Minerálne zloženie kryštalických vápencov z lokality Dobšiná - Kruhová (Slovenská republika)

2021 ◽  
Vol 29 (2) ◽  
pp. 285-296
Author(s):  
Peter Ružička ◽  
Pavol Myšľan ◽  
Tomáš Mikuš
Keyword(s):  
High Temperature ◽  
Chemical Composition ◽  
Amphibolite Facies ◽  
Western Carpathians ◽  
Lower Content ◽  
Mineral Association ◽  
Decomposition Processes ◽  
Identical Chemical Composition

Crystalline limestones containing fragments of amphibolites from the locality Dobšiná - Kruhová are part of the Klátov complex (Northern Gemericum, Western Carpathians). The colour of studied rocks is light grey with massive texture and granoblastic structure. Inhomogeneous mottled to breccia-like character of a crystalline limestones is caused by the presence of amphiboles in the studied rocks. The identified mineral association of crystalline limestones consists of calcite, amphiboles (pargasite, magnesio-hornblende, actinolite), clinopyroxenes (diopside), albite and titanite. Chemical zonation of amphiboles from the crystalline limestones and fragments of amphibolites have been studied in BSE imaging. Light grey BSE zone is represented by pargasite (with more Fe2+ up to 1.37 apfu and less Mg up to 2.26 apfu) and dark grey BSE zone is represented by magnesio-hornblend and actinolite (less Fe2+ 0.68 apfu in magnesio-hornblende; 0.62 apfu in actinolite and more Mg up to 3.30 apfu in magnesio-hornblende and up to 4.03 apfu in actinolite). Diopside has slightly higher content of Al (up to 0.13 apfu) and low content of Fe2+ (up to 0.17 apfu) with XMg ratio in the range 0.83 - 0.96. Chemical composition of albites is Ab91.12-98.21An1.52-5.12 with ortoclase component in the range 0.22 - 4.49 mol. %. Titanites from the amphibolite fragments and crystalline limestones have identical chemical composition (Ca up do 1.00 apfu, Si up to 0.97 apfu). Lower content of Ti (0.88 - 0.95 apfu) and higher content of F (up to 0.27 wt. %) and H2O (up to 0.38 wt. %) is present. In titanites not very significant (Al, Fe3+) + (OH, F) ↔ Ti + O substitution was also identified. We assume that pargasite and magnesio-hornblende are products of prograde etape of metamorphosis unlike actinolite which is product of retrograde etape of metamorphosis. Diopside was generated by dehydration and decomposition processes of magnesio-hornblende and pargasite in a high-temperature prograde regime of metamorphosis in the conditions of upper amphibolite facies. Calcite is chemically pure, presence of dolomite has not been confirmed.

NICROFER 5520 Co

Alloy Digest ◽  
1995 ◽  
Vol 44 (3) ◽  
Keyword(s):  
High Temperature ◽  
Chemical Composition ◽  
Physical Properties ◽  
Tensile Properties ◽  
High Temperatures ◽  
Heat Treating ◽  
High Temperature Corrosion ◽  
Creep Properties ◽  
Nickel Chromium ◽  
Temperature Performance

Abstract NICROFER 5520 Co is a nickel-chromium-cobalt-molybdenum alloy with excellent strength and creep properties up to high temperatures. Due to its balanced chemical composition the alloy shows outstanding resistance to high temperature corrosion in the form of oxidation and carburization. This datasheet provides information on composition, physical properties, elasticity, and tensile properties. It also includes information on high temperature performance as well as forming, heat treating, machining, and joining. Filing Code: Ni-480. Producer or source: VDM Technologies Corporation.

Scaling Behavior of Superheater Tube Alloys in ASME High Temperature Steam Research Tests at 1100–1500 F

1962 ◽  
Vol 84 (3) ◽  
pp. 223-257 ◽  
Author(s):  
F. Eberle ◽  
C. H. Anderson
Keyword(s):  
High Temperature ◽  
Chemical Composition ◽  
Thermal Shock ◽  
Thermal Shock Resistance ◽  
Scaling Behavior ◽  
Effect Of Temperature ◽  
Relative Resistance ◽  
Superheater Tube ◽  
Shock Resistance ◽  
High Temperature Steam

The scales formed on seven ferritic and ten austenitic types of commercial tubing presently in use and of potential future use for superheater service were examined after 6, 12, and 18 months’ exposure to air and to flowing steam of 2000 psi at temperatures of 1100, 1200, 1350, and 1500 F. The effect of temperature and time of exposure on the adherence, thermal-shock resistance, thickness, structure, and chemical composition of the scales was investigated and the relative resistance to scaling of the various alloys evaluated.

scholarly journals Formation of Intermediate Phases and Supersaturated Solid Solution in Al-Cu System during Diffusion

2018 ◽  
Vol 383 ◽  
pp. 31-35 ◽  
Author(s):  
Alexey Rodin ◽  
Nataliya Goreslavets
Keyword(s):  
Phase Diagram ◽  
Solid Solution ◽  
High Temperature ◽  
Chemical Composition ◽  
Low Temperature ◽  
Supersaturated Solid Solution ◽  
Diffusion Processes ◽  
Equilibrium Phase ◽  
Equilibrium Phase Diagram ◽  
Intermediate Phases

The study of diffusion processes in the aluminum - copper system was carried out at the temperature 350 and 520 °C. Special attention was paid on the chemical composition of the system near Al/Cu interface. It was determined that the intermediate phases in the system, corresponding to the equilibrium phase diagram, were not formed at low temperature. At high temperature the intermediate phases forms starting with Cu - rich phases. In both cases supersaturated solid solution of copper in aluminum could be observed near the interface.

scholarly journals Measurement of high-temperature strains in superalloy and carbon/carbon composites using chemical composition gratings

Strain ◽  
2016 ◽  
Vol 53 (1) ◽  
pp. e12218
Author(s):  
Weihua Xie ◽  
Songhe Meng ◽  
Hua Jin ◽  
Chong Du ◽  
Shiyu Huo ◽  
...  
Keyword(s):  
High Temperature ◽  
Chemical Composition ◽  
Carbon Composites

Metamorphism of the MacLean Lake and Central Metavolcanic belts, La Ronge domain, Trans-Hudson Orogen: pressure-temperature variations and tectonic implications

1998 ◽  
Vol 35 (8) ◽  
pp. 905-922 ◽  
Author(s):  
Haiming Yang ◽  
Kurt Kyser ◽  
Kevin Ansdell
Keyword(s):  
High Temperature ◽  
Thermal Gradient ◽  
Amphibolite Facies ◽  
Tectonic Zone ◽  
Thrust Sheet ◽  
Temperature Variations ◽  
High Thermal Gradient ◽  
Tectonic Implications ◽  
Peak Metamorphism ◽  
Peak Pressures

Metamorphic assemblages differ between the metasedimentary MacLean Lake belt and the adjacent Central Metavolcanic belt in the La Ronge domain, Trans-Hudson Orogen. The former consists of meta-arkoses, psammitic gneisses, metaconglomerates, and calc-silicate gneisses of upper amphibolite facies (600-740°C, 440-660 MPa) with local migmatization, whereas the latter is comprised mainly of metavolcanic and plutonic rocks, with minor metasedimentary schists of greenschist to lower amphibolite facies (480-630°C, 520-560 MPa). Petrographic evidence indicates that peak metamorphic conditions were reached towards the end of D1 deformation during which the Central Metavolcanic belt was thrust onto the MacLean Lake belt along the McLennan Lake tectonic zone, which separates the two belts. Peak metamorphic assemblages did not undergo retrograde alteration during D2 deformation, indicating that high temperature was maintained during D2 deformation. Differences in pressure (P) and temperature (T) between the northeastern and southwestern parts of the Central Metavolcanic belt may have resulted from tilting along strike after peak metamorphism. Peak temperatures increase gradually from the Central Metavolcanic belt to MacLean Lake belt across the McLennan Lake tectonic zone. Peak pressures in the two belts are similar, implying that the Central Metavolcanic belt thrust sheet was probably thin. The P-T data for the MacLean Lake belt indicate a relatively high thermal gradient (40-50°C/km), similar to that in the metasedimentary Kisseynew domain in the orogen.

scholarly journals Determination of Chromite Sands Suitability for Use in Moulding Sands

2017 ◽  
Vol 17 (2) ◽  
pp. 107-110
Author(s):  
K. Stec ◽  
J. Podwórny ◽  
B. Psiuk ◽  
Ł. Kozakiewicz
Keyword(s):  
Phase Composition ◽  
High Temperature ◽  
Chemical Composition ◽  
Chemical Properties ◽  
Grinding Process ◽  
X Ray Diffraction ◽  
Scanning Microscope ◽  
Spectroscopy Technique ◽  
X Ray

Abstract Using the available analytical methods, including the determination of chemical composition using wavelength-dispersive X-ray fluorescent spectroscopy technique and phase composition determined using X-ray diffraction, microstructural observations in a highresolution scanning microscope equipped with an X-ray microanalysis system as well as determination of characteristic softening and sintering temperatures using high-temperature microscope, the properties of particular chromite sands were defined. For the study has been typed reference sand with chemical properties, physical and thermal, treated as standard, and the sands of the regeneration process and the grinding process. Using these kinds of sand in foundries resulted in the occurrence of the phenomenon of the molding mass sintering. Impurities were identified and causes of sintering of a moulding sand based on chromite sand were characterized. Next, research methods enabling a quick evaluation of chromite sand suitability for use in the preparation of moulding sands were selected.

Ag2S2O8 meets AgSO4: the second example of metal–ligand redox isomerism among inorganic systems

2016 ◽  
Vol 45 (45) ◽  
pp. 18202-18207 ◽  
Author(s):  
Tomasz E. Gilewski ◽  
Piotr J. Leszczyński ◽  
Armand Budzianowski ◽  
Zoran Mazej ◽  
Adam Grzelak ◽  
...  
Keyword(s):  
Chemical Composition ◽  
Physicochemical Properties ◽  
Inorganic Systems ◽  
Redox Isomerism ◽  
First Time ◽  
Identical Chemical Composition ◽  
Metal Ligand

Ag(i)2S2O8 – prepared here for the first time – constitutes a redox isomer of the already known Ag(ii)SO4. These “electromers” have identical chemical composition but they differ in all important physicochemical properties.

A Study on Slag Composition inside Biomass Boiler System

2020 ◽  
Vol 901 ◽  
pp. 113-117
Author(s):  
Jirasak Tharajak ◽  
Noppakun Sanpo
Keyword(s):  
High Temperature ◽  
Chemical Composition ◽  
Slag Composition ◽  
Pulp And Paper ◽  
Critical Factors ◽  
Temperature Zone ◽  
Biomass Boiler ◽  
Factors Influencing ◽  
Steel Industries ◽  
Reliability And Availability

It was found that slagging in high temperature zone is one of the major problems in the refinery, petrochemical, pulp and paper, and steel industries; especially in biomass and coal pulverized power plant. Slagging conditions are critical factors influencing reliability and availability on a biomass utility boiler. In this study, several types of slagging were collected for chemical analysis. It was revealed that the chemical composition and other properties of received slagging showed unique results based on the type of feedstock fuel materials.

Active Chemistry Control for Coolant Helium Applying High-Temperature Gas-Cooled Reactors

2008 ◽  
Author(s):  
Nariaki Sakaba ◽  
Shimpei Hamamoto ◽  
Yoichi Takeda
Keyword(s):  
Heat Transfer ◽  
High Temperature ◽  
Heat Exchanger ◽  
Chemical Composition ◽  
Structural Integrity ◽  
Carbon Deposition ◽  
Control Technology ◽  
Equilibrium Study ◽  
Intermediate Heat Exchanger ◽  
High Temperature Gas

Lifetime extension of high-temperature equipment such as the intermediate heat exchanger of high-temperature gas-cooled reactors (HTGRs) is important from the economical point of view. Since the replacing cost will cause the increasing of the running cost, it is important to reduce replacing times of the high-cost primary equipment during assumed reactor lifetime. In the past, helium chemistry has been controlled by the passive chemistry control technology in which chemical impurity in the coolant helium is removed as low concentration as possible, as does Japan’s HTTR. Although the lifetime of high-temperature equipment almost depends upon the chemistry conditions in the coolant helium, it is necessary to establish an active chemistry control technology to maintain adequate chemical conditions. In this study, carbon deposition which could occur at the surface of the heat transfer tubes of the intermediate heat exchanger and decarburization of the high-temperature material of Hastelloy XR used at the heat transfer tubes were evaluated by referring the actual chemistry data obtained by the HTTR. The chemical equilibrium study contributed to clarify the algorism of the chemistry behaviours to be controlled. The created algorism is planned to be added to the instrumentation system of the helium purification systems. In addition, the chemical composition to be maintained during the reactor operation was proposed by evaluating not only core graphite oxidation but also carbon deposition and decarburization. It was identified when the chemical composition could not keep adequately, injection of 10 ppm carbon monoxide could effectively control the chemical composition to the designated stable area where the high-temperature materials could keep their structural integrity beyond the assumed duration. The proposed active chemistry control technology is expected to contribute economically to the purification systems of the future very high-temperature reactors.

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