Adsorption efficiency, thermodynamics, and kinetics of amino-functionalized mesoporous calcium silicate for the removal of heavy metal ions

2018 ◽  
Vol 107 ◽  
pp. 165-181 ◽  
Author(s):  
Lihua Liu ◽  
Jinyan Liu ◽  
Tong Li ◽  
Ganggang Yang ◽  
Anping Tang ◽  
...  
2018 ◽  
Vol 77 (10) ◽  
pp. 2355-2368 ◽  
Author(s):  
Khalida Naseem ◽  
Zahoor H. Farooqi ◽  
Muhammad Z. Ur Rehman ◽  
Muhammad A. Ur Rehman ◽  
Robina Begum ◽  
...  

Abstract This review is based on the adsorption characteristics of sorghum (Sorghum bicolor) for removal of heavy metals from aqueous media. Different parameters like pH, temperature of the medium, sorghum concentration, sorghum particle size, contact time, stirring speed and heavy metal concentration control the adsorption efficiency of sorghum biomass for heavy metal ions. Sorghum biomass showed maximum efficiency for removal of heavy metal ions in the pH range of 5 to 6. It is an agricultural waste and is regarded as the cheapest biosorbent, having high adsorption capacity for heavy metals as compared to other reported adsorbents, for the treatment of heavy metal polluted wastewater. Adsorption of heavy metal ions onto sorghum biomass follows pseudo second order kinetics. Best fitted adsorption isotherm models for removal of heavy metal ions on sorghum biomass are Langmuir and Freundlich adsorption isotherm models. Thermodynamic aspects of heavy metal ions adsorption onto sorghum biomass have also been elaborated in this review article. How adsorption efficiency of sorghum biomass can be improved by different physical and chemical treatments in future has also been elaborated. This review article will be highly useful for researchers working in the field of water treatment via biosorption processing. The quantitative demonstrated efficiency of sorghum biomass for various heavy metal ions has also been highlighted in different sections of this review article.


2020 ◽  
Vol 99 ◽  
pp. 106072 ◽  
Author(s):  
Lihua Liu ◽  
Siyan Liu ◽  
Hongliang Peng ◽  
Zhengchi Yang ◽  
Lu Zhao ◽  
...  

Minerals ◽  
2019 ◽  
Vol 9 (5) ◽  
pp. 291 ◽  
Author(s):  
Dongxiao Ouyang ◽  
Yuting Zhuo ◽  
Liang Hu ◽  
Qiang Zeng ◽  
Yuehua Hu ◽  
...  

Tailings generated from mineral processing have attracted worldwide concerns due to creating serious environmental pollution. In this work, porous adsorbents were prepared as a porous block by using silicate tailings, which can adsorb heavy metal ions from the solution and are easy to separate. The synthesized silicate porous material (SPM) was characterized by X-ray diffraction (XRD), Brunner–Emmet–Teller (BET), and scanning electron microscope (SEM). The material presented a surface area of 3.40 m2⸱g−1, a porosity of 54%, and the compressive strength of 0.6 MPa. The maximum adsorption capacities of Pb2+, Cd2+, and Cu2+ by SPM were 44.83 mg·g−1, 35.36 mg·g−1, and 32.26 mg·g−1, respectively. The experimental data were fitted well by the Freundlich and Langmuir adsorption models. The kinetics of the adsorption process were fitted well by the pseudo-first order kinetic equation. These results show that the porous materials prepared with silicate tailings could act as an effective and low-cost adsorbent for the removal of heavy metal ions from wastewater. This study may provide a new thought on the high-value utilization of tailing for alleviating environmental pressure.


2016 ◽  
Vol 18 (23) ◽  
pp. 15564-15573 ◽  
Author(s):  
Weijie You ◽  
Mingzhu Hong ◽  
HaiFeng Zhang ◽  
Qiuping Wu ◽  
Zanyong Zhuang ◽  
...  

Inorganic hierarchical nanostructures have remarkable potential applications in environmental metal remediation; however, their applications usually suffer from low capacity, high cost, and difficulties in the recycling of adsorbents.


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