  
Zhao You Zhu ◽  
Li Li Wang ◽  
Wan Ling Wang ◽  
Ying Long Wang
Keyword(s):  
Activated Carbon ◽  
Carbon Layer ◽  
Carbon Surface ◽  
Optimum Conditions ◽  
Gas Velocity ◽  
Thermal Regeneration ◽  
Regeneration Time ◽  
Before And After ◽  
Carbon Regeneration ◽  
Carrier Gas Velocity

Waste activated carbon (AC) containing caffeine was produced during the process of the production for caffeine. The process of treatment caffeine-saturated AC using thermal regeneration was explored and factors on the regeneration of activated carbon were investigated. The optimum conditions obtained were: temperature is 650 °C, the regeneration time is 180 min, the carrier gas velocity is 0.002 m/s, carbon layer thickness is 0.1 m. Under these conditions, activated carbon regeneration efficiency reached 90.3%. In addition, the pore structure of activated carbon before and after regeneration was characterized and the activated carbon surface area and pore size distribution under optimum conditions were determined by the adsorption isotherms.

Effect of Modification with Nitric Acid and Hydrogen Peroxide on Chromium (VI) Adsorption by Activated Carbon Fiber

2012 ◽  
Vol 518-523 ◽  
pp. 2099-2103
Author(s):  
Guang Zhou Qu ◽  
Hai Bing Ji ◽  
Ran Xiao ◽  
Dong Li Liang
Keyword(s):  
Hydrogen Peroxide ◽  
Activated Carbon ◽  
Nitric Acid ◽  
Carbon Fiber ◽  
Adsorption Capacity ◽  
Adsorption Kinetics ◽  
Ph Value ◽  
Activated Carbon Fiber ◽  
Order Kinetic ◽  
Adsorption Amount

The activated carbon fiber (ACF) was treated by different concentration nitric acid (HNO3) and hydrogen peroxide (H2O2) oxidization to enhance its adsorption capacity to hexavalent chromium (Cr6+) ion. The adsorption amount and adsorption kinetics of Cr6+ion on ACFs, and the surface chemical groups were investigated. The results showed that the modified ACFs with 1% HNO3and 10% H2O2had a better adsorption capacity, respectively. The adsorption amount of ACFs was affected strongly solution pH value, and decreased significantly with increasing of the pH value. The adsorption kinetics indicated that the adsorption rates of Cr6+ ion on different modified ACFs were well fitted with the pseudo-second-order kinetic model. After 1% HNO3and 10% H2O2modification, respectively, the total acidic oxygen-containing groups on ACFs surface had an increase obviously, which might be enhance the adsorption amount of Cr6+ion on ACFs.

Removal of Tributyltin in Shipyard Waters: Characterization and Treatment to Meet Low Parts per Trillion Levels

2003 ◽  
Vol 19 (03) ◽  
pp. 179-186
Author(s):  
Gary C. Schafran ◽  
R. Prasad ◽  
F. H. Thorn ◽  
R. Michael Ewing ◽  
J. Soles
Keyword(s):  
Hydrogen Peroxide ◽  
Activated Carbon ◽  
Hydroxyl Radical ◽  
Ultraviolet Irradiation ◽  
Treatment Plant ◽  
Full Scale ◽  
Radical Formation ◽  
Estuarine Waters ◽  
Treatment Conditions ◽  
Made In

Removal of tributyltin (TBT) from shipyard waters has been conducted in Virginia shipyards for over 2.5 years and has resulted in a 99% reduction of TBT discharged to coastal-estuarine waters. This has been achieved by conventional coagulation clarification for particulate TBT removal and removal of dissolved TBT using activated carbon. Although advances have been made in the understanding of TBT removal under various treatment conditions, TBT removal with the existing full-scale treatment plant to levels that would comply with a 50 parts per trillion (pptr) discharge limit are not possible. Results from study efforts that are currently ongoing suggest that the 50 pptr limit might be reached using ultraviolet irradiation or ozonation and that both processes would be substantially improved with the addition of hydrogen peroxide to promote hydroxyl radical formation.

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