Optimization of total organic carbon removal of a real dyeing wastewater by heterogeneous Fenton using response surface methodology

2018 ◽  
Vol 136 ◽  
pp. 186-198 ◽  
Author(s):  
Bi Gouessé Henri Briton ◽  
Laurent Duclaux ◽  
Yohan Richardson ◽  
Kouassi Benjamin Yao ◽  
Laurence Reinert ◽  
...  
Keyword(s):  
Response Surface Methodology ◽  
Organic Carbon ◽  
Total Organic Carbon ◽  
Response Surface ◽  
Dyeing Wastewater ◽  
Heterogeneous Fenton ◽  
Carbon Removal ◽  
Total Organic Carbon Removal

scholarly journals Taguchi Method and Response Surface Methodology in the Treatment of Highly Contaminated Tannery Wastewater Using Commercial Potassium Ferrate

Materials ◽  
2019 ◽  
Vol 12 (22) ◽  
pp. 3784 ◽  
Author(s):  
Violetta Kozik ◽  
Krzysztof Barbusinski ◽  
Maciej Thomas ◽  
Agnieszka Sroda ◽  
Josef Jampilek ◽  
...  
Keyword(s):  
Response Surface Methodology ◽  
Organic Carbon ◽  
Taguchi Method ◽  
Chemical Oxygen Demand ◽  
Total Organic Carbon ◽  
Response Surface ◽  
Suspended Solids ◽  
Oxygen Demand ◽  
Tannery Wastewater ◽  
Potassium Ferrate

The potential implementation of Envifer®, a commercial product containing potassium ferrate (40.1% K2FeO4), for the purification of highly contaminated tannery wastewater from leather dyeing processes was proposed. The employment of the Taguchi method for optimization of experiments allowed the discoloration (98.4%), chemical oxygen demand (77.2%), total organic carbon (75.7%), and suspended solids (96.9%) values to be lowered using 1.200 g/L K2FeO4 at pH 3 within 9 min. The application of the central composite design (CCD) and the response surface methodology (RSM) with the use of 1.400 g/L K2FeO4 at pH 4.5 diminished the discoloration, the chemical oxygen demand, the total organic carbon, and suspended solids within 9 min. The Taguchi method is suitable for the initial implementation, while the RSM is superior for the extended optimization of wastewater treatment processes.

scholarly journals Degradation and mineralization of 4-tert-butylphenol in water using Fe-doped TiO2 catalysts

2019 ◽  
Vol 9 (1) ◽  
Author(s):  
Ardak Makhatova ◽  
Gaukhar Ulykbanova ◽  
Shynggys Sadyk ◽  
Kali Sarsenbay ◽  
Timur Sh. Atabaev ◽  
...  
Keyword(s):  
Organic Carbon ◽  
Photocatalytic Degradation ◽  
Total Organic Carbon ◽  
Uv Light ◽  
Electric Energy ◽  
Carbon Removal ◽  
Wet Impregnation ◽  
Total Organic Carbon Removal ◽  
Butyl Phenol ◽  
Pseudo Second Order

AbstractIn the present work, the photocatalytic degradation and mineralization of 4-tert-butylphenol in water was studied using Fe-doped TiO2 nanoparticles under UV light irradiation. Fe-doped TiO2 catalysts (0.5, 1, 2 and 4 wt.%) were prepared using wet impregnation and characterized via SEM/EDS, XRD, XRF and TEM, while their photocatalytic activity and stability was attended via total organic carbon, 4-tert-butyl phenol, acetic acid, formic acid and leached iron concentrations measurements. The effect of H2O2 addition was also examined. The 4% Fe/TiO2 demonstrated the highest photocatalytic efficiency in terms of total organic carbon removal (86%). The application of UV/H2O2 resulted in 31% total organic carbon removal and 100% 4-t-butylphenol conversion, however combining Fe/TiO2 catalysts with H2O2 under UV irradiation did not improve the photocatalytic performance. Increasing the content of iron on the catalyst from 0.5 to 4% considerably decreased the intermediates formed and increased the production of carbon dioxide. The photocatalytic degradation of 4-tert-butylphenol followed pseudo-second order kinetics. Leaching of iron was observed mainly in the case of 4% Fe/TiO2, but it was considered negligible taking into account the iron load on catalysts. The electric energy per order was found in the range of 28–147 kWh/m3/order and increased with increasing the iron content of the catalyst.

scholarly journals Tubular nanofiltration of highly concentrated C.I. Acid Black 210 dye

2013 ◽  
Vol 67 (4) ◽  
pp. 901-906 ◽  
Author(s):  
A. Y. Zahrim ◽  
N. Hilal ◽  
C. Tizaoui
Keyword(s):  
Organic Carbon ◽  
Total Organic Carbon ◽  
Dye Removal ◽  
Nanofiltration Membrane ◽  
Solution Ph ◽  
Carbon Removal ◽  
Initial Concentration ◽  
Membrane Performance ◽  
Total Organic Carbon Removal ◽  
Fouling Factor

Tubular nanofiltration membrane performance to treat water for reuse was carried out by choosing C.I. Acid Black 210 dye as a model dye. It has been shown that increasing pH causes reduction in irreversible fouling factor (IFF) and the dye removal is also affected by solution pH. The total organic carbon removal for pH 4, pH 7, pH 8 and pH 10 is 97.9, 92.3, 94.5 and 94.6%, respectively. The conductivity removal for pH 4, pH 7, pH 8 and pH 10 is 85.1, 88.3, 87.8 and 90.7% respectively. The increase in the initial dye concentration causes rapid increase in fouling until 100 mg/l. Then the fouling increases gradually as it reaches a maximum IFF around 13%. This study also shows that the colour of permeate changes from colourless to light greenish/yellowish (initial concentration of 2,000 and 4,000 mg/l) as the initial dye concentration increases. The conductivity removal was also reduced as the initial dye concentration increased due to screening of the Donnan effect with the presence of salt.

Comparative study on electrochemical 4-chlorophenol degradation in different diaphragm systems with combined reduction and oxidation properties

2014 ◽  
Vol 71 (1) ◽  
pp. 126-130 ◽  
Author(s):  
S. L. Liu ◽  
H. Wang ◽  
Z. Y. Bian
Keyword(s):  
Organic Carbon ◽  
Total Organic Carbon ◽  
Electrode System ◽  
Hydrogen Gas ◽  
Combined Processes ◽  
Carbon Removal ◽  
Total Organic Carbon Removal ◽  
Oxidation Properties ◽  
Reduction And Oxidation ◽  
The Difference

Two diaphragm electrolysis systems, two-electrode (anode–cathode) and three-electrode (cathode–anode–cathode), were compared for the electrochemical degradation of 4-chlorophenol. The performance of these systems was improved by feeding with hydrogen gas and then with air, in aid of the combined processes of reduction and oxidation. The 4-chlorophenol degradation, dechlorination, and total organic carbon removal were monitored to characterize the difference between the two systems. The results indicated that the three-electrode system exhibited higher degradation percentages for 4-chlorophenol compared with that of the two-electrode system. The dechlorination property of the three-electrode system was stronger than that of the two-electrode system. In addition, the total organic carbon removal percentage of the anodic compartment in the three-electrode system was higher than that of the two-electrode system. The three-electrode system showed excellent treatment properties for 4-chlorophenol.

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