Sorption of heavy metal ions onto e-waste-derived ion-exchange material – selecting the optimum isotherm

2018 ◽  
Vol 126 ◽  
pp. 196-207 ◽  
Author(s):  
Akanksha Kalra ◽  
Pejman Hadi ◽  
Hamish R. Mackey ◽  
Tareq Al Ansari ◽  
Gordon McKay
Keyword(s):  
Heavy Metal ◽  
Ion Exchange ◽  
Metal Ions ◽  
Heavy Metal Ions ◽  
Exchange Material

scholarly journals Modified ion exchange jackfruit seeds resin for removal of selected trace heavy metal ions from aqueous solution

2021 ◽  
Vol 2 (2) ◽  
pp. 84-92
Author(s):  
S N Ndung’u ◽  
E W Nthiga ◽  
R N Wanjau
Keyword(s):  
Heavy Metal ◽  
Ion Exchange ◽  
Metal Ions ◽  
Heavy Metal Ions ◽  
Active Sites ◽  
Ion Exchange Resin ◽  
Standard Entropy ◽  
Environmentally Sustainable ◽  
Heavy Metal Ions Removal ◽  
Metal Ions Removal

Water is essential for every life processes. However, its quality is deteriorating every day due to the recent industrial advancements. Anthropogenic processes such as industrialization, mining and agricultural activities have led to alarming discharge of heavy metal ions to the aquatic bodies. This possess a greater threat to human, animal and the entire ecosystem wellbeing. Accumulation of heavy metal ions in drinking water beyond permissible limits is detrimental to human health. Therefore, their removal is paramount. Conventional remediation techniques have been employed but have remained expensive and not universally appropriate. This has therefore spurred research interests in the use of adsorption techniques from locally available materials as an environmentally sustainable alternative. Jackfruit seeds are discarded as wastes of a Jackfruit and can be utilized as an ion exchange resin in heavy metal ions removal from wastewater. The present study involved application of previously prepared raw and modified Jackfruit seed resins to study thermodynamics of copper (II), lead (II) and cadmium (II) ions adsorption from synthetic water. FTIR results showed presence of functional groups in raw and modified resins as important sites for studying thermodynamics of adsorption of copper (II), lead (II) and cadmium (II) ions. Thermodynamic data showed that standard Gibb’s free energy () values for all metals were negative indicating that adsorption process was feasible and favourable. Standard enthalpy change (), standard entropy () and activation energy () were positive (> 40 kJ mol-1) and in the order lead (II) > copper (II) > cadmium (II). This confirmed adsorption of copper (II), lead (II) and cadmium (II) ions onto both raw and modified resins was predominated by chemical interactions between the metal ions and the resin active sites. This was confirmed by very low values of sticking probability (S*). The findings indicated that ion exchange Jackfruit seeds resin is promising for heavy metal ions removal from wastewater in an optimized temperature controlled system.

Recent Advances in Water Treatment Using Graphene-based Materials

2020 ◽  
Vol 17 (1) ◽  
pp. 74-90 ◽  
Author(s):  
Nader Ghaffari Khaligh ◽  
Mohd Rafie Johan
Keyword(s):  
Heavy Metal ◽  
Water Treatment ◽  
Ion Exchange ◽  
Metal Ions ◽  
Metal Ion ◽  
Heavy Metal Ions ◽  
Membrane Filtration ◽  
Chemical Precipitation ◽  
High Specific Surface Area ◽  
Adsorption Parameters

: A variety of processes were reported for efficient removing of heavy metal from wastewater, including but not limited to ion exchange, reverse osmosis, membrane filtration, flotation, coagulation, chemical precipitation, solvent extraction, electrochemical treatments, evaporation, oxidation, adsorption, and biosorption. Among the aforementioned techniques, adsorption/ion exchange has been known as a most important method for removing heavy metal ions and organic pollutants due to great removal performance, simple and easy process, cost-effectiveness and the considerable choice of adsorbent materials. : Nanotechnology and its applications have been developed in most branches of science and technology. Extensive studies have been conducted to remove heavy metal ions from wastewater by preparation and applications of various nanomaterials. Nanomaterials offer advantages in comparison to other materials including an extremely high specific surface area, low-temperature modification, short intraparticle diffusion distance, numerous associated sorption sites, tunable surface chemistry, and pore size. In order to evaluate an adsorbent, two key parameters are: the adsorption capacity and the desorption property. The adsorption parameters including the absorbent loading, pH and temperature, concentration of heavy metal ion, ionic strength, and competition among metal ions are often studied and optimized. : Several reviews have been published on the application of Graphene (G), Graphene Oxide (GO) in water treatment. In this minireview, we attempted to summarize the recent research advances in water treatment and remediation process by graphene-based materials and provide intensive knowledge of the removal of pollutants in batch and flow systems. Finally, future applicability perspectives are offered to encourage more interesting developments in this promising field. This minireview does not include patent literature.

Layered silicate RUB-15 for efficient removal of UO22+ and heavy metal ions by ion-exchange

2017 ◽  
Vol 4 (9) ◽  
pp. 1851-1858 ◽  
Author(s):  
Zhe Chen ◽  
Yu Liang ◽  
Dashuang Jia ◽  
Wanying Chen ◽  
Zhimin Cui ◽  
...  
Keyword(s):  
Heavy Metal ◽  
Ion Exchange ◽  
Metal Ions ◽  
Heavy Metal Ions ◽  
Layered Silicate ◽  
High Adsorption ◽  
Efficient Removal

Layered silicate RUB-15 exhibited high adsorption abilities for not only UO22+ but also heavy metal ions through ion-exchange.

EFFICIENCY OF EXTRACTION HEAVY METAL IONS FROM DILUTED SOLUTIONS BY ION-EXCHANGE METHODS

2017 ◽  
pp. 154-162 ◽  
Author(s):  
Nikolai Gomelya ◽  
◽  
Veronika Ivanova ◽  
Inna Trus ◽  
◽  
...  
Keyword(s):  
Heavy Metal ◽  
Ion Exchange ◽  
Metal Ions ◽  
Heavy Metal Ions

Ion Exchange Extraction of Heavy Metal Ions from Wastewater

2005 ◽  
Vol 39 (9) ◽  
pp. 2031-2040 ◽  
Author(s):  
Svetlana Verbych ◽  
Nidal Hilal ◽  
Genady Sorokin ◽  
Mark Leaper
Keyword(s):  
Heavy Metal ◽  
Ion Exchange ◽  
Metal Ions ◽  
Heavy Metal Ions ◽  
Exchange Extraction

scholarly journals LEANING THE GALVANIC WASTE WATER OF THE COMPANY «THIEN MY» (VIETNAM) USING SAWDUST AND ION EXCHANGE

2020 ◽  
pp. 36-41
Author(s):  
I.G. Shaikhiev ◽  
T.K.T. Nguyen ◽  
R.Z. Galimova ◽  
V.O. Dryakhlov
Keyword(s):  
Heavy Metal ◽  
Ion Exchange ◽  
Metal Ions ◽  
Heavy Metal Ions ◽  
Ion Exchange Resin ◽  
Standard Test ◽  
Acacia Auriculiformis ◽  
Socialist Republic ◽  
Sorption Material ◽  
Galvanic Production

The technology for wastewater treatment of galvanic production was developed for «Thien Mi» LLC, Vinh Fuk, Socialist Republic of Vietnam. Initially, a characteristic of the existing method for the extraction of heavy metal ions from electroplating is given. It was revealed that the treatment of wastewater from galvanic plants with a suspension of calcium hydroxide leads to the formation of a large volume of galvanic sludge and an insufficient degree of purification from heavy metal ions. The possibility of sorption purification of the galvanic drains of the named enterprise using the sawdust of acacia (Acacia auriculiformis) as a sorption material was investigated. The adsorption isotherms of Cu2+, Ni2+, and Zn2+ ions with native sawdust of acacia were constructed. Sorption material was processed with weakly concentrated solutions of sulfuric acid, which leads to an increase of more than 4 times in the sorption capacity of the mentioned ITMs. The post-treatment of galvanic solutions from heavy metal ions was carried out using the Lewatit Monoplus TP 207 ion-exchange resin. The toxicity of the initial galvanic drains was investigated after each cleaning step using standard test objects Paramecium caudatum and Daphia magna. As a result of the studies, sorption and ion-exchange methods are recommended for the treatment of wastewater of galvanic production of small volumes, which can significantly reduce the concentration of heavy metal ions in purified solutions.

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