scholarly journals Transport Properties of Ordered and Disordered Doped Metallic Nanotubes

Author(s):  
Rekha Singh

We have studied the transport properties of ordered and disordered doped metallic nanotubes. We have presented these properties in periodic chemically metallic nitrogen doped metallic nanotubes. Transport properties with long range correlation have been studied using the Green’s function formalism in the frame work of the tight binding approach with effective parameters. Resonant conduction behaviour and ballistic transport have been demonstrated for particular positions of the dopant. These doping patterns have been shown to preserve the Bloach like transport properties and then to avoid Anderson localisation. The conductance response was almost changed because one of the two conductance channels remains true for both armchair and chiral nanotubes. These result reproduce the electronic properties of periodic nitrogen doped graphene. The present result has been drawn for specific chemical substitution of carbon atoms by nitrogen. These remain qualitatively valid for other local modifications of the nanotube by other chemical species by covalent or noncovalent functionalization. The energy of the quasi bound state depend on the specific local modification. We have shown that both axial and screw periodicities gave rise to such a behaviour and that specific disorder preserve their ballistic transport in doped metallic carbon nanotube.

Water ◽  
2020 ◽  
Vol 12 (11) ◽  
pp. 3121
Author(s):  
Hosna Ghanbarlou ◽  
Nikoline Loklindt Pedersen ◽  
Morten Enggrob Simonsen ◽  
Jens Muff

The synergy between electrochemical oxidation and adsorption on particle electrodes was investigated in three-dimensional (3D) systems for p-nitrosodimethylaniline (RNO) decolorization and pesticide removal. A comparison was made between granular activated carbon (GAC) and a novel synthesized nitrogen-doped graphene-based particle electrode (NCPE). Experiments on RNO decolorization show that the synergy parameter of the 3D-NCPE system was improved 3000 times compared to the studied 3D-GAC system. This was due to the specific nanostructure and composition of the NCPE material. Nitrogen-doped graphene triggered an oxygen reduction reaction, producing hydrogen peroxide that simultaneously catalyzed on iron sites of the NCPEs to hydroxyl radicals following the electro-Fenton (EF) process. Data showed that in the experimental setup used for the study, the applied cell voltage required for the optimal value of the synergy parameter could be lowered to 5V in the 3D-NCPEs process, which is significantly better than the 15–20 V needed for synergy to be found in the 3D-GAC process. Compared to previous studies with 3D-GAC, the removal of pesticides 2,6 dichlorobenzamide (BAM), 2-methyl-4-chlorophenoxyaceticacid (MCPA), and methylchlorophenoxypropionic acid (MCPP) was also enhanced in the 3D-NCPE system.


2021 ◽  
Author(s):  
Jingjing Liu ◽  
Wenyao Li ◽  
Zhe Cui ◽  
Jiaojiao Li ◽  
Fang Yang ◽  
...  

A core–shell CoMn-P@NG heterostructure electrode demonstrated impressive performance of hydrogen evolution over a broad pH range and maintained excellent stability.


Author(s):  
Periasamy Anbu ◽  
Subash C.B. Gopinath ◽  
Kandasamy Saravanakumar ◽  
Sekar Vijayakumar ◽  
Santheraleka Ramanathan ◽  
...  

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