Assessment of Heavy Metal Contamination in Roadside Soils along Irbid-Amman Highway, Jordan by ICP-OES

2020 ◽  
Vol 15 (1) ◽  
pp. 1-12

In this study, the concentrations of selected heavy metals (Al, Cd, Cr, Cu, Mn, Pb, Co, Fe, Ni, V and Zn) in roadside soil samples were determined by Inductively Coupled Plasma-Optical Emission Spectroscopy (ICP-OES) after microwave digestion. A total of sixty roadside soil samples were collected during July 2018 from seventeen sampling sites (5 km apart) from both sides along Irbid-Amman highway, Jordan. The average concentrations (±SD) of the investigated metals in the analyzed soil samples were found to be 18400 (± 11200), 6.0 (± 4.7), 132 (± 47), 49 (± 26), 695 (± 310), 96 (± 53), 78 (± 32), 31800 (± 12600), 116 (± 67), 141 (± 74) and 129 (± 112) µg/g for Al, Cd, Cr, Cu, Mn, Pb, Co, Fe, Ni, V and Zn, respectively. With exception of Mn, the enrichment factors for the investigated metals in roadside soils were found to be more than 10, indicating anthropogenic sources such as automobile traffic. In the absence of any industrial activities in the sampling sites, the high concentrations of the investigated metals suggest that automobile emissions are the major source of roadside soil pollution. The results obtained in this study showed that metal concentrations in the analyzed soil samples are strongly influenced by the wind direction and traffic density in the investigated area. The higher metal concentrations on the west side of the road were due to the easterly prevailing wind in the studied area. As expected, the concentrations of heavy metals decreased with increasing distance from the edge of the road. The results obtained in this work were compared with the literature values.

2012 ◽  
Vol 37 (1) ◽  
pp. 9-17 ◽  
Author(s):  
Habib Mohammad Naser ◽  
Sarmin Sultana ◽  
Rebeca Gomes ◽  
Shamsun Noor

Levels of lead, cadmium, and nickel in roadside soils and vegetables along a  major highway in Gazipur, Bangladesh were investigated. Soil samples were  collected at distances of 0, 50, 100, and 1000 m (meter) from the road. The  concentrations of lead (Pb) and nickel (Ni) in soil and vegetables (bottle gourd  and pumpkin) decreased with distance from the road, indicating their relation to  traffic and automotive emissions. The concentration of cadmium (Cd) was found  to be independent of distance from road. There were significant differences in  the concentrations of lead, cadmium, and nickel for different plant species and  soils at various distances. The heavy metals contents both in the soils and  vegetables for every distance from the road was found in the order  nickel>lead>cadmium. DOI: http://dx.doi.org/10.3329/bjar.v37i1.11170 Bangladesh J. Agril. Res. 37(1): 9-17, March 2012


Author(s):  
Nachana’a Timothy

Heavy metal concentration in roadside soil and plants are increasingly becoming of health concern. This work determined the concentration of selected heavy metals (Cd, Pb, Zn, Cr, Fe, Mg, Mn, Co, Ni and Cu) in roadside soils and plants samples from selected sites (Plaifu, Shiwa, Fadama-rake and Damdrai) along major road in Hong. Soil samples were taken 10 m, 20 m and 30 m away from the edge of the road at the  depth of 0-10 cm, 10-20 cm and 20-30 cm. Plant samples were randomly collected within the vicinity where the soil samples were taken and were analysed using Atomic Absorption Spectrophotometer. The result revealed the trend in soil heavy metal concentration was Fe > Mn > Mg > Pb > Zn > Ni > Co > Cu > Cr > Cd and for plant the trend was Fe > Mn > Mg > Zn > Pb > Ni > Cu > Cd > Co > Cr. The concentrations decreased with increasing distance away from the edge of the road as well as with depth at which the soil sample were taken. The transfer factor showed that the concentration of Zn, Mn, Cu and Mg were greater than 1, which shows that plant were enriched by Zn, Mn, Cu and Mg from the soil. Mg and Cd equal to 1 at Plaifu and Damdrai. Most of the values of TF at the study area super pass 0.5, which implies that generally, the ability of bioaccumulation of these heavy metals in examined plants were relatively high.


Author(s):  
Laxmi Kant Sharma

Pollution of natural environment due to release of heavy metals from various sources is a widespread problem throughout the world. This study explains the effect of heavy metal contaminants in Roadside soil of Morena district. Twelve air dried surface soil samples were collected from 50cm – 1m (point A) and twelve from 30m (point B) away from the roadside along a road with a distance of 50 km. Heavy metals were found in both points with highest concentration at 50cm – 1m (point A). Roadside soil is a definite indicator of vehicular pollution from where the high degree of contamination, is expected. The presence of heavy metals like Cu, Cr, Fe, Pb, Zn and Mn in the roadside soil was also considerable.


2016 ◽  
Vol 18 (4) ◽  
pp. 742-760 ◽  

<div> <p>This paper present migration of some selected heavy metal (zinc, lead, copper, chromium and nickel) of roadside soil samples from along Ilesa-Akure highway with a view to assess the degree of contamination such soils contain and the likelihood that this contamination can be remobilized. Soil samples were collected from 5 locations (Ilesa, Ipetu-ijesa, JABU, Ilara-mokin and FUTA north gate) at depths of 0-5, 15-20, 35-40 and 55-60cm and analysed for the five selected heavy metals in the bulk sample and clay fraction. Their concentrations and distributions in four different road verge zones (5m, 30m, 60m and 110m) were determined. The 5m zone had the highest mean concentration of the five metals whereas the 110m zone exhibited the lowest mean concentration. Zinc and lead exhibited a significant decrease in the roadside soils with the increasing distance from the road while chromium and nickel showed significant increase, copper on the other hand showed no significant difference. Quantitative assessment of the heavy metal contamination using the I<sub>geo </sub>and <em>PI</em> indexes showed that the selected heavy metals were in the order of Cu &lt; Pb &lt; Zn &lt; Ni &lt;Cr for both Indexes. Soil characteristics (which include pH, Cation exchange capacity {CEC}, organic matter and other basic geotechnical tests) responsible for the mobility and vertical distributions of these heavy metals from the road side soil were also assessed.</p> </div> <p>&nbsp;</p>


1999 ◽  
Vol 39 (2) ◽  
pp. 201-208 ◽  
Author(s):  
C. Dierkes ◽  
W. F. Geiger

Runoff from highways contains significant loads of heavy metals and hydrocarbons. According to German regulations, it should be infiltrated over embankments to support groundwater-recharge. To investigate the decontaminating effect of greened embankments, soil-monoliths from highways with high traffic densities were taken. Soils were analyzed to characterize the contamination in relation to distance and depth for lead, zinc, copper, cadmium, PAH and MOTH. Lysimeters were charged in the field and laboratory with highway runoff to study the effluents under defined conditions. Concentrations of pollutants in roadside soils depend on the age of embankments and traffic density. Highest concentrations were found in the upper 5 cm of the soil and within a distance of up to two metres from the street. Concentrations of most pollutants decreased rapidly with depth and distance. Lead and cadmium could not be detected in lysimeter effluent. Zinc and copper were found in concentrations that did not exceed drinking water quality limits.


2009 ◽  
Vol 66 (3) ◽  
pp. 361-367 ◽  
Author(s):  
Gustavo Souza Valladares ◽  
Otávio Antônio de Camargo ◽  
José Ruy Porto de Carvalho ◽  
Alessandra Maria Cia Silva

Agricultural management with chemicals may contaminate the soil with heavy metals. The objective of this study was to apply Principal Component Analysis and geoprocessing techniques to identify the origin of the metals Cu, Fe, Mn, Zn, Ni, Pb, Cr and Cd as potential contaminants of agricultural soils. The study was developed in an area of vineyard cultivation in the State of São Paulo, Brazil. Soil samples were collected and GPS located under different uses and coverings. The metal concentrations in the soils were determined using the DTPA method. The Cu and Zn content was considered high in most of the samples, and was larger in the areas cultivated with vineyards that had been under the application of fungicides for several decades. The concentrations of Cu and Zn were correlated. The geoprocessing techniques and the Principal Component Analysis confirmed the enrichment of the soil with Cu and Zn because of the use and management of the vineyards with chemicals in the preceding decades.


2002 ◽  
Vol 11 (4) ◽  
pp. 285-300 ◽  
Author(s):  
V. MÄNTYLAHTI ◽  
P. LAAKSO

Increasing concentrations of arsenic and heavy metals in agricultural soils are becoming a growing problem in industrialized countries. These harmful elements represent the basis of a range of problems in the food chain, and are a potential hazard for animal and human health. It is therefore important to gauge their absolute and relative concentrations in soils that are used for crop production. In this study the arsenic and heavy metal concentrations in 274 mineral soil samples and 38 organogenic soil samples taken from South Savo province in 2000 were determined using the aqua regia extraction technique. The soil samples were collected from 23 farms.The elements analyzed were arsenic, cadmium, chromium, copper, mercury, nickel, lead and zinc. The median concentrations in the mineral soils were:As 2.90 mg kg –1, Cd 0.084 mg kg –1, Cr 17.0 mg kg –1, Cu 13.0 mg kg –1, Hg 0.060 mg kg –1, Ni 5.4 mg kg –1, Pb 7.7 mg kg –1, Zn 36.5 mg kg –1. The corresponding values in the organogenic soils were:As 2.80 mg kg –1, Cd 0.265 mg kg –1, Cr 15.0 mg kg –1, Cu 29.0 mg kg –1, Hg 0.200 mg kg –1, Ni 5.9 mg kg –1, Pb 11.0 mg kg –1, Zn 25.5 mg kg –1. The results indicated that cadmium and mercury concentrations in the mineral and organogenic soils differed. Some of the arsenic, cadmium and mercury concentrations exceeded the normative values but did not exceed limit values. Most of the agricultural fields in South Savo province contained only small amounts of arsenic and heavy metals and could be classified as “Clean Soil”. A draft for the target values of arsenic and heavy metal concentrations in “Clean Soil” is presented.;


2020 ◽  
Vol 10 (27) ◽  
pp. 200911
Author(s):  
Aung Zaw Tun ◽  
Pokkate Wongsasuluk ◽  
Wattasit Siriwong

Background. Artisanal and small-scale mining activities are widely practiced globally. Concentrations of heavy metals associated with gold, such as copper (Cu), zinc (Zn), arsenic (As), cadmium (Cd), mercury (Hg) and lead (Pb) can increase in the environment as a result of mining activities, leading to environmental pollution and pose toxicity risks to humans and animals. Objectives. The aim of the present study was to investigate soil concentrations of toxic heavy metals in placer small-scale gold mining operations in Myanmar. Methods. Soil samples were collected from three placer small-scale gold mining sites: Site A located in the Hmawbon public protected forest, Site B and Site C, situated in the Nant-Kyin reserved forest around Nar Nant Htun village. At each site, soil samples were collected from four gold mining stages (ore processing, sluicing, panning, and amalgamation). Atomic absorption spectroscopy was utilized to examine the concentrations of As, Cd, Pb, and Hg. Results. The highest heavy metal concentrations were generally found in the amalgamation stages across all the gold mining sites. Across the three mining sites, the maximum heavy metal concentrations in the amalgamation stage were 22.170 mg.kg−1 for As, 3.070 mg.kg−1 for Cd, 77.440 mg.kg−1 for Hg, and 210.000 mg.kg−1 for Pb. Conclusions. The present study examined the concentrations of As, Cd, Hg and Pb in the soil of several small-scale gold mining sites in Banmauk Township, Myanmar. The results demonstrated the presence of high concentrations of heavy metals in the soil of the gold mining sites. Miners in this area work without proper personal protective equipment, and frequent exposure to heavy metals in the soil may cause adverse health effects. The present study provides baseline data for future risk assessment studies of heavy metal contamination in gold mines. Competing Interests. The authors declare no competing financial interests


Author(s):  
V. O. Wekpe ◽  
G. O. Chukwu-Okeah ◽  
Godspower Kinikanwo

City growth often time results in advancement and development in transportation which comes with its attendant changes in road infrastructure and transport support services such as road side mechanic workshops, vulcanizers and bus stops. A byproduct of these attendant contiguous activities and processes is the emission and release of trace heavy metals. Trace heavy metals have been identified as major carcinogens. This study aimed at determining the occurrence and concentration of heavy metals in roadside soils in an expanding third world metropolis. To achieve the aim of the research, the total length of the road within the study section was measured. Ten sample locations were indentified at about 2.5km intervals along the road section under review. The heavy metal concentration was determined the using Buck Scientific 210 VGP Atomic Absorption Spectrophotometer. Heavy metals such as Iron (Fe), Copper (Cu), Cadmium (Cd), Lead (Pb) and Mercury (Hg) were determined. The result of the analysis showed that the concentration values ranged from <0.001 to 48.90 µg/mg. The results also revealed that the experimental sample points recorded higher values than the control samples; however, some of the control points had relatively higher concentration values. This observation may have emanated from the low lying trajectory and topography of the surrounding area, which allows run-off from the road side soils to wash off heavy metals and deposit them at these lower lying areas. The sources of these trace heavy metals are attributed to emissions from motor vehicles that ply the road on a day to day basis. Emanating from the findings, this study recommends that improved public transportation and cleaner sources of energy is recommended.


Soil Research ◽  
2003 ◽  
Vol 41 (7) ◽  
pp. 1329 ◽  
Author(s):  
G. F. Birch ◽  
A. Scollen

The current temporal and spatial investigation was undertaken to determine the nature and concentration of heavy metals in road dust and to assess whether road dust was a possible source of metals to adjacent soils and gully pots.Three roads were selected in the Iron Cove catchment, Sydney Harbour, to investigate the influence of traffic volume on the heavy metal concentrations and accumulations rates with time. The mass of road dust increased irregularly with time since the last cleaning event and metal concentrations increased with traffic volume, but concentrations did not increase with antecedent time, possible due to variable particle size distributions. The mass of material accumulating on 1 m2 of road surface over 5 days was 72.5, 41.7, and 4.8 g for high (Parramatta Road), medium (Marion Street), and low (National Street) traffic volume roads, respectively. The source area of road surface for the test sites (200–400 m of road) may provide, over the 5-day test period, maximum loads of (g): Cr 2, Cu 7, Ni 2, Pb 29, and Zn 28 for Marion Street; Cr 0.1, Cu 0.3, Ni 0.1, Pb 2, and Zn 3 for National Street; and Cr 2, Cu 8, Ni 1, Pb 26, and Zn 18 for Parramatta Road. To provide better spatial information than the 3 samples sites used in the temporal study, road dust (n = 171) and gully pot (n = 23) samples where taken across the entire Iron Cove catchment. Mean concentrations of road dust were 6, 34, 164, 28 000, 284, 27, 487, and 523 μg/g for Co, Cr, Cu, Fe, Mn, Ni, Pb, and Zn, respectively, for all road types, and concentrations in gully pot material were 7, 20, 112, 24 000, 316, 20, 199, and 257 μg/g, respectively. A large proportion of these metals is associated with the mobile, fine fraction (<62.5 μm), and the majority (54–100%) of these elements are extracted with weak leaching agents (EDTA and 1 M hydrochloric acid). However, more information on speciation is required to determine bioavailability. SEM/EDAX analysis suggests that metals in the fine fraction may be adsorbed, whereas particulate metal and inclusion phases are common in the coarser (62.5–125 μm) material.Metal concentrations in parkland soils adjacent to the roads are highly enriched and increase with traffic volume. Concentrations decline markedly with distance from roads, but maximum values are at 30–50 m from the road edge, due to high-velocity wind generated by vehicles in proximity to the road. Metal-rich soils and gully pot deposits may be available for transport to the adjacent stormwater system.


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