Influence of Solvents on Properties of ZnS Thin Films Synthesized by Chemical Spray Pyrolysis Technique

2021 ◽  
Vol 14 (4) ◽  
pp. 349-358
Keyword(s):  
Thin Films ◽  
Ethylene Glycol ◽  
Spray Pyrolysis ◽  
Spray Pyrolysis Technique ◽  
Cost Effective ◽  
Chemical Spray Pyrolysis ◽  
Cost Effective Technique ◽  
Alcohol Solvents ◽  
Zns Films ◽  
Influence Of Solvents

Abstract: In this paper, the influence of solvents on the structural, optical, surface and electrical properties of spray-deposited ZnS thin films has been studied. Different precursor mixtures were prepared from ethylene glycol, deionized water and alcohol solvents and sprayed on heated glasses via a simple and cost-effective technique known as spray pyrolysis. XRD patterns confirmed cubic and tetragonal phases of synthesized ZnS material. The optical analysis of the synthesized ZnS films showed that films prepared using ethylene glycol solvent have the highest transmittance and the best bandgap (3.61 eV). Surface morphology showed the absence of voids and pinholes in the Scanning Electron Micrograph of ZnS film prepared from ethylene glycol and electrical studies showed that ZnS films prepared using the same solvent have the lowest resistivity. Keywords: ZnS, Thin film, Spray pyrolysis, Bandgap, Morphology.

scholarly journals Strong texture tuning along different crystalline directions in glass-supported CeO2 thin films by ultrasonic spray pyrolysis

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Inti Zumeta-Dubé ◽  
José Manuel García Rangel ◽  
Jorge Roque ◽  
Issis Claudette Romero-Ibarra ◽  
Mario Fidel García Sánchez
Keyword(s):  
Thin Films ◽  
Spray Pyrolysis ◽  
Spray Pyrolysis Technique ◽  
Morphological Characteristics ◽  
Ultrasonic Spray Pyrolysis ◽  
Cost Effective ◽  
Growth Direction ◽  
Large Area ◽  
Smart Windows ◽  
Ultrasonic Spray

AbstractThe strong facet-dependent performance of glass-supported CeO2 thin films in different applications (catalysis, smart windows, etc.) has been the target of diverse fundamental and technological approaches. However, the design of accurate, cost-effective and scalable methods with the potential for large-area coverage that produce highly textured glass-supported CeO2 thin films remains a technological challenge. In the present work, it is demonstrated that under proper tuning conditions, the ultrasonic spray pyrolysis technique enables one to obtain glass-supported polycrystalline CeO2 films with noticeable texture along both the (100) and (111) directions, as well as with randomly oriented crystallites (no texture). The influence of flow rates, solution molarity, and substrate temperature on the texture and morphological characteristics, as well as optical absorption and Raman response of the deposited films, is evaluated. The obtained results are discussed on the basis of the combined dependence of the CeO2-exposed surfaces on the thermodynamic stability of the corresponding facets and the reaction kinetics, which modulate the crystallite growth direction.

scholarly journals Influence of Ag-Dopant on Structural Optical and Electrical Properties of Cu(1-x)AgxO Thin Films Prepared By Chemical Spray Pyrolysis Technique

2018 ◽  
Vol 4 (5) ◽  
pp. 542-545 ◽  
Author(s):  
R. Shabu ◽  
A. Moses Ezhil Raj
Keyword(s):  
Thin Films ◽  
Band Gap ◽  
Spray Pyrolysis ◽  
Optical Band Gap ◽  
Spray Pyrolysis Technique ◽  
Precursor Solution ◽  
Oxide Semiconductor ◽  
Chemical Spray Pyrolysis ◽  
Chemical Spray Pyrolysis Technique ◽  
Chemical Spray

As major attention has been paid to transition metal oxide semiconductor suitable for solar cell, photo detector and gas sensor, present study embark on the structural, optical and electrical characterization of Ag doped CuO thin films prepared using chemical spray pyrolysis technique at the constant substrate temperature of 350 �C. For Ag doping, various concentrations of silver acetate (0.5-3.0 wt.%) was used in the sprayed precursor solution. Confirmed monoclinic lattice shows the tenorite phase formation of CuO in the pure and Ag doped films. The optical band gap of the films was in the range of 2.4 -3.4 eV. A minimum resistivity of 0.0017x103 ohmcm was achieved in the 0.5 wt.% Ag doped film, and its optical band gap was 2.74 eV.

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