Degradation of isopropyl ethylthionocarbamate from aqueous solution by Fenton oxidation: RSM optimization, mechanisms, and kinetic analysis

2018 ◽  
Vol 130 ◽  
pp. 87-97 ◽  
Author(s):  
Donghui Liu ◽  
Guohua Gu ◽  
Bichao Wu ◽  
Chongqing Wang ◽  
Xiong Chen
2010 ◽  
Vol 5 (12) ◽  
pp. 1934578X1000501 ◽  
Author(s):  
Paul Slusarewicz ◽  
Keng Zhu ◽  
Tom Hedman

Degradation of genipin (GP), a low toxicity natural protein crosslinking agent, in aqueous solution was monitored by HPLC at various pH levels. Degradation of GP was consistent with a mechanism consisting of a first order reaction with a reversible first step. Formation of the intermediate was slowest at more neutral pHs while formation of the irreversible product was correlated to increasing alkalinity. Degradation at all pHs was enhanced by the presence of phosphate ions. Degradation of GP most likely proceeds via the reversible opening of the dihydropyran ring by water followed by irreversible polymerization of the intermediate. Degraded solutions containing no detectable GP or intermediate, however, are still capable of crosslinking proteins.


2016 ◽  
Vol 8 ◽  
pp. 670-672 ◽  
Author(s):  
Roli Saini ◽  
Chelluboyana Vaishnava Raghunath ◽  
Poornima Pandey ◽  
Pradeep Kumar

2003 ◽  
Vol 37 (12) ◽  
pp. 3023-3033 ◽  
Author(s):  
N.K. Lazaridis ◽  
T.D. Karapantsios ◽  
D. Georgantas

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